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Safety Data Sheet EN

Chloromethane

CAS 74-87-3
EC 200-817-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Chloromethane
Product Code
295507
Chemical Name
chloromethane (methyl chloride)

Regulatory Identifiers

CAS Number
74-87-3 Check regulations →
EC Number
200-817-4 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street, SAINT LOUIS MO 63103, USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Gas Cat. 1 H220
Gases under pressure (Liquefied gas) H280
Carc. Cat. 2 H351
Repr. Cat. 2 H361
STOT RE Cat. 2 H373

GHS Pictograms

GHS02 - Flammable

GHS02

GHS04 - Compressed gas

GHS04

GHS08 - Serious health hazard

GHS08

Hazard Statements

H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs (Eyes, Nervous system, Testes) through prolonged or repeated exposure if inhaled.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P281 Use personal protective equipment as required.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 Eliminate all ignition sources if safe to do so.
P405 Store locked up.
P410 + P403 Protect from sunlight. Store in a well-ventilated place.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
chloromethane (methyl chloride) EC: 200-817-4 74-87-3 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Consult a physician.

Eye contact

Flush eyes with water as a precaution.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact Material: Fluorinated rubber Minimum layer thickness: 0.7 mm Break through time: 480 min Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M) Splash contact Material: Fluorinated rubber Minimum layer thickness: 0.7 mm Break through time: 480 min Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Properties Status
---
Density
---
Kinematic Viscosity
---
Relative Evaporation Rate
---
Bulk Density
---
Physical State
compressed liquefied gas
Freezing Point
---
Metal Corrosion
---
Solubility In Water
5.32 g/l at 25 ℃ (77 ºF) - soluble
Flammability
No data available
Solubility In Fat
---
Form
compressed liquefied gas
Softening Point
---
Evaporation Rate
No data available
Voc Content
---
Ph
No data available
Solidification Point
---
Flash Point
No data available
Vapor Density
No data available
Solubility
5.32 g/l at 25 ℃ (77 ºF) - soluble
Odor Threshold
No data available
Partition Coefficient
log Pow: 0.91
Molecular Weight
---
Decomposition Temperature
No data available
Auto Ignition Temperature
632.0 °℃ (1,169.6 °F)
Boiling Point
-24.2 °℃ (-11.6 ºF)
Melting Point
-97 ℃ (-143 ºF)
Upper Explosive Limit
17.4 %(V)
Crystallisation Point
---
Vapor Pressure
5,060.9 hPa (3,796.0 mmHg) at 20.0 ℃ (68.0 °F)
Relative Density
0.915 g/cm3 at 25 °℃ (77 ºF)
Odor
No data available
State Under Standard Conditions
---
Lower Explosive Limit
7 %(V)
Physical State Data
liquid
Colour Intensity
---
Dynamic Viscosity
---
Explosive Limits
---
Cloud Point
---
Appearance
compressed liquefied gas
Colour
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1063
Shipping Name
Methyl chloride
Transport Class
2.1
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Chloromethane?

The signal word is danger.

What is the physical form of Chloromethane?

Chloromethane is a compressed liquefied gas appearing as compressed liquefied gas . It has no data available odor.

What is the solubility of Chloromethane?

5.32 g/l at 25 ℃ (77 ºF) - soluble

What is Chloromethane used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Chloromethane?

This substance has 5 hazard statements:

  • H220: Extremely flammable gas.
  • H280: Contains gas under pressure; may explode if heated.
  • H351: Suspected of causing cancer.
  • H361: Suspected of damaging fertility or the unborn child.
  • H373: May cause damage to organs (Eyes, Nervous system, Testes) through prolonged or repeated exposure if inhaled.

What is the melting point of Chloromethane?

The melting point is -97 ℃ (-143 ºF) and the boiling point is -24.2 °℃ (-11.6 ºF).

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