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Safety Data Sheet EN

R404A

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
R404A

Regulatory Identifiers

CAS Number
N/A
REACH No.
01-2119492869-13, 01-2119485636-25, 01-2119459374-33

Identified Uses

Refrigeration

Manufacturers & Suppliers

H

Harp International Ltd

manufacturer

Gellihirion Industrial Estate, Pontypridd, Rhondda Cynon Taff, CF37 5SX

+44 (0) 1443 842255

Emergency Contacts

Emergency Contact

+44 (0) 1270 502891

24 hour

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Gases under pressure – Liquefied gas

GHS Pictograms

GHS04 - Compressed gas

GHS04

Hazard Statements

H280 Contains gas under pressure; may explode if heated

Precautionary Statements

P410 + P403 Protect from sunlight. Store in a well-ventilated place.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
1,1,1-Trifluoroethane (143a) EC: 206-996-5 420-46-2 52% Yes
Pentafluoroethane (R125) EC: 206-557-8 354-33-6 44% Yes
1,1,1,2-Tetrafluoroethane (R134a) EC: 212-377-0 811-97-2 4% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Oxygen or artificial respiration if needed. If symptoms persist, call a physician.

Symptoms: In case of higher concentrations: narcosis, asphyxia, may cause cardio arrhythmia.

Skin contact

Allow to evaporate. Wash off with warm water. If symptoms persist, call a physician.

Symptoms: Contact with liquid or refrigerated gas can cause cold burns and frostbite. Prolonged skin contact may defat the skin and produce dermatitis.

Eye contact

Immediately irrigate with eyewash solution or clean water, holding the eyelids apart for at least 10 minutes. Obtain immediate medical attention.

Symptoms: Causes frostbite burns to eyes. Symptoms: Lachrymation, redness, swelling of tissue, frostbite, burn.

Ingestion

Unlikely route of exposure.

Symptoms: Gas. Not applicable.

Immediate Medical Attention

Obtain immediate medical attention.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

As appropriate for surrounding fire. Keep fire exposed containers cool by spraying with water.

Unsuitable media

None.

Specific hazards

The product is not flammable. Hazardous decomposition products formed under fire conditions.

Instructions

In case of fire, use water spray. Keep product and empty container away from heat and sources of ignition.

Firefighter Protection

Wear self-contained breathing apparatus and protective suit. Wear chemical resistant oversuit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Suppress (knock down) gases/vapours/mists with a water spray jet. Avoid spraying the leak source. Ventilate area.

Environmental

Discharge into the environment must be avoided

Cleanup methods

Allow to evaporate

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only in well-ventilated areas, Use only clean and dry utensils, Keep away from water, Preferably transfer by pump or gravity, Keep away from incompatible products

Storage

Keep only in the original container, Store in a receptacle equipped with a vent, Keep containers tightly closed in a cool, well-ventilated place, Keep in properly labelled containers, Keep in a bunded area, Keep away from heat/sparks/open flames/hot surfaces. No smoking., Keep away from incompatible products

Fire prevention

Keep away from heat/sparks/open flames/hot surfaces. No smoking.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation. Apply technical measures to comply with the occupational exposure limits.

Hands

Take note of the information given by the producer concerning permeability and break through times and of special workplace conditions (mechanical strain, duration of contact). Protective gloves. Suitable material: Fluoroelastomer.

Eyes

Tightly fitted safety goggles.

Respiratory

Self-contained breathing apparatus (EN 133). Wear self-contained breathing apparatus in confined spaces, in cases where the oxygen level is depleted, or in case of significant emissions. Use only respiratory protection that conforms to international / national standards.

Skin/Body

Wear suitable protective clothing. If splashes are likely to occur, wear: apron, boots, Neoprene.

Environmental

Dispose of rinse water in accordance with local and national regulations.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Compressed liquefied gas
Physical State Data
gas
State Under Standard Conditions
---
Appearance
---
Colour
Colourless
Colour Intensity
---
Form
Compressed liquefied gas
Odor
Ether-like
Odor Threshold
---
Ph
Neutral
Melting Point
-103°C (Pentafluoroethane)
Boiling Point
-46.7°C
Flash Point
Not applicable
Freezing Point
-103 [o] C (Pentafluoroethane)
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data
Vapor Pressure
10.98 bar at 20°C 20.03 bar at 50°C
Vapor Density
>3
Relative Density
---
Bulk Density
Not applicable
Density
Not applicable
Flammability
The product is not flammable
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
728°C
Decomposition Temperature
>700°C
Solubility
430 mg/l at 25 [o] C, water (pentafluoroethane)
Partition Coefficient
log Pow: 1.48, 20°C (pentafluoroethane)
Solubility In Water
430 mg/l at 25°C, water (pentafluoroethane)
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions

Hazardous reactions

Strong oxidizers, alkali metals and alkaline earth metals may cause fires or explosions. Vapours are heavier than air and may spread along floors

Avoid

Heat

Incompatible

Light and/or alkaline metals, powdered metals, alkaline earth metals, oxidising agents

Decomposition

Gaseous hydrogen fluoride (HF), Fluorophosgene. The release of other hazardous decomposition products is possible

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Refer to manufacturer/supplier for information on recovery/recycling

Disposal

In accordance with local and national regulations

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3337
Shipping Name
REFRIGERANT GAS R404A
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for R404A?

The signal word is warning.

What is the physical form of R404A?

R404A is a compressed liquefied gas with colourless color. It has ether-like odor.

What is the solubility of R404A?

430 mg/l at 25 [o] C, water (pentafluoroethane)

What is R404A used for?

Refrigeration

What are the hazard statements for R404A?

This substance has 1 hazard statement:

  • H280: Contains gas under pressure; may explode if heated

What is the melting point of R404A?

The melting point is -103°C (Pentafluoroethane) and the boiling point is -46.7°C.