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Safety Data Sheet EN

CRUDE C4

CAS 68476-52-8
EC 270-691-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
CRUDE C4
Product Code
270-691-3
Chemical Name
Hydrocarbons, C4, ethylene-manuf.-byproduct
Synonyms
Debutanizer Overhead

Regulatory Identifiers

CAS Number
68476-52-8 Check regulations →
EC Number
270-691-3 Check regulations →
REACH No.
01-2119473796-21-0000

Identified Uses

Manufacture, Distribution of substance, Use as intermediate, Formulation, Uses in Coatings, Use as a fuel, Manufacture of rubber products, Polymer production, Polymer processing

Manufacturers & Suppliers

B

Basell Polyolefine GmbH

manufacturer

Brhler Strae 60 D-50389 Wesseling Germany

+49 (0)2236 72 0

B

Basell Polyolfines France SAS

national supplier

Chemin dpartemental 54 B.P. 14 13131 Berre l'Etang Cedex France

R

Raffinerie de Berre

manufacturer

Emergency Contacts

Basell Polyolefine GmbH

+49(0)2236 72 2555

Raffinerie de Berre

+33 (0) 4 42 74 42 74

Giftnotruf der Charit

+49 30 19240

24 hours all days

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. H220
Press. Gas (Liq.) H280
Muta. Cat. 1 H340
Carc. Cat. 1B H350

GHS Pictograms

GHS02 - Flammable

GHS02

GHS04 - Compressed gas

GHS04

GHS08 - Serious health hazard

GHS08

Hazard Statements

H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
H340 May cause genetic defects.
H350 May cause cancer.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from open flames/hot surfaces. - No smoking.
P243 Take precautionary measures against static discharge.
P281 Use personal protective equipment as required.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 Eliminate all ignition sources if safe to do so.
P410 + P403 Protect from sunlight. Store in a well-ventilated place.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Substance

>= 98.0 % A 28.0 - 90.0 % A 0.0 - 33.0 % A

Chemical Name CAS Number Concentration Hazardous
Hydrocarbons, C4, ethylene-manuf.-byproduct EC: 270-691-3 68476-52-8 --- No
buta-1,3-dieen EC: 203-450-8 106-99-0 --- No
2-methylpropne EC: 204-066-3 115-11-7 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not leave the victim unattended. Keep patient warm and at rest. Immediately seek medical attention. If breathing is difficult, give oxygen. If unconscious place in recovery position and seek medical advice. In the event of unconsciousness, apnea or cardiac arrest (no pulse), apply cardiopulmonary resuscitation.

Symptoms: Inhalation of very high concentrations may cause asphyxia, anesthesia, CNS depresssion (primarily fatigue, dizziness and loss of concentration, with collapse, coma and death in cases of severe overexposure), and possible cardiac sensitization.

Skin contact

If frostbite has not occurred, immediately flush affected area with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. If frostbite has occurred, seek medical attention immediately; do not rub the affected area or flush with water. To prevent further damage, do not attempt to remove frozen clothing from affected area. Get medical attention immediately if irritation persists.

Symptoms: Non-irritating to the skin. Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite.

Eye contact

If eye tissue is frozen, seek medical attention immediately. If tissue is not frozen, thoroughly flush the eyes with large amounts of clean low-pressure water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation persists seek medical attention.

Symptoms: If eye tissue is frozen, seek medical attention immediately. Skin or eye contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite.

Ingestion

Ingestion is not a route of exposure for gases.

Symptoms: Ingestion is not a route of exposure for gases.

Immediate Medical Attention

Immediately seek medical attention (for inhalation). If frostbite has occurred (skin or eye), seek medical attention immediately. Get medical attention immediately if skin irritation persists.

Medical Treatment

Treat symptomatically. Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient. Treat frost-bitten areas as needed.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits.

Hands

Wear insulated gloves if contact with liquid is possible. The selected gloves must satisfy the European norm standard EN 511 for protection against the cold.

Eyes

Safety glasses are the minimum requirements. Use chemical type goggles and face shield when handling liquified gases. The selected goggles or glasses must satisfy the European norm standard EN 166.

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Use only approved supplied air or self-contained breathing apparatus operated in positive pressure mode. If needed, wear a supplied air respirator conforming to a European norm standard such as EN 139 or equivalent. Wear a respirator conforming to EN 371 with Type AX filter designed for low boiling compounds.

Environmental

See section 6.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solidification Point
---
Ph
Note: Not applicable.
Dynamic Viscosity
Note: Not applicable (gas).
Bulk Density
---
Softening Point
---
Voc Content
---
Melting Point
-105.5 C
Colour Intensity
---
Flash Point
< -30 - -18 C
Decomposition Temperature
---
Flammability
---
Physical State
gaseous at 20 C (1,013 hPa)
Freezing Point
Note: no data available
Crystallisation Point
---
Solubility In Fat
---
Odor
Faint, mild hydrocarbon odor.
Metal Corrosion
---
Evaporation Rate
---
State Under Standard Conditions
---
Appearance
---
Lower Explosive Limit
1.6 vol%
Explosive Limits
---
Solubility
---
Relative Density
---
Physical State Data
gas
Relative Evaporation Rate
---
Boiling Point
Note: Not applicable (gas).
Upper Explosive Limit
12 vol%
Kinematic Viscosity
Note: Not applicable (gas).
Auto Ignition Temperature
364 - 413 C
Vapor Pressure
2,170 hPa at 16.85 C 2,550 hPa at 21.85 C
Solubility In Water
0.1356 - 0.7923 g/l at 20 C
Molecular Weight
---
Vapor Density
---
Properties Status
---
Density
Note: Not applicable (gas).
Colour
colorless
Cloud Point
---
Odor Threshold
---
Form
---
Partition Coefficient
log Pow: 2.09 - 2.31
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1010
Shipping Name
BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED
Transport Class
2
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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is CRUDE C4 known by?

CRUDE C4 is also known as: Debutanizer Overhead

What is the hazard signal word for CRUDE C4?

The signal word is danger.

What is the physical form of CRUDE C4?

CRUDE C4 is a gaseous at 20 c (1,013 hpa) with colorless color. It has faint, mild hydrocarbon odor. odor.

What is CRUDE C4 used for?

Manufacture, Distribution of substance, Use as intermediate, Formulation, Uses in Coatings, Use as a fuel, Manufacture of rubber products, Polymer production, Polymer processing

What are the hazard statements for CRUDE C4?

This substance has 4 hazard statements:

  • H220: Extremely flammable gas.
  • H280: Contains gas under pressure; may explode if heated.
  • H340: May cause genetic defects.
  • H350: May cause cancer.

What is the melting point of CRUDE C4?

The melting point is -105.5 C and the boiling point is Note: Not applicable (gas)..

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