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Safety Data Sheet EN

Ammonium Hydroxide, ACS

CAS 1336-21-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ammonium Hydroxide, ACS
Product Form
Substance
Product Code
LC11050
Chemical Name
Ammonium Hydroxide, ACS
Synonyms
ammonia hydrate, 28%-30% / ammonia,liquor,25%<=conc<35% / ammonia, solutions, 28%-30% / ammoniawater, 28%-30% / aqua ammonia, solution, 28%-30% / spirit of hartshorn, 28%-30%

Regulatory Identifiers

CAS Number
1336-21-6 Check regulations →

Identified Uses

Chemical raw material Food industry: additive Solvent

Manufacturers & Suppliers

LabChem Inc logo

LabChem Inc

manufacturer

Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA

412-826-5230

http://www.labchem.com

Emergency Contacts

CHEMTREC

1-800-424-9300

CHEMTREC

011-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H332
Skin Corr. Cat. 1C H314
Eye Dam. Cat. 1 H318
Aquatic Acute Cat. 1 H400

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 + H332 Harmful if swallowed or if inhaled
H314 Causes severe skin burns and eye damage
H400 Very toxic to aquatic life

Precautionary Statements

P260 Do not breathe mist, spray, vapors.
P264 Wash exposed skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear eye protection, face protection, protective clothing, protective gloves.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a poison center or doctor/physician.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container to comply with local, state and federal regulations

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Water 7732-18-5 72% No
Ammonia 7664-41-7 28% Yes

Notes

Full text of hazard classes and H-statements : see section 16

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.

Symptoms: Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. Nausea. Headache. EXPOSURE TO HIGH CONCENTRATIONS: Possible oedema of the upper respiratory tract. Possible inflammation of the respiratory tract. Possible laryngeal spasm/oedema.

Skin contact

Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing agents. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take victim to hospital.

Symptoms: Caustic burns/corrosion of the skin.

Eye contact

Rinse immediately with plenty of water for 15 minutes. Cover eyes aseptically. Do not apply neutralizing agents. Take victim to an ophthalmologist.

Symptoms: Irritation of the eye tissue. Permanent eye damage.

Ingestion

Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Immediately consult a doctor/medical service. Call Poison Information Centre (www.big.be/antigif.htm). Take the container/vomit to the doctor/hospital. Ingestion of large quantities: immediately to hospital.

Symptoms: Risk of aspiration pneumonia. Nausea. Vomiting. AFTER ABSORPTION OF LARGE QUANTITIES: Blue/grey discoloration of the skin. Blood in stool. Blood in vomit. Possible esophageal perforation.

Immediate Medical Attention

Depending on the victim's condition: doctor/hospital. Respiratory problems: consult a doctor/medical service. Consult a doctor/medical service. If burned surface > 10%: take victim to hospital. Take victim to an ophthalmologist. Immediately consult a doctor/medical service. Ingestion of large quantities: immediately to hospital.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Adapt extinguishing media to the environment.

Unsuitable media

No unsuitable extinguishing media known.

Specific hazards

DIRECT FIRE HAZARD. Non combustible. INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard".

Instructions

Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to heat. Dilute toxic gases with water spray. Take account of toxic fire-fighting water. Use water moderately and if possible collect or contain it.

Firefighter Protection

Do not enter fire area without proper protective equipment, including respiratory protection.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep upwind. Mark the danger area. Consider evacuation. Close doors and windows of adjacent premises. No naked flames. Keep containers closed. Wash contaminated clothes. Stop leak if safe to do so. Ventilate area.

Environmental

Prevent soil and water pollution.

Cleanup methods

Damaged/cooled tanks must be emptied. Take up liquid spill into absorbent material, e.g.: sand/earth or powdered limestone. Scoop absorbed substance into closing containers. Carefully collect the spill/leftovers. Take collected spill to manufacturer/competent authority. Clean contaminated surfaces with an excess of water. Wash clothing and equipment after handling.

Materials: sand/earth or powdered limestone

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Comply with the legal requirements. Remove contaminated clothing immediately. Clean contaminated clothing. Use corrosionproof equipment. Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Keep away from naked flames/heat. Observe strict hygiene. Keep container tightly closed. Measure the concentration in the air regularly. Carry operations in the open/under local exhaust/ventilation or with respiratory protection. Exhaust gas must be neutralised.

Storage

Keep container tightly closed.

Hygiene

Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse. Observe strict hygiene.

