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Safety Data Sheet EN

WEVO – HARDENER 300

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
WEVO – HARDENER 300

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Hardener for polyurethanes

Manufacturers & Suppliers

W

WEVO-CHEMIE GmbH

manufacturer

Schönbergstrasse 14, D - 73760 Ostfeldern - Kemnat

+49 - 711 - 16761 - 0

Emergency Contacts

Vergiftungs-Informations-Zentrale, Freiburg

+49 761 – 19240

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Resp. Sens. Cat. 1 H334
Skin Sens. Cat. 1 H317
Carc. Cat. 2 H351
STOT SE Cat. 3 H335
STOT RE Cat. 2 H373

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 Causes skin irritation.
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful if inhaled
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H351 Suspected of causing cancer
H373 May cause damage to organs (Respiratory organs) through prolonged or repeated exposure if inhaled.

Precautionary Statements

P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray
P280 Wear protective gloves/eye protection/face protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P308 + P313 IF exposed or concerned: Get medical advice/attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

diphenyl methane diisocyanate, isomers and homologues

Chemical Name CAS Number Concentration Hazardous
diphenyl methane diisocyanate, isomers and homologues 9016-87-9 50 - 75% No
Formaldehyde, oligomeric reaction products with aniline and phosgene EC: 500-079-6 32055-14-4 25 - 50% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Take the person into the fresh air and keep him warm, let him rest

Symptoms: difficulty in breathing

Skin contact

In the event of contact with the skin, preferably wash with a cleanser based on polyethylene glycol or with plenty of warm water and soap.

Symptoms: skin reaction

Eye contact

Hold the eyes open and rinse with preferably lukewarm water for a sufficiently long period of time (at least 10 minutes). Contact an ophthalmologist.

Ingestion

DO NOT induce the patient to vomit

Immediate Medical Attention

if there is difficulty in breathing, medical advice is required. Consult a doctor in the event of a skin reaction. Contact an ophthalmologist. medical advice is required (for ingestion).

Medical Treatment

Treatment of acute irritation or bronchial constriction is primarily symptomatic. Extended medical treatment may be required depending on the degree of exposure and the severity of the symptoms.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2), Foam, extinguishing powder, in cases of larger fires, water spray should be used.

Unsuitable media

High volume water jet

Specific hazards

Burning releases carbon monoxide, carbon dioxide, oxides of nitrogen, isocyanate vapors and traces of hydrogen cyanide. In the event of fire and/or explosion do not breathe fumes. Fire in vicinity poses risk of pressure build-up and rupture.

Instructions

Containers at risk from fire should be cooled with water and, if possible, removed from the danger area.

Firefighter Protection

During fire-fighting respirator with independent air-supply and airtight garment is required.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep unauthorized persons away.

Environmental

Do not flush into surface water or sanitary sewer system.

Cleanup methods

After approx. one hour transfer to waste container and do not seal (evolution of CO2!). Keep damp in a safe ventilated area for several days.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Provide sufficient air exchange and/or exhaust in work rooms. In all workplaces or parts of the plant where high concentrations of isocyanate aerosols and/or vapors may be generated (e.g. during pressure release, mold venting or when cleaning mixing heads with an air blast), appropriately located exhaust ventilation must be provided in order to prevent occupational exposure limits from being exceeded. The air should be drawn away from the personnel handling the product. The efficiency of the exhaust equipment should be periodically checked. The threshold limit values noted in Chapter 8 must be monitored. The personal protective measures described in Chapter 8 must be observed. Contact with skin and eyes and inhalation of vapors must be avoided under all circumstances.

Storage

Keep container tightly closed and dry. Prevent cooling below 10°C and heating above 40°C. Storage best at +15°C to +25°C.

Hygiene

Keep away from foodstuffs, drinks and tobacco. Wash hands before breaks and at the end of workday. Keep working clothes separately. Take off all contaminated clothing immediately. Decontaminate, destroy and dispose of soiled protective clothing (see Section 13).

