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Safety Data Sheet EN

Manganese lithium rechargeable battery (ML Series)

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Manganese lithium rechargeable battery (ML Series)

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

P

Panasonic Energy Co., Ltd.

manufacturer

1-1 Matsushita-cho, Moriguchi-city, Osaka, 570-8511, Japan

Emergency Contacts

Emergency Contact

+81-80-9932-3190

JST Working hours

Emergency Contact

+81-6-6991-1141

Holiday

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H228 Hazard : Electrolyte and lithium metal are inflammable.
H228 Stacking or jumbling batteries may cause external short circuits, heat generation, fire or explosion.
H242 Risk of explosion by fire if batteries are disposed in fire or heated above 100 degrees C.
H335 Toxicity : Vapor generated from burning batteries, may irritate eyes, skin and throat.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

The product is composed of a positive electrode (Lithium manganese oxide), a negative electrode (Lithium, Aluminum), an electrolyte (1,2-dimethoxyethane, Propylene Carbonate), and other parts (Steel or Plastic parts: Steel, Polypropylene).

Chemical Name CAS Number Concentration Hazardous
Lithium manganese oxide 12057-17-9 9 - 28% No
Lithium 7439-93-2 0.4 - 3% No
Aluminum 7429-90-5 2 - 11% No
1,2-dimethoxyethane 110-71-4 1 - 4% No
Propylene Carbonate 108-32-7 3 - 11% No
Steel --- 60 - 85% No
Polypropylene 9003-07-0 1 - 15% No

Lithium content per cell: ML421: 0.0008g; ML614: 0.001g; ML621: 0.002g; ML920: 0.004g; ML1220: 0.006g; ML2020: 0.02g.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air immediately. Get medical treatment immediately.

Skin contact

Wash the affected area under tepid running water using a mild soap. Get medical attention if irritation develops or persists.

Symptoms: If appropriate procedures are not taken, this may cause sores on the skin.

Eye contact

Flush the eyes with plenty of clean water for at least 15 minutes immediately, without rubbing. Get immediate medical treatment.

Symptoms: If appropriate procedures are not taken, this may cause eye injury.

Immediate Medical Attention

Get immediate medical treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Alcohol-resistant foam and dry sand are effective.

Specific hazards

vapor may make eyes, nose and throat irritate

Instructions

Be sure on the windward to extinguish the fire

Firefighter Protection

Wear the respiratory protection equipment in some cases.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Take up with absorbent cloth, treat cloth as inflammable. Move the battery away from the fire.

Cleanup methods

Take up with absorbent cloth

Materials: absorbent cloth

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not allow battery terminals to contact each other or other metals. Pack with partitions or in separate plastic bags to prevent mixing. Do not short-circuit, deform, throw into fire, or disassemble. Charge according to specified conditions. Do not mix different types of batteries. Do not solder directly onto batteries. Insert correctly in electrical equipment.

Storage

Do not store in high temperature or under direct sunlight. Avoid high humidity. Do not expose to condensation, rain, or frozen conditions. Prevent water penetration into packaging boxes.

Fire prevention

Do not throw into fire.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Facilities : Nothing in particular.

Hands

Safety gloves.

Eyes

Safety goggle

Respiratory

For most condition no respiratory protection.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State Data
---
State Under Standard Conditions
---
Evaporation Rate
---
Freezing Point
---
Voc Content
---
Density
---
Metal Corrosion
---
Relative Evaporation Rate
---
Relative Density
---
Dynamic Viscosity
---
Cloud Point
---
Properties Status
---
Auto Ignition Temperature
---
Flash Point
---
Form
---
Solubility In Fat
---
Appearance
Coin shape
Solubility
---
Vapor Pressure
---
Explosive Limits
---
Lower Explosive Limit
---
Odor Threshold
---
Boiling Point
---
Upper Explosive Limit
---
Solidification Point
---
Ph
---
Partition Coefficient
---
Softening Point
---
Kinematic Viscosity
---
Vapor Density
---
Solubility In Water
---
Bulk Density
---
Crystallisation Point
---
Decomposition Temperature
---
Odor
---
Melting Point
---
Colour Intensity
---
Flammability
---
Molecular Weight
---
Physical State
---
Colour
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Reactivity

Since batteries utilize a chemical reaction they are actually considered a chemical product.

Avoid

various usage conditions such as discharge, ambient temperature, etc. are not maintained within the specified ranges

Decomposition

electrolyte leakage

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

When the battery is worn out, dispose of it under the ordinance of each local government.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3090
Shipping Name
Lithium metal batteries
Transport Class
Class 9
ADR

During the transportation of a large amount of batteries by ship, trailer or railway, do not leave them in the places of high temperatures and do not allow them to be exposed to condensation. During the transportation do not allow packages to be dropped or damaged.

IMDG

During the transportation of a large amount of batteries by ship, trailer or railway, do not leave them in the places of high temperatures and do not allow them to be exposed to condensation. During the transportation do not allow packages to be dropped or damaged.

IATA

During the transportation of a large amount of batteries by ship, trailer or railway, do not leave them in the places of high temperatures and do not allow them to be exposed to condensation. During the transportation do not allow packages to be dropped or damaged.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Manganese lithium rechargeable battery (ML Series)?

The signal word is danger.

What are the hazard statements for Manganese lithium rechargeable battery (ML Series)?

This substance has 4 hazard statements:

  • H228: Hazard : Electrolyte and lithium metal are inflammable.
  • H228: Stacking or jumbling batteries may cause external short circuits, heat generation, fire or explosion.
  • H242: Risk of explosion by fire if batteries are disposed in fire or heated above 100 degrees C.
  • H335: Toxicity : Vapor generated from burning batteries, may irritate eyes, skin and throat.