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Safety Data Sheet EN

Eni i-Sigma top MS 10W-30

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Eni i-Sigma top MS 10W-30
Product Form
Mixture
Product Code
1067

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Lubricant for internal combustion engines

Uses advised against

Recommended use are listed above; other uses are not recommended unless an assessment has provided that risks are controlled.

Manufacturers & Suppliers

E

Enilive S.p.A

manufacturer

Viale Giorgio Ribotta 51 - 00144 Rome Italy

(+39) 06 59821

Emergency Contacts

CNIT

+39 0382 24444

24h

IT, EN

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Aquatic Chronic Cat. 3 H412

GHS Pictograms

Hazard Statements

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P273 Avoid release to the environment.
P501 Dispose of contents/container to according to national or local regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Mixture of hydrocarbons Additives

Chemical Name CAS Number Concentration Hazardous
destillaten (aardolie), met waterstof behandelde zware paraffinehoudende. Basisolie - niet gespecifieerd EC: 265-157-1 64742-54-7 50 - 70% No
destillaten (aardolie), met waterstof behandelde zware paraffinehoudende. Basisolie - niet gespecifieerd EC: 265-157-1 64742-54-7 10 - 20% Yes
Mineral base oil, severely refined (For identification of the substance, see note [*], see note [***]) --- 2 - 7% Yes
Phosphordithiosure, gemischte O, O-Bis (1,3-dimethylbutyl- und Iso-Pr) ester, Zinksalze EC: 283-392-8 84605-29-8 0.5 - 1.5% Yes
Dodecylphenol, mixed isomers (branched) EC: 310-154-3 121158-58-5 0.001 - 0.036% Yes

Notes

Comments : Composition/information on ingredients. [*] Note: this product may be formulated with one or more of the following severely refined mineral base oils (not classified as hazardous): CAS 64742-54-7/EC 265-157-1/REACH Reg. # 01-2119484627-25-xxxx; CAS 64742-65-0/EC 265-169-7/REACH Reg. # 01-2119471299-27-xxxx; CAS 64742-55-8/EC 265-158-7/REACH Reg. # 01-2119487077-29-xxxx; CAS 64742-56-9/EC 265-159-2/ REACH Reg. # 01-2119480132-48-xxxx. All these substances have a value < 3 % wt of DMSO extract, according to IP 346 (Nota L Annex VI Reg (CE) 1272/2008, # 1.1.3). Note [**]: this product has a value of DMSO extract < 3 % wt, according to IP 346. According to the criteria laid out by the EU (note L, Annex VI of Regulation (CE) 1272/2008), this product must be regarded as non carcinogenic. Note [***]: substance with occupational exposure limits for some EU countries affecting the category of mineral oils (finely refined mineral base oil mists; see section 8.1). Specific concentration limits for Phosphorodithioic acid, mixed O,O-bis(1,3dimethylbutyl and iso-Pr)esters, zinc salts: (6.25 C < 100) Skin Irrit. 2, H315; (10 < C 12.5) Eye Irrit. 2, H319; (12.5 < C 100) Eye Dam. 1, H318.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

In case of disturbances owing to inhalation of vapours or mists, remove the victim from exposure; keep at rest; if necessary, seek medical attention.

Symptoms: Irritation to airways, nausea and dizziness.

Skin contact

Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs, get medical advice/attention. In case of burns, cool affected part with cold running water for at least 10 min. Cover with gauze or clean cloth. Ask for medical assistance or bring to a hospital. Do not apply salves or other substances, unless by doctor's advice. Do not put ice on the burn.

Symptoms: Prolonged and repeated skin contact may cause reddening, irritation and dermatitis. May produce an allergic reaction. Contact with hot product may cause thermal burns.

Eye contact

Rinse eyes thoroughly for at least 15 minutes. Keep eyelids well apart. If irritation, blurred vision or swelling occurs and persists, obtain medical advice from a specialist. In case of burns, cool affected part with cold running water for at least 10 min. Cover with gauze or clean cloth. Ask for medical assistance or bring to a hospital. Do not apply salves or other substances, unless by doctor's advice.

Symptoms: Contact with eyes may cause temporary reddening and irritation. Contact with hot product or vapours may cause burns.

Ingestion

Do not induce vomiting. If the person is conscious, rinse mouth with water without swallowing. Keep at rest. Call for medical assistance or bring to an hospital. If the casualty is unconscious, place in the recovery position. In case of spontaneous vomiting, keep head low, to avoid the risk of aspiration into the lungs. Do not give anything by mouth to an unconscious person.

Symptoms: Nausea, discomfort and gastric disturbances.

Immediate Medical Attention

Obtain medical attention if casualty has an altered state of consciousness or if symptoms do not resolve. Seek medical attention in all cases of serious burns. If there is any suspicion of inhalation of H2S (hydrogen sulphide), Rescuers must wear breathing apparatus, belt and safety rope, and follow rescue procedures. Send patient to hospital. Immediately begin artificial respiration if breathing has ceased. Administer oxygen if necessary.

