Eni CLADIUM 50 (SAE 30)

Remove to fresh air, keep the casualty warm and at rest. If breathing is difficult, give oxygen if possible, or assisted ventilation. If necessary, give external cardiac massage and obtain medical advice. See also section 4.3.

Symptoms: Inhalation of fumes or oil mists produced at high temperatures may cause irritation of the respiratory tract. Symptoms of overexposure to vapours include drowsiness, weakness, headache, dizziness, nausea, vomiting, dimming of vision.

Remove contaminated clothing and shoes. Wash skin with soap and water. If skin irritation occurs: Get medical advice/attention. In case of contact with hot product, cool affected part with plenty of cold water, and cover with gauze or clean cloth. Call a doctor or bring to an hospital. Do not use salves or ointments, unless directed by doctor.

Symptoms: Prolonged and repeated skin contact may cause reddening, irritation and dermatitis, due to a defatting effect. May cause an allergic skin reaction. Contact with hot product may cause thermal burns.

Remove contact lenses, if present and easy to do so. Rinse eyes thoroughly for at least 15 minutes. Keep eyelids well apart. If irritation, blurred vision or swelling occurs and persists, obtain medical advice from a specialist. In case of contact with hot product, cool affected part with plenty of cold water, and cover with gauze or clean cloth. Call a doctor or bring to an hospital. Do not use salves or ointments, unless directed by doctor.

Symptoms: Contact with eyes may cause temporary reddening and irritation. Contact with hot product or vapours may cause burns.

Rinse mouth thoroughly with water. Give water to drink if victim completely conscious/alert. Do not induce vomiting.

Symptoms: Accidental ingestion of small quantities of the product may cause nausea, discomfort and gastric disturbances.

Small-size fires: carbon dioxide, dry chemicals, foam, sand or earth. Large fires: foam or water fog (mist). These means should be used by trained personnel only. Other extinguishing gases (according to regulations).

Do not use water jets. They could cause splattering, and spread the fire. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.

Fire hazard: This product is combustible, but not classified as Flammable. The creation of flammable vapour mixtures takes place at temperatures which are higher than normal ambient levels. Explosion hazard: In case of losses from pressurized circuits, the sprays may form mists. Take into account that in this case the lower explosion limit for mists is about 45 g/m3 of air. Vapours are heavier than air, spread along floors and form explosive mixtures with air.

Shut off source of product, if possible. Move undamaged containers from immediate hazard area if it can be done safely. Spilled product which is not burning should be covered with sand or foam. Use water sprays to cool containers and surfaces exposed to the flames. If the fire cannot be controlled, evacuate area.

General measures: Stop or contain leak at the source, if safe to do so. Eliminate all ignition sources if safe to do so (e.g. electricity, sparks, fires, flares). Avoid accidental sprays on hot surfaces or electrical contacts. Avoid direct contact with released material. Keep upwind. For non-emergency personnel: Keep non-involved personnel away from the area of spillage. Alert emergency personnel. Except in case of small spillages, the feasibility of any actions should always be assessed and advised, if possible, by a trained, competent person in charge of managing the emergency. For emergency responders: Notify local authorities according to relevant regulations.

Do not let the product accumulate in confined or underground spaces. Do not let the product flow into sewers or water courses, or in any way contaminate the environment. In case of contamination of environment compartments (soil, subsoil, surface or underground waters), remove contaminated soil when possible, and in any case treat all involved compartments in accordance with local regulations. The site should have a spill plan to ensure that adequate safeguards are in place to minimize the impact of episodic releases.

Transfer recovered product and other materials to suitable tanks or containers and store/dispose according to relevant regulations. Clean contaminated area.

Materials: sand, earth or other suitable absorbents (non-flammable). suitable waterproof and oil-resistant containers.

This material is combustible, but will not ignite readily. Due to the extremely slippery nature of this material, more care than usual must be exercised in material handling practices to keep off all walking surfaces. Emptied containers can contain combustible product residues. Do not cut, weld, drill, burn or incinerate empty containers or drums, unless they have been drained and cleaned. The product may release Hydrogen Sulphide: a specific assessment of inhalation risks from the presence of hydrogen sulphide in tank headspaces, confined spaces, product residue, tank waste and waste water, and unintentional releases should be made to help determine controls appropriate to local circumstances. See also Section 16, "Other information".

