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Safety Data Sheet EN

Hammer

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hammer

Regulatory Identifiers

CAS Number
N/A

Identified Uses

crop protection product, herbicide

Manufacturers & Suppliers

B

BASF SE

manufacturer

67056 Ludwigshafen, GERMANY

+49 621 60-27777

Emergency Contacts

International emergency number

+49 180 2273-112

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Aquatic Acute Cat. 1
Aquatic Chronic Cat. 1

GHS Pictograms

GHS09 - Environmental hazard

GHS09

Hazard Statements

H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
P391 Collect spillage.
P501 Dispose of contents and container to hazardous or special waste collection point.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

crop protection product, herbicide, Soluble concentrate (SL)

Chemical Name CAS Number Concentration Hazardous
3-Pyridinecarboxylic acid, 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-ethyl- 81335-77-5 9.35% Yes
Ethane-1,2-diol EC: 203-473-3 107-21-1 10% Yes
Ammonia, aqueous solution EC: 215-647-6 1336-21-6 3% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Keep patient calm, remove to fresh air.

Skin contact

Wash thoroughly with soap and water

Eye contact

Wash affected eyes for at least 15 minutes under running water with eyelids held open.

Ingestion

Rinse mouth and then drink 200-300 ml of water.

Medical Treatment

Symptomatic treatment (decontamination, vital functions).

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

water spray, carbon dioxide, foam, dry powder

Specific hazards

Carbon monoxide, Ammonia, anhydrous, Carbon dioxide, Hydrogen chloride, nitrogen oxides, organochloric compounds, silica compounds. The substances/groups of substances mentioned can be released in case of fire.

Instructions

Keep containers cool by spraying with water if exposed to fire.

Firefighter Protection

Wear self-contained breathing apparatus and chemical-protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray.

Small spill

Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).

Large spill

Dike spillage. Pump off product.

Environmental

Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.

Cleanup methods

Pick up with suitable absorbent material. Pump off product.

Materials: sand, sawdust, general-purpose binder, kieselguhr

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

No special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.

Storage

Keep away from heat. Protect from direct sunlight. Segregate from foods and animal feeds.

Hygiene

When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.

Fire prevention

No special precautions necessary. The substance/product is non-combustible.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc.

Eyes

Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Respiratory

Respiratory protection not required.

Skin/Body

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

State Under Standard Conditions
---
Boiling Point
approx. 98 - 102 °C
Decomposition Temperature
No decomposition if stored and handled as prescribed/indicated.
Relative Density
approx. 1,07 g/cm3 (20 ℃)
Appearance
---
Freezing Point
---
Bulk Density
---
Partition Coefficient
1,49 (25 °C; pH value: 7)
Molecular Weight
---
Solubility
readily soluble
Form
liquid
Vapor Density
---
Vapor Pressure
approx. 23 hPa (20 °C)
Flash Point
Non-flammable.
Solubility In Water
readily soluble
Odor Threshold
Not determined due to potential health hazard by inhalation.
Melting Point
---
Properties Status
---
Ph
approx. 6,0 - 8,0 (20 °C)
Upper Explosive Limit
As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use.
Solidification Point
---
Density
approx. 1,07 g/cm³ (20 °C)
Odor
musty
Solubility In Fat
---
Explosive Limits
---
Physical State
liquid
Voc Content
---
Flammability
not applicable
Kinematic Viscosity
---
Softening Point
---
Crystallisation Point
< 17 °C
Colour Intensity
---
Lower Explosive Limit
As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use.
Evaporation Rate
not applicable
Metal Corrosion
---
Cloud Point
---
Auto Ignition Temperature
Based on the water content the product does not ignite.
Colour
green to dark brown
Dynamic Viscosity
approx. 29,8 mPa.s (20 °C)
Relative Evaporation Rate
---
Physical State Data
liquid
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable if stored and handled as prescribed/indicated.

Reactivity

No hazardous reactions if stored and handled as prescribed/indicated.

Hazardous reactions

No hazardous reactions if stored and handled as prescribed/indicated.

Avoid

See SDS section 7 - Handling and storage.

Incompatible

strong bases, strong acids, strong oxidizing agents

Decomposition

No hazardous decomposition products if stored and handled as prescribed/indicated.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Must be sent to a suitable incineration plant, observing local regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains IMAZETHAPYR)
Transport Class
9, EHSM
Packing Group
III
ADR

None known

IMDG

None known

IATA

None known

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

To avoid risks to man and the environment, comply with the instructions for use.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hammer?

The signal word is warning.

What is the physical form of Hammer?

Hammer is a liquid with green to dark brown color. It has musty odor.

What is the solubility of Hammer?

readily soluble

What is Hammer used for?

crop protection product, herbicide

What are the hazard statements for Hammer?

This substance has 2 hazard statements:

  • H400: Very toxic to aquatic life.
  • H410: Very toxic to aquatic life with long lasting effects.