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Safety Data Sheet EN

Permethrin

CAS 52645-53-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Permethrin
Product Code
45614

Regulatory Identifiers

CAS Number
52645-53-1 Check regulations →

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street, SAINT LOUIS MO 63103, USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H332
Skin Sens. Cat. 1 H317
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 + H332 Harmful if swallowed or if inhaled
H317 May cause an allergic skin reaction.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312 Call a POISON CENTER or doctor/ physician if you feel unwell.
P321 Specific treatment (see supplemental first aid instructions on this label).
P330 Rinse mouth.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Permethrin EC: 258-067-9 52645-53-1 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Consult a physician.

Eye contact

Flush eyes with water as a precaution.

Ingestion

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Specific hazards

Carbon oxides, Hydrogen chloride gas

Firefighter Protection

Wear self contained breathing apparatus for fire fighting if necessary.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Avoid breathing dust.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

Cleanup methods

Pick up and arrange disposal without creating dust. Sweep up and shovel.

Materials: Keep in suitable, closed containers for disposal.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Further processing of solid materials may result in the formation of combustible dusts. The potential for combustible dust formation should be taken into consideration before additional processing occurs.

Storage

Keep container tightly closed in a dry and well-ventilated place.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Handle in accordance with good industrial hygiene and safety practice.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Material: Nitrile rubber, Minimum layer thickness: 0.11 mm, Break through time: 480 min, Material tested: Dermatril® (KCL 740 / Aldrich Z677272, Size M), test method: EN374

Eyes

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator. For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Semi-solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Semi-solid melting to a liquid
Colour
---
Colour Intensity
---
Form
Semi-solid melting to a liquid
Odor
no data available
Odor Threshold
no data available
Ph
no data available
Melting Point
34 °C (93 °F)
Boiling Point
>290 °C (>554 °F) at 1,013 hPa (760 mmHg)
Flash Point
no data available
Freezing Point
34 °C (93 °F)
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
no data available
Vapor Pressure
no data available
Vapor Density
no data available
Relative Density
1.190 - 1.270 g/cm³ at 20 °C (68 °F)
Bulk Density
---
Density
1.190 - 1.270 g/cm³ at 20 °C (68 °F)
Flammability
no data available
Upper Explosive Limit
no data available
Lower Explosive Limit
no data available
Explosive Limits
---
Auto Ignition Temperature
no data available
Decomposition Temperature
no data available
Solubility
---
Partition Coefficient
log Pow: 6.5
Solubility In Water
no data available
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
no data available
Kinematic Viscosity
no data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

no data available

Hazardous reactions

no data available

Avoid

no data available

Incompatible

Strong oxidizing agents

Decomposition

Other decomposition products - no data available. In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

Disposal

Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3077
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Permethrin)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Permethrin?

The signal word is warning.

What is the physical form of Permethrin?

Permethrin is a semi-solid appearing as semi-solid melting to a liquid . It has no data available odor.

What is Permethrin used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Permethrin?

This substance has 3 hazard statements:

  • H302 + H332: Harmful if swallowed or if inhaled
  • H317: May cause an allergic skin reaction.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of Permethrin?

The melting point is 34 °C (93 °F) and the boiling point is >290 °C (>554 °F) at 1,013 hPa (760 mmHg).