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Safety Data Sheet EN

p-Toluenesulfonyl chloride

CAS 98-59-9
EC 202-684-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
p-Toluenesulfonyl chloride
Product Code
16205

Regulatory Identifiers

CAS Number
98-59-9 Check regulations →
EC Number
202-684-8 Check regulations →

Identified Uses

SU24 Scientific research and development

Manufacturers & Suppliers

Alfa Aesar, Thermo Fisher Scientific Chemicals, Inc. logo

Alfa Aesar, Thermo Fisher Scientific Chemicals, Inc.

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

800-343-0660

http://www.alfa.com

Emergency Contacts

Emergency Contact

(800) 343-0660

Monday-Friday, 8am-7pm EST

Carechem 24

(866) 928-0789

After normal business hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Water-react. Cat. 2 H261
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

Hazard Statements

H261 In contact with water releases flammable gas.
H314 Causes severe skin burns and eye damage.

Precautionary Statements

P231 + P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P303 + P361 + P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

CAS# Description: 98-59-9 p-Toluenesulfonyl chloride

Chemical Name CAS Number Concentration Hazardous
p-Toluenesulfonyl chloride EC: 202-684-8 98-59-9 --- No

Identification number(s): EC number: 202-684-8

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.

Skin contact

Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Ingestion

Seek medical treatment.

Immediate Medical Attention

Seek immediate medical advice.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, sand, extinguishing powder.

Unsuitable media

Water

Specific hazards

Reacts violently with water. Reacts with water forming hydrochloric acid (HCl). If this product is involved in a fire, the following can be released:

Firefighter Protection

Wear self-contained respirator. Wear fully protective impervious suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment. Keep unprotected persons away.

Environmental

Do not allow material to be released to the environment without proper governmental permits.

Cleanup methods

Use neutralizing agent.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep container tightly sealed. Store in cool, dry place in tightly closed containers. Ensure good ventilation at the workplace.

Storage

Store in cool, dry place in tightly closed containers. Protect from humidity and water.

Fire prevention

Protect from humidity and water.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Property operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves. Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.

Eyes

Tightly sealed goggles. Full face protection.

Respiratory

Use suitable respirator when high concentrations are present.

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Appearance
---
Kinematic Viscosity
Not applicable.
Odor
Not determined
Physical State Data
solid
Explosive Limits
---
Flash Point
110 °C (230 °F)
Physical State
Crystalline
Melting Point
69-71 °C (156-160 °F)
Odor Threshold
Not determined.
State Under Standard Conditions
---
Relative Density
Not determined.
Flammability
Not determined.
Bulk Density
---
Lower Explosive Limit
Not determined
Relative Evaporation Rate
---
Evaporation Rate
Not applicable.
Decomposition Temperature
Not determined
Density
1.33 g/cm³ (11.099 lbs/gal)
Properties Status
---
Solidification Point
---
Voc Content
---
Cloud Point
---
Auto Ignition Temperature
Not determined
Crystallisation Point
---
Metal Corrosion
---
Vapor Density
Not applicable.
Upper Explosive Limit
Not determined
Boiling Point
112 °C (234 °F) ((116mm Hg))
Softening Point
---
Solubility In Fat
---
Solubility In Water
Reacts violently
Molecular Weight
---
Vapor Pressure
Not applicable.
Colour Intensity
---
Partition Coefficient
Not determined.
Ph
Not applicable.
Colour
Colorless
Freezing Point
---
Dynamic Viscosity
Not applicable.
Form
Crystalline
Solubility
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

Reacts violently with water.

Hazardous reactions

Reacts with water forming hydrochloric acid (HCl); Reacts violently with water

Avoid

No further relevant information available.

Incompatible

Bases, Oxidizing agents, Alcohols, Water/moisture

Decomposition

Hydrogen chloride (HCl), Sulfur oxides (SOx), Carbon monoxide and carbon dioxide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Consult state, local or national regulations to ensure proper disposal.

Disposal

Consult state, local or national regulations to ensure proper disposal.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3096
Shipping Name
Corrosive solids, water-reactive, n.o.s. (p-toluenesulfonyl chloride)
Transport Class
8
Packing Group
II
ADR

Warning: Corrosive substances

IMDG

Warning: Corrosive substances

IATA

Warning: Corrosive substances

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for p-Toluenesulfonyl chloride?

The signal word is danger.

What is the physical form of p-Toluenesulfonyl chloride?

p-Toluenesulfonyl chloride is a crystalline with colorless color. It has not determined odor.

What is p-Toluenesulfonyl chloride used for?

SU24 Scientific research and development

What are the hazard statements for p-Toluenesulfonyl chloride?

This substance has 2 hazard statements:

  • H261: In contact with water releases flammable gas.
  • H314: Causes severe skin burns and eye damage.

What is the melting point of p-Toluenesulfonyl chloride?

The melting point is 69-71 °C (156-160 °F) and the boiling point is 112 °C (234 °F) ((116mm Hg)).