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Respiratory protection required in insufficiently ventilated working areas.

Hands

Suitable materials for safety gloves; EN 374-3: Polychloroprene - CR: thickness >=0,50 mm; breakthrough time >= 480 min. Nitrile rubber- NBR: thickness >=0,35 mm; breakthrough time >= 480 min. Butyl rubber - IIR: thickness >=0,50 mm; breakthrough time >= 480 min. Fluorinated rubber - FKM: thickness >=0,40 mm; breakthrough time >= 480 min. Recommendation: contaminated gloves should be disposed of.

Eyes

Wear eye/face protection.

Respiratory

Respiratory protection required in insufficiently ventilated working areas and during spraying. An air-fed mask, or for short periods of work, a combination o f charcoal filter and particulate filter is recommended.

Skin/Body

Wear suitable protective clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
liquid
Colour
brown
Colour Intensity
---
Form
---
Odor
earthy, musty
Odor Threshold
---
Ph
---
Melting Point
---
Boiling Point
- 300 C DIN 51757
Flash Point
229 C DIN 51758
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
21 hPa at 20C EG A 4 20 hPa at 50C EG A 4 22 hPa at 55C EG A 4
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1,20 1,24 g/cm at 22C
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
- 500 C DIN 51794
Decomposition Temperature
---
Solubility
immiscible at 15C
Partition Coefficient
---
Solubility In Water
immiscible at 15C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
70 120 mPa.s at 25C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Polymerises at about 200 °C with evolution of CO2.

Hazardous reactions

Exothermic reaction with amines and alcohols; reacts with water forming CO2; in closed containers, risk of bursting owing to increase of pressure.

Incompatible

amines and alcohols

Decomposition

No hazardous decomposition products when stored and handled correctly.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12. Ecological information

Formaldehyde, oligomeric reaction products with aniline and phosgene EC50 > 1.000 mg/l Species: Daphnia magna (Water flea) Exposure duration: 24 h Method: OECD Test Guideline 202 Acute bacterial toxicity: diphenylmethane-diisocyanate, isomers and homologues EC50 > 100 mg/l Tested on: activated sludge Duration of test: 3 h Method: OECD Test Guideline 209 Formaldehyde, oligomeric reaction products with aniline and phosgene EC50 > 100 mg/l Tested on: activated sludge Duration of test: 3 h Method: OECD Test Guideline 209 Studies of a comparable product.

Persistence and degradability

Biodegradability: diphenylmethane-diisocyanate, isomers and homologues Biodegradation: 0 %, 28 d, i.e. not degradable Method: OECD Test Guideline 302 C Formaldehyde, oligomeric reaction products with aniline and phosgene Biodegradation: 0 %, 28 d, i.e. not degradable Method: OECD Test Guideline 302 C Studies of a comparable product.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

After final product withdrawal, all residues must be removed from containers (drip-free, powderfree or paste-free). Once the product residues adhering to the walls of the containers have been rendered harmless, the product and hazard labels must be invalidated.

Waste Codes

the appropriate code according to the European Waste Catalogue (EWC) should be used EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Any existing national regulations on the handling of isocyanates must be observed.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for WEVO – HARDENER 300?

The signal word is danger.

What is the physical form of WEVO – HARDENER 300?

WEVO – HARDENER 300 is a liquid appearing as liquid with brown color. It has earthy, musty odor.

What is the solubility of WEVO – HARDENER 300?

immiscible at 15C

What is WEVO – HARDENER 300 used for?

Hardener for polyurethanes

What are the hazard statements for WEVO – HARDENER 300?

This substance has 8 hazard statements:

  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction
  • H319: Causes serious eye irritation
  • H332: Harmful if inhaled
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled
  • H335: May cause respiratory irritation
  • H351: Suspected of causing cancer
  • H373: May cause damage to organs (Respiratory organs) through prolonged or repeated exposure if inhaled.