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Safety Data Sheet EN

Cumene hydroperoxide

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Cumene hydroperoxide
Product Code
247502

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV/SRL

national supplier

Brusselsesteenweg 288 B-3090 OVERIJSE

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Org. Perox. Cat. F H242
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 3 H331
Acute Tox. Cat. 4 H312
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335
STOT RE Cat. 2 H373
Asp. Tox. Cat. 1 H304
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H242 Heating may cause a fire.
H302 + H312 Harmful if swallowed or in contact with skin.
H304 May be fatal if swallowed and enters airways.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H373 May cause damage to organs (Lungs) through prolonged or repeated exposure if inhaled.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Cumol hydroperoxide EC: 201-254-7 80-15-9 70 - 90% Yes
cumene EC: 202-704-5 98-82-8 20 - 25% Yes
2-Phenylpropan-2-ol EC: 210-539-5 617-94-7 1 - 10% Yes

Notes

A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) No 1907/2006, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting. Call a physician immediately. Do not attempt to neutralise.

Symptoms: risk of perforation. Pulmonary failure possible after aspiration of vomit.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Full contact Material: butyl-rubber Minimum layer thickness: 0,3 mm Break through time: 480 min Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0,4 mm Break through time: 240 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type ABEK The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solubility In Fat
---
Upper Explosive Limit
No data available
Relative Evaporation Rate
---
Melting Point
No data available
Physical State
liquid
Bulk Density
---
Vapor Pressure
0,5 hPa at 55 °C < 0,04 hPa at 20 °C
Partition Coefficient
No data available
Form
liquid
Evaporation Rate
No data available
Boiling Point
100 - 101 °C
Odor Threshold
No data available
State Under Standard Conditions
---
Solubility In Water
soluble
Colour Intensity
---
Properties Status
---
Freezing Point
No data available
Physical State Data
liquid
Molecular Weight
---
Ph
No data available
Appearance
liquid
Flammability
No data available
Decomposition Temperature
70 °C
Explosive Limits
---
Metal Corrosion
---
Odor
No data available
Dynamic Viscosity
