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Safety Data Sheet EN

2102 Hard Hat Adhesion Primer

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
2102 Hard Hat Adhesion Primer
Product Form
Aerosol

Regulatory Identifiers

CAS Number
N/A
UFI Code
HRH1-J09R-Q00J-M32Q

Manufacturers & Suppliers

R

RUST-OLEUM EUROPE (Martin Mathys NV)

manufacturer

Kolenbergstraat 23, B-3545 Zelem, Belgium

+32 (0) 13 460 200

T

Tor Coatings Limited

manufacturer

Unit 21, White Rose Way, Follingsby Park, Gateshead, Tyne & Wear, NE10 8YX United Kingdom

+44 (0) 191 4106611

Emergency Contacts

Poison centre

+32(0)70 245 245

Emergency Contact

+359 2 9154 409

Emergency Contact

+385 1 2348 342

Emergency Contact

1401

Toxikologické informační středisko

+420 224 919 293

Toxikologické informační středisko

+420 224 915 402

Giftlinien

82 12 12 12

open 24 hours a day

Emergency Contact

16662

Emergency Contact

0800 147 111

ORFILA (INRS)

+33 (0)1 45 42 59 59

24/7

Emergency Telephone Poison Center Nos. Children Aglaia Kyriakou

+30 210 7793777

Health Toxicology Information Service (ETTSZ)

(+ 36-80) 201-199

0-24 h

Emergency Contact

+354 5432222

Emergency Contact

809 2166

8am to 10pm 7 days per week

Emergency Contact

800183459

Toxicology and sepsis clinics Poisoning and Drug Information Center

+371 67042473

Poison Information Office

+370 (5) 2362052

24 hours a day

Poison centre

+32(0)70 245 245

Emergency Contact

112

Emergency Contact

088-755 8000

Emergency Contact

+47 22 59 13 00

Emergency Contact

112

24/7

Emergency Contact

800 250 250

Emergency Contact

+40 21 318 36 06

Monday - Friday between 8:00 -15:00, local hour

NATIONAL TOXICOLOGICAL INFORMATION CENTER

+421 2 5477 4166

Non-stop 24-hour

Emergency Contact

915 620 420

Poison Information Center

112

Swiss Toxicological Information Centre

145

24 h

Emergency Contact

809 2166

8am to 10pm 7 days per week

Emergency Contact

+43 13649237

24 / 7

Emergency Contact

+32 28083237

24 / 7

Emergency Contact

+359 32570104

24 / 7

Emergency Contact

+385 17776920

24 / 7

Emergency Contact

+420 228880039

24 / 7

Emergency Contact

+45 69918573

24 / 7

Emergency Contact

+372 6681294

24 / 7

Emergency Contact

+358 942419014

24 / 7

Emergency Contact

+33 975181407

24 / 7

Emergency Contact

+49 69643508409

24 / 7

Emergency Contact

0800-181-7059

24 / 7

Emergency Contact

+30 2111768478

24 / 7

Emergency Contact

+36 18088425

24 / 7

Emergency Contact

+354 539 0655

24 / 7

Emergency Contact

+353 19014670

24 / 7

Emergency Contact

+39 0245557031

24 / 7

Emergency Contact

800-789-767

24 / 7

Emergency Contact

+371 66165504

24 / 7

Emergency Contact

+370 52140238

24 / 7

Emergency Contact

352-20202416

24 / 7

Emergency Contact

+31 858880596

24 / 7

Emergency Contact

+48 223988029

24 / 7

Emergency Contact

+351 308801773

24 / 7

Emergency Contact

+40 37 6300026

24 / 7

Emergency Contact

+421 233057972

24 / 7

Emergency Contact

+38 618888016

24 / 7

Emergency Contact

+34 931768545

24 / 7

Emergency Contact

+46 852503403

24 / 7

Emergency Contact

+41 435082011

24 / 7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Aerosol Cat. 1 H222
Aerosol Cat. 1 H229
STOT SE Cat. 3 H336

