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Safety Data Sheet EN

3-Methylbutyraldehyde

CAS 590-86-3
EC 209-691-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
3-Methylbutyraldehyde
Product Code
163970000; 163970025; 163971000; 163975000
Chemical Name
3-Methylbutyraldehyde
Synonyms
Isovaleraldehyde

Regulatory Identifiers

CAS Number
590-86-3 Check regulations →
EC Number
209-691-5 Check regulations →
REACH No.
01-2119474890-30

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

F

Fisher Scientific UK

distributor

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

T

Thermo Fisher Scientific

distributor

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

Emergency Contacts

US information

001-800-227-6701

Europe information

+32 14 57 52 11

Emergency Number US

001-201-796-7100

Emergency Number Europe

+32 14 57 52 99

CHEMTREC US

001-800-424-9300

CHEMTREC Europe

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H225 Highly flammable liquid and vapor
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P280 Wear protective gloves/protective clothing/eye protection/face protection
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P312 Call a POISON CENTER or doctor if you feel unwell
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention
P337 + P313 If eye irritation persists: Get medical advice/attention

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Isopentaldehyde EC: 209-691-5 590-86-3 95% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Symptoms: headache, dizziness, tiredness, nausea and vomiting

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Symptoms: allergic skin reaction, rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Clean mouth with water and drink afterwards plenty of water.

Immediate Medical Attention

If symptoms persist or occur, get medical attention or call a physician.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

No information available.

Specific hazards

Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Ensure adequate ventilation. Use personal protective equipment as required. Remove all sources of ignition. Take precautionary measures against static discharges.

Environmental

Do not flush into surface water or sanitary sewer system.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

Storage

Keep refrigerated. Keep container tightly closed in a dry and well-ventilated place.

Hygiene

When using do not eat, drink or smoke. Provide regular cleaning of equipment, work area and clothing.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting equipment. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves Glove material Breakthrough time Glove thickness EU standard Glove comments Nitrile rubber See manufacturers - EN 374 - EN 374 (minimum requirement) Neoprene Natural rubber PVC See manufacturers recommendations Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced Recommended Filter type: Organic gases and vapours filter Type A Brown conforming to EN14387 Small scale/Laboratory use Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141 When RPE is used a face piece Fit Test should be conducted

Skin/Body

Long sleeved clothing.

Environmental

Do not allow material to contaminate ground water system. Prevent product from entering drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colorless, Light yellow
Colour
Colorless, Light yellow
Colour Intensity
---
Form
---
Odor
Stench
Odor Threshold
No data available
Ph
5.3
Melting Point
-28 C / -18.4 F
Boiling Point
91 - 93 C / 195.8 - 199.4 F @ 760 mmHg
Flash Point
-5 C / 23 F
Freezing Point
---
Softening Point
No data available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
57.9 mbar (20C)
Vapor Density
2.97 (Air = 1.0)
Relative Density
0.796
Bulk Density
Not applicable Liquid
Density
0.796
Flammability
Highly flammable On basis of test data
Upper Explosive Limit
5.6 Vol%
Lower Explosive Limit
1.4 Vol%
Explosive Limits
---
Auto Ignition Temperature
235 C / 455 F
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
Isopentaldehyde 1.5
Solubility In Water
Soluble
Solubility In Fat
---
Molecular Weight
86.13
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.6 mPa s at 20 C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Air sensitive.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. None under normal processing.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition. Exposure to air.

Incompatible

Strong oxidizing agents. Strong bases. Strong reducing agents.

Decomposition

Carbon monoxide (CO). Carbon dioxide (CO₂).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Ecotoxicity effects The product contains following substances which are hazardous for the environment. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Component | Freshwater Fish | Water Flea | Freshwater Algae --- | --- | --- | --- Isopentaldehyde | LC50 96h 53 mg/L (Leuciscus idus) | EC50: = 177 mg/L, 48h (Daphnia magna) | EC50: = 78 mg/L, 96h (Desmodesmus subspicatus) EC50: = 80 mg/L, 72h (Desmodesmus subspicatus)

12.2. Persistence and degradability

Resistence Degradation in sewage treatment plant Readily biodegradable Soluble in water, Persistence is unlikely, based on information available. Contains substances known to be hazardous to the environment or not degradable in waste water treatment plants.

The substance is described as readily biodegradable and soluble in water, with persistence being unlikely. However, it also contains substances known to be hazardous to the environment or not degradable in waste water treatment plants.

12.3. Bioaccumulative potential

Bioaccumulation is unlikely | Component | log Pow | Bioconcentration factor (BCF) | | --- | --- | --- | | Isopentaldehyde | 1.5 | No data available |

Bioaccumulation is unlikely

12.4. Mobility in soil

The product is water soluble, and may spread in water systems. Will likely be mobile in the environment due to its water solubility. Highly mobile in soils

The product is water soluble and highly mobile in soils, with potential to spread in water systems.

12.5. Results of PBT and vPvB assessment

No data available for assessment.

12.6. Endocrine disrupting properties

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors

The product does not contain any known or suspected endocrine disruptors.

12.7. Other adverse effects

Persistent Organic Pollutant Ozone Depletion Potential This product does not contain any known or suspected substance This product does not contain any known or suspected substance

The product does not contain any known or suspected persistent organic pollutants or ozone-depleting substances.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2058
Shipping Name
VALERALDEHYDE
Transport Class
3
Packing Group
II
ADR

No special precautions required.

IMDG

No special precautions required.

IATA

No special precautions required.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Safety Assessment Not performed

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. UK - Take note of Control of Substances Hazardous to Health Regulations (COSHH) 2002 and 2005 Amendment

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 3-Methylbutyraldehyde known by?

3-Methylbutyraldehyde is also known as: Isovaleraldehyde

What is the hazard signal word for 3-Methylbutyraldehyde?

The signal word is danger.

What is the physical form of 3-Methylbutyraldehyde?

3-Methylbutyraldehyde is a liquid appearing as colorless, light yellow with colorless, light yellow color. It has stench odor.

What is 3-Methylbutyraldehyde used for?

Laboratory chemicals.

What are the hazard statements for 3-Methylbutyraldehyde?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H317: May cause an allergic skin reaction
  • H319: Causes serious eye irritation
  • H335: May cause respiratory irritation
  • H411: Toxic to aquatic life with long lasting effects

What is the melting point of 3-Methylbutyraldehyde?

The melting point is -28 C / -18.4 F and the boiling point is 91 - 93 C / 195.8 - 199.4 F @ 760 mmHg.