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Safety Data Sheet EN

Sodium hydrogen sulfate monohydrate extra pure

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Sodium hydrogen sulfate monohydrate extra pure
Product Code
106350

Regulatory Identifiers

CAS Number
N/A
REACH No.
A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) No 1907/2006, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Materials for use in technical applications For additional information on uses please refer to the Merck Chemicals portal (www.merck-chemicals.com).

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

64271 Darmstadt, Germany

+49 6151 72-0

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H318 Causes serious eye damage.

Precautionary Statements

P280 Wear eye protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P313 Get medical advice/ attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Formula NaHSO * HO HNaOS * HO (Hill)

Chemical Name CAS Number Concentration Hazardous
sodium hydrogensulphate monohydrate EC: 231-665-7 10034-88-5 100% Yes

Notes

A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) No 1907/2006, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air.

Skin contact

wash off with plenty of water. Remove contaminated clothing.

Eye contact

rinse out with plenty of water. Immediately call in ophthalmologist.

Symptoms: Risk of blindness!

Ingestion

immediately make victim drink water (two glasses at most). Consult a physician.

Immediate Medical Attention

Immediately call in ophthalmologist. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

Foam, Water

Specific hazards

Not combustible. Ambient fire may liberate hazardous vapours. Fire may cause evolution of: Sulphur oxides. May not get in touch with: Water. The product reacts with water and generates heat.

Instructions

Suppress (knock down) gases/vapours/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid substance contact. Avoid inhalation of dusts. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not empty into drains.

Cleanup methods

Take up dry. Dispose of properly. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Observe label precautions. Keep workplace dry. Do not allow product to come into contact with water.

Storage

Tightly closed. Dry. Storage temperature: no restrictions.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, Break through time: > 480 min; splash contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, Break through time: > 480 min; The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 741 Dermatril® L (full contact), KCL 741 Dermatril® L (splash contact).

Eyes

Tightly fitting safety goggles

Respiratory

required when dusts are generated. Recommended Filter type: Filter P 2 (acc. to DIN 3181) for solid and liquid particles of harmful substances. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not empty into drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solidification Point
---
Lower Explosive Limit
not applicable
Voc Content
---
State Under Standard Conditions
---
Crystallisation Point
---
Auto Ignition Temperature
No information available.
Boiling Point
not applicable
Partition Coefficient
not applicable
Physical State Data
solid
Vapor Density
---
Ph
ca. 1 at 50 g/l 20 °C
Colour Intensity
---
Metal Corrosion
---
Molecular Weight
---
Colour
off-white
Melting Point
183 °C (decomposition)
Softening Point
---
Cloud Point
---
Solubility
---
Flammability
The product is not flammable.
Relative Density
No information available.
Form
solid
Solubility In Water
ca.1.080 g/l at 20 °C
Decomposition Temperature
> 183 °C
Flash Point
does not flash
Appearance
---
Properties Status
---
Evaporation Rate
No information available.
Odor
odourless
Solubility In Fat
---
Dynamic Viscosity
No information available.
Relative Evaporation Rate
---
Density
---
Upper Explosive Limit
not applicable
Freezing Point
---
Odor Threshold
not applicable
Explosive Limits
---
Physical State
solid
Bulk Density
900 - 970 kg/m³
Vapor Pressure
No information available.
Kinematic Viscosity
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

sensitive to moisture, releases water of crystallisation when heated.

Reactivity

See section 10.3

Hazardous reactions

Exothermic reaction with: Water, Strong oxidizing agents, Strong bases, Alcohols

Avoid

Strong heating (decomposition).

Incompatible

Metals

Decomposition

in the event of fire: See section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Sodium hydrogen sulfate monohydrate extra pure?

The signal word is danger.

What is the physical form of Sodium hydrogen sulfate monohydrate extra pure?

Sodium hydrogen sulfate monohydrate extra pure is a solid with off-white color. It has odourless odor.

What is Sodium hydrogen sulfate monohydrate extra pure used for?

Materials for use in technical applications For additional information on uses please refer to the Merck Chemicals portal (www.merck-chemicals.com).

What are the hazard statements for Sodium hydrogen sulfate monohydrate extra pure?

This substance has 1 hazard statement:

  • H318: Causes serious eye damage.

What is the melting point of Sodium hydrogen sulfate monohydrate extra pure?

The melting point is 183 °C (decomposition) and the boiling point is not applicable.