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H222 Extremely flammable aerosol. Pressurised container: may burst if heated.
H336 May cause drowsiness or dizziness.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P271 Use only outdoors or in a well-ventilated area.
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
n-butyl acetate EC: 204-658-1 123-86-4 10 - 25% Yes
Ethylacetate EC: 205-500-4 141-78-6 8.7% Yes
xylene (mixture of isomeres) EC: 215-535-7 1330-20-7 1.2% Yes

Notes

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: respiratory tract irritation, coughing, nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness

Skin contact

Wash skin thoroughly with soap and water or use recognised skin cleanser. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: irritation, dryness, cracking

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Symptoms: irritation, redness

Ingestion

Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: No specific data.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable media

None known.

Specific hazards

Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material.

Materials: inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment. Pressurised container: protect from sunlight and do not expose to temperature exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.

Storage

Do not store above 35°C (95°F). Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Store locked up. Eliminate all ignition sources.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Eliminate all ignition sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. > 8 hours (breakthrough time): polyethylene (PE), polyvinyl alcohol (PVA). The recommendation for the type or types of glove to use when handling this product is based on information from the following source: EN374.

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Use eye protection according to EN 166. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Recommended: organic vapour filter (Type A) particulate filter (EN 140)

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods. Recommended: Personnel should wear antistatic clothing made of natural fibres or of high-temperature-resistant synthetic fibres. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid. [Aerosol.]
Physical State Data
aerosol
State Under Standard Conditions
---
Appearance
---
Colour
Blue.
Colour Intensity
---
Form
---
Odor
Solvent-like [Slight]
Odor Threshold
Not available.
Ph
Not applicable.
Melting Point
Not available.
Boiling Point
Not available.
Flash Point
-40°C
Freezing Point
Not available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
6,2 (Butyl acetate. = 1)
Evaporation Rate
6,2 (Butyl acetate. = 1)
Vapor Pressure
400 kPa
Vapor Density
>1 [Air = 1]
Relative Density
Not available.
Bulk Density
---
Density
0,88 to 0,98 g/cm³
Flammability
Highly flammable in the presence of the following materials or conditions: open flames, sparks and static discharge and heat. Slightly flammable in the presence of the following materials or conditions: shocks and mechanical impacts. In use, may form flammable/explosive vapour-air mixture. Vapour may travel a considerable distance to source of ignition and flash back.
Upper Explosive Limit
18%
Lower Explosive Limit
3%
Explosive Limits
---
Auto Ignition Temperature
350°C
Decomposition Temperature
>200°C
Solubility
cold water: Not soluble, hot water: Not soluble
Partition Coefficient
Not applicable.
Solubility In Water
Not available.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not available.
Kinematic Viscosity
Not available.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid all possible sources of ignition (spark or flame).

Incompatible

No specific data.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Waste Codes

20 01 27* paint, inks, adhesives and resins containing hazardous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1950
Shipping Name
AEROSOLS, flammable
Transport Class
2
IMDG

63, 190, 277, 327, 344, 381, 959

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This product contains substances for which Chemical Safety Assessments are still required.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 2102 Hard Hat Adhesion Primer?

The signal word is danger.

What is the physical form of 2102 Hard Hat Adhesion Primer?

2102 Hard Hat Adhesion Primer is a liquid. [aerosol.] with blue. color. It has solvent-like [slight] odor.

What is the solubility of 2102 Hard Hat Adhesion Primer?

cold water: Not soluble, hot water: Not soluble

What are the hazard statements for 2102 Hard Hat Adhesion Primer?

This substance has 2 hazard statements:

  • H222: Extremely flammable aerosol. Pressurised container: may burst if heated.
  • H336: May cause drowsiness or dizziness.

What is the melting point of 2102 Hard Hat Adhesion Primer?

The melting point is Not available. and the boiling point is Not available..