C7 + GASOLINE

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not leave the victim unattended. Get medical attention immediately. Keep patient warm and at rest. If breathing is difficult, give oxygen. If unconscious place in recovery position. In the event of unconsciousness, apnea or cardiac arrest (no pulse) apply cardiopulmonary resuscitation.

Symptoms: Inhalation of vapors may cause signs of respiratory tract irritation (cough and difficulty breathing), CNS depression (fatigue, dizziness, headache, collapse, coma and death), possible cardiac sensitization, and irritation of the eyes, nose and throat.

Take off contaminated clothing and wash it before reuse. After contact with skin, wash immediately with plenty of soap and water. In case of skin contact, consider inhalation as route of entry at the same time. Never use low boiling point naphthas for washing contaminated skin. Do not wash with machine dishwashing or laundry detergents. Get medical attention immediately.

Symptoms: Causes skin irritation. Repeated or prolonged contact with the skin may cause defatting dermatitis.

In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Do not use eye ointment unless directed to by a physician. Get medical attention immediately.

Symptoms: May cause minor eye irritation.

DO NOT induce vomiting. If vomiting does occur, have victim lean forward to reduce risk of aspiration. Get medical attention immediately. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person.

Symptoms: Aspiration into the lungs during swallowing or vomiting can cause lung damage, possibly leading to chronic lung dysfunction or death.

SMALL FIRE: Dry chemical. CO2. Water spray. Foam. Sand. LARGE FIRES: Water spray. Water fog. Foam. Dry chemical. CO2. Sand.

Do not use solid water stream/may spread fire. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.

When exposed to ignition source in air, vapors can burn in open or explode if confined. Flammable vapors may be heavier than air and travel long distances along the ground before igniting and flashing back to vapor source. Releases flammable vapors below normal ambient temperatures. Sustained fire attack on vessels may result in a Boiling Liquid Expanding Vapour Explosion (BLEVE).

Move containers from fire area if you can do it without risk. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. Always stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

Stop leak if you can do it without risk. Do not touch or walk through spilled material.

Prevent entry into waterways, sewers, basements or confined areas.

Restrict water use for cleanup. DO NOT use water jet. The use of dispersants should be advised by an expert, and, if required, approved by local authorities. Water spray may reduce vapor; but may not prevent ignition in closed spaces. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.

Materials: dry earth, sand or other non-combustible material

Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Containers must be properly grounded before beginning transfer. Use only non-sparking tools. Check atmosphere for explosiveness and oxygen deficiencies. Carefully vent any internal pressure before removing closure. Observe precautions pertaining to confined space entry. Do not use compressed air for filling, discharging or handling. Handle empty containers with care; vapor residue may be flammable/explosive. Decontaminate containers thoroughly before reuse/disposal. Isolate, vent, drain, wash and purge systems or equipment before maintenance or repair. Do not pressurize, cut, weld, braze solder, drill, or grind on containers. Use only bottom loading of tankers, in compliance with European regulations.

Store only in tightly closed, properly vented containers away from heat, sparks, open flame and strong oxidizing agents. Store closed drums with bung in up position. Vapor space above stored liquid may be flammable/explosive unless blanketed with inert gas. Keep container tightly closed and properly labeled.

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges.

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits.

Wear chemical resistant gloves such as: Glove material fluoroelastomer; material thickness 0.4 mm; break through time ≥ 480 min. Gloves must be replaced after 8 hours of wear. The selected protective gloves have to satisfy the standard EN 374 derived from it. The suitability for a specific workplace should be discussed with the producers of the protective gloves. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Safety glasses with side-shields Eye protection such as chemical splash goggles and/or face shield must be worn when possibility exists for eye contact due to splashing or spraying liquid. The selected goggles or glasses must satisfy the European norm standard EN 166.

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. The type of respiratory protection will depend upon whether the maximum exposure concentration is known. If needed, wear a supplied air respirator conforming to a European norm standard such as EN 139 or equivalent. Wear a respirator conforming to EN 140 with type A filter or better. Consider the maximum period for wear.

When skin contact is possible, protective clothing including gloves, apron, sleeves, boots, head and face protection should be worn. The selected protective clothing has to satisfy the standard EN 13034, which describes clothing offering limited 8 hour protection against splashes. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Use PPE that is chemical resistant to the product and prevents skin contact. Fire retardant clothing is appropriate for routine occupational use.

General advice : See section 6. Soil : Waste management practices such as incineration, recycling, reuse must be enforced as needed to reduce exposures to an acceptable level. External treatment and disposal of waste should comply with applicable local and/or national regulations. The maximum allowable site tonnage and the days of use should be below the number needed to maintain exposures at an acceptable level. Water : If necessary, all contaminated waste water must be treated in a municipal or industrial wastewater treatment plant before release to surface water. Chemical removal by air and water pollution control devices must meet the minimum efficiency requirements needed to reduce exposures to an acceptable level. The discharge of treatment plant effluent to rivers and oceans must achieve the dilution ratio needed to reduce exposures to an acceptable level. The size and capacity of wastewater treatment plants must meet the minimum requirements needed to reduce exposures to an acceptable level. Maritime spillages should be dealt with according to a Shipboard Oil Pollution Emergency Plan (SOPEP), as required by MARPOL Annex1 Regulation 26.

Stable under recommended storage conditions.

Stable

Not expected to occur. Note: This material is stable when properly handled and stored.

Heat, sparks, open flame, other ignition sources, and oxidizing conditions.

Strong oxidizing agents

Combustion may produce oxides of carbon and other toxic gases. Thermal decomposition : Note: Thermal decomposition may generate carbon monoxide, carbon dioxide, and perhaps other toxic vapors.

Preferred disposal for this volatile, flammable product is through combustion. Use flare if pressure warrants.

Preferred disposal for this volatile, flammable product is through combustion.