Store in dry, well ventilated area. Keep away from open flames, hot surfaces and sources of ignition. Do not smoke. Keep containers tightly closed and properly labelled. Keep only in the original container or in a suitable container for this kind of product.

Ensure that proper housekeeping measures are in place. Avoid contact with skin. Do not breathe fume/ mist/ vapours. Do not ingest. Do not smoke. Do not eat and do not drink during use. Do not clean hands with dirty or oil-soaked rags. Do not re-use clothes, if they are still contaminated. Keep away from food and beverages. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Contaminated work clothing should not be allowed out of the workplace. Separate working clothes from town clothes. Launder separately.

This material is combustible, but will not ignite readily. Keep away from open flames, hot surfaces and sources of ignition. Do not smoke. Emptied containers can contain combustible product residues. Do not cut, weld, drill, burn or incinerate empty containers or drums, unless they have been drained and cleaned.

Ensure good ventilation of the work station. Before entering storage tanks and commencing any operation in a confined area (e.g. tunnels), check the atmosphere for oxygen content, presence of hydrogen sulphide (H2S) and SOx, and flammability. See also Section 16, "Other information".

When there is a risk of contact with the skin, use hydrocarbon-resistant, felt-lined gloves. Adequate materials: nitrile (NBR) or PVC with a protection index > 5 (permeation time > 240 mins). Use gloves respecting all the conditions and within the limits set by the manufacturer. Replace gloves immediately in case of cuts, holes or other signs of damages or degradation. If necessary, refer to the EN 374 standard. Personal hygiene is a key element for an effective hand care. Gloves must be worn only with clean hands. After wearing gloves, hands must be carefully washed and dried.

When there is a risk of contact with the eyes, use safety goggles or other means of protection (face shield). If necessary, refer to national standards or to the EN 166 standard.

Independently from other possible actions (technical modifications, operating procedures, and other means to limit the exposure of workers), personal protection equipment can be used according to necessity. Open or well ventilated spaces: if the product is handled without adequate containment: use full or half-face masks with adequate filter for organic vapours. (EN 136/140/145). Combination filter device (DIN EN 141). Closed or confined areas (e.g. tank interiors): the use of protection measures for airways (masks or self-contained breathing apparatus), must be assessed according to the specific activity, as well as level and duration of predicted exposure. (EN 136/140/145). Approved respiratory protection equipment shall be used in spaces where hydrogen sulphide may accumulate: full face mask with cartridge/filter type “B” (grey for inorganic vapours including H2S) or self-contained breathing apparatus (SCBA). (EN 136/140/145)

Long-sleeved overalls. If necessary, refer to the EN 340 and related standards, for definition of characteristics and performance according to the risk rating of the area. Antistatic non-skid safety shoes or boots, chemical resistant, if necessary heat resistant and insulated.

Do not discharge the product into the environment. Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or reclaimed. Prevent discharge of undissolved substance to or recover from onsite wastewater. Storage areas/installations should be designed with adequate bunds so as to prevent ground and water pollution in case of leaks or spills.

Stable product, according to its intrinsic properties (in normal conditions of storage and handling).

This mixture does not offer any further hazard for reactivity, except what is reported in the following paragraphs.

None (in normal conditions of storage and handling). Contact with strong oxidizers (peroxides, chromates, etc.) may cause a fire hazard. Sensitivity to heat, friction or shock cannot be assessed in advance.

Keep away from open flames, hot surfaces and sources of ignition.

Strong oxidants.

Under normal conditions of storage and use, hazardous decomposition products should not be produced. Thermal decomposition may produce : Carbon dioxide, Carbon monoxide. In exceptional cases (i.e prolonged storage in tanks contaminated with water, and presence of anaerobic sulfate-reducing microbial colonies), the product may undergo a degradation and generate small amounts of sulfur compounds, including H2S. See also Section 16, "Other information".