Medical Treatment

Immediately begin artificial respiration if breathing has ceased. Administer oxygen if necessary. Send patient to hospital.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure that there is a suitable ventilation system. Before entering storage tanks and commencing any operation in a confined area (e.g. tunnels), check the atmosphere for oxygen content, presence of hydrogen sulphide (H2S) and SOx, and flammability.

Hands

When there is a risk of contact with the skin, use waterproof gloves, resistant to chemical products. Gloves must be felt-lined. Adequate materials: nitrile (NBR) or PVC with a protection index > 5 (permeation time > 240 mins). Use gloves respecting all the conditions and within the limits set by the manufacturer. Replace gloves immediately in case of cuts, holes or other signs of damages or degradation. If necessary, refer to the EN 374 standard.

Eyes

When there is a risk of contact with the eyes, use safety goggles or other means of protection (face shield). If necessary, refer to national standards or to the EN 166 standard.

Respiratory

Independently from other possible actions (technical modifications, operating procedures, and other means to limit the exposure of workers), personal protection equipment can be used according to necessity. Open or well ventilated spaces: in presence of oil mists and if the product is handled without adequate containment means: use full or half-face masks with filter for mists/aerosols (P). In case there is a significant presence of vapours (e.g. through handling at high temperature), use full or half-face masks with a filter for organic vapours (A), and H2S (B) where applicable. (EN 136/140/145). Combined gas/dust mask with filter type: EN 14387. Closed or confined areas (e.g. tank interiors): the use of protection measures for airways (masks or self-contained breathing apparatus), must be assessed according to the specific activity, as well as level and duration of predicted exposure. Approved respiratory protection equipment shall be used in spaces where hydrogen sulphide may accumulate: full face mask with cartridge/filter type B (grey for inorganic vapours including H2S) or self-contained breathing apparatus (SCBA). (EN 136/140/145)

Skin/Body

Long-sleeved overalls. If necessary, refer to the EN 340 and related standards, for definition of characteristics and performance according to the risk rating of the area. Antistatic non-skid safety shoes or boots, chemical resistant, if necessary heat resistant and insulated.

Environmental

Do not discharge the product into the environment. Prevent discharge of undissolved substance to or recover from onsite wastewater. Storage areas/installations should be designed with adequate bunds so as to prevent ground and water pollution in case of leaks or spills. Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or reclaimed.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Molecular Weight
---
Lower Explosive Limit
Not determined
Flammability
Not flammable
Appearance
Clear liquid.
Crystallisation Point
---
Solidification Point
---
Physical State
Liquid
Kinematic Viscosity
78.7 mm/s (40 C) (ASTM D 445)
Dynamic Viscosity
Not determined
Vapor Pressure
0.1 hPa (20 C) (Mineral oil, ASTM D 5191) (CONCAWE, 2010)
Colour Intensity
---
Colour
Yellow-brown.
Bulk Density
---
Vapor Density
---
State Under Standard Conditions
---
Form
---
Density
Not determined
Freezing Point
Not determined
Metal Corrosion
---
Odor
Slight odour of petroleum.
Boiling Point
- 315 C (CAS 64742-54-7)
Solubility
Water: Immiscible and insoluble
Explosive Limits
---
Softening Point
---
Cloud Point
---
Relative Evaporation Rate
Negligible.
Ph
Not determined
Relative Density
Not determined
Voc Content
---
Partition Coefficient
Not applicable for mixtures
Odor Threshold
Not determined
Auto Ignition Temperature
250 370 C (CAS 64742-54-7)
Decomposition Temperature
Not determined
Evaporation Rate
---
Properties Status
---
Upper Explosive Limit
Not determined
Solubility In Fat
---
Physical State Data
liquid
Flash Point
- 220 C (ASTM D 92)
Solubility In Water
Immiscible and insoluble
Melting Point
Not determined
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
Not regulated for transport
Shipping Name
Not regulated.
Transport Class
Not regulated.
Packing Group
Not regulated.
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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Eni i-Sigma top MS 10W-30?

The signal word is no signal word.

What is the physical form of Eni i-Sigma top MS 10W-30?

Eni i-Sigma top MS 10W-30 is a liquid appearing as clear liquid. with yellow-brown. color. It has slight odour of petroleum. odor.

What is the solubility of Eni i-Sigma top MS 10W-30?

Water: Immiscible and insoluble

What is Eni i-Sigma top MS 10W-30 used for?

Lubricant for internal combustion engines

What are the hazard statements for Eni i-Sigma top MS 10W-30?

This substance has 1 hazard statement:

  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of Eni i-Sigma top MS 10W-30?

The melting point is Not determined and the boiling point is - 315 C (CAS 64742-54-7).

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