Fire prevention

Keep away from naked flames/heat.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide adequate general and local exhaust ventilation.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid.
Colour
Colourless
Colour Intensity
---
Form
---
Odor
Irritating/pungent odour
Odor Threshold
5 - 50 ppm
Ph
11.7 (3.5 %)
Melting Point
No data available
Boiling Point
27 °C
Flash Point
Not applicable
Freezing Point
No data available
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
No data available
Evaporation Rate
No data available
Vapor Pressure
No data available
Vapor Density
---
Relative Density
0.88 - 0.91
Bulk Density
---
Density
0.89
Flammability
Non flammable.
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
Not applicable
Decomposition Temperature
No data available
Solubility
Water: Complete
Partition Coefficient
-1.3
Solubility In Water
Complete
Solubility In Fat
---
Molecular Weight
35.05 g/mol
Voc Content
Not applicable
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

On heating: release of toxic/corrosive/combustible gases/vapours (ammonia). On burning: release of toxic and corrosive gases/vapours (nitrous vapours). Concentrated solution violent to explosive reaction with many compounds e.g.: with (some) halogens compounds, with (strong) oxidizers and with (some) acids.

Hazardous reactions

Reacts vigorously with strong oxidizers and acids.

Avoid

High temperature. Incompatible materials. Direct sunlight. Extremely high or low temperatures.

Incompatible

May react violently with acids. Strong acids. Strong bases.

Decomposition

Gaseous ammonia, fume. Carbon monoxide. Carbon dioxide.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Ecology - general : Dangerous for the environment. Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Ecology - water : Water pollutant (surface water). Affects the self-cleaning capacity of surface water. Ground water pollutant. Maximum concentration in drinking water: 0.50 mg/l (ammonium) (Directive 98/83/EC). Highly toxic to fishes. Toxic to invertebrates (Daphnia). May cause eutrophication. Highly toxic to plankton. pH shift. Inhibition of activated sludge.

The substance is classified as dangerous for the environment and is a water pollutant. It is highly toxic to fish and plankton, toxic to invertebrates, and can cause eutrophication and inhibit activated sludge.

12.1. Toxicity

Ammonium Hydroxide, ACS (1336-21-6) | LC50 fish 1 | 0.16 - 1.1 mg/l (LC50; 96 h) | EC50 Daphnia 1 | 2.08 mg/l (LC50; 48 h)

12.2. Persistence and degradability

12.2. Persistence and degradability

Readily biodegradable in water. Ozonation in water. Biodegradable in the soil. No test data on mobility of the components available. Ozonation in the air.

The substance is readily biodegradable in water and soil, and undergoes ozonation in water and air.

12.2. Persistence and degradability

Not established.

Not established.

12.2. Persistence and degradability

Not established.

Not established.

12.3. Bioaccumulative potential

12.3. Bioaccumulative potential

| Ammonium Hydroxide, ACS (1336-21-6) | | | --- | --- | | Log Pow | -1.3 | | Bioaccumulative potential | Bioaccumulation: not applicable. |

12.3. Bioaccumulative potential

| Water (7732-18-5) | | Bioaccumulative potential | Not established. |

Not established.

12.3. Bioaccumulative potential

| Ammonia (7664-41-7) | | Bioaccumulative potential | Not established. |

Not established.

12.5. Other adverse effects

Other information : Avoid release to the environment.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Remove for physico-chemical/biological treatment. Remove to an authorized incinerator equipped with an afterburner and a flue gas scrubber with energy recovery.

Disposal

Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. Recycle/reuse.

Waste Codes

KGA category 02 KGA category 02 national code
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2672
Shipping Name
Ammonia solutions
Transport Class
8
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Ammonium Hydroxide, ACS known by?

Ammonium Hydroxide, ACS is also known as: ammonia hydrate, 28%-30% / ammonia,liquor,25%<=conc<35% / ammonia, solutions, 28%-30% / ammoniawater, 28%-30% / aqua ammonia, solution, 28%-30% / spirit of hartshorn, 28%-30%

What is the hazard signal word for Ammonium Hydroxide, ACS?

The signal word is danger.

What is the physical form of Ammonium Hydroxide, ACS?

Ammonium Hydroxide, ACS is a liquid appearing as liquid. with colourless color. It has irritating/pungent odour odor.

What is the solubility of Ammonium Hydroxide, ACS?

Water: Complete

What is Ammonium Hydroxide, ACS used for?

Chemical raw material Food industry: additive Solvent

What are the hazard statements for Ammonium Hydroxide, ACS?

This substance has 3 hazard statements:

  • H302 + H332: Harmful if swallowed or if inhaled
  • H314: Causes severe skin burns and eye damage
  • H400: Very toxic to aquatic life

What is the melting point of Ammonium Hydroxide, ACS?

The melting point is No data available and the boiling point is 27 °C.