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Safety Data Sheet EN

Hydrofluoric acid, 40%

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hydrofluoric acid, 40%
Product Code
10989

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

Alfa Aesar, A Johnson Matthey Company logo

Alfa Aesar, A Johnson Matthey Company

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

http://www.alfa.com

J

Johnson Matthey Catalog Company, Inc.

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

Emergency Contacts

Alfa Aesar, A Johnson Matthey Company

(978) 521-6300

CHEMTREC

(800) 424-9300

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 2
Acute Tox. Cat. 2
Acute Tox. Cat. 2
Skin Corr. Cat. 1A

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H300 Fatal if swallowed.
H310 Fatal in contact with skin.
H314 Causes severe skin burns and eye damage.
H330 Fatal if inhaled.

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P341 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P320 Specific treatment is urgent (see label).
P321 Specific treatment (see label).
P322 Specific measures (see label).
P330 Rinse mouth.
P361 Remove/Take off immediately all contaminated clothing.
P363 Wash contaminated clothing before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Hydrogen fluoride (CAS# 7664-39-3) , 40% Water (CAS# 7732-18-5), 60%

Chemical Name CAS Number Concentration Hazardous
Hydrogen fluoride EC: 231-634-8 7664-39-3 40% No
Water 7732-18-5 60% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.

Skin contact

Immediately wash with water and soap and rinse thoroughly. Rub in calcium gluconate solution or calcium gluconate gel immediately. Seek immediate medical advice.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Ingestion

Do not induce vomiting; immediately call for medical help. Seek immediate medical advice.

Immediate Medical Attention

Seek immediate medical advice.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Product is not flammable. Use fire fighting measures that suit the surrounding fire.

Specific hazards

In case of fire, the following can be released: Hydrogen fluoride (HF)

Firefighter Protection

Wear self-contained respirator. Wear fully protective impervious suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation.

Environmental

Do not allow material to be released to the environment without proper governmental permits.

Cleanup methods

Absorb with liquid-binding material. Use neutralizing agent.

Materials: sand, diatomite, acid binders, universal binders, sawdust

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep container tightly sealed. Open and handle container with care.

Storage

Store in cool, dry place in tightly closed containers.

Fire prevention

No special measures required.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves

Eyes

Safety glasses, Tightly sealed goggles, Full face protection

Respiratory

Use suitable respirator when high concentrations are present.

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Freezing Point
---
Upper Explosive Limit
Not determined
Explosive Limits
---
Physical State
Liquid
Odor Threshold
---
Softening Point
---
Bulk Density
---
Colour
Colorless
Vapor Pressure
33.25 hPa (25 mm Hg)
Boiling Point
108°C (226°F)
Kinematic Viscosity
---
Physical State Data
liquid
Metal Corrosion
---
Melting Point
-36°C (-33°F)
Molecular Weight
---
Properties Status
---
Flammability
Product is not flammable.
Evaporation Rate
---
Solubility
---
Solubility In Fat
---
Vapor Density
---
Dynamic Viscosity
---
Voc Content
---
Ph
---
Crystallisation Point
---
State Under Standard Conditions
---
Colour Intensity
---
Appearance
---
Flash Point
Not determined
Decomposition Temperature
Not determined
Density
1.15-1.18 g/cm³
Solidification Point
---
Odor
Acrid
Auto Ignition Temperature
Not determined
Relative Evaporation Rate
---
Cloud Point
---
Partition Coefficient
---
Relative Density
---
Form
Liquid
Lower Explosive Limit
Not determined
Solubility In Water
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Decomposition will not occur if used and stored according to specifications.

Reactivity

Reacts with metals forming hydrogen, Attacks materials containing glass and silicate, Reacts with strong alkali

Hazardous reactions

Reacts with metals forming hydrogen, Attacks materials containing glass and silicate, Reacts with strong alkali

Avoid

Used and stored according to specifications.

Incompatible

Alkali metals, Bases

Decomposition

Hydrogen fluoride

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Consult state, local or national regulations to ensure proper disposal.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1790
Shipping Name
HYDROFLUORIC ACID
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

For use only by technically qualified individuals. This product is being sold for research and development use only for the significant new use listed.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hydrofluoric acid, 40%?

The signal word is danger.

What is the physical form of Hydrofluoric acid, 40%?

Hydrofluoric acid, 40% is a liquid with colorless color. It has acrid odor.

What are the hazard statements for Hydrofluoric acid, 40%?

This substance has 4 hazard statements:

  • H300: Fatal if swallowed.
  • H310: Fatal in contact with skin.
  • H314: Causes severe skin burns and eye damage.
  • H330: Fatal if inhaled.

What is the melting point of Hydrofluoric acid, 40%?

The melting point is -36°C (-33°F) and the boiling point is 108°C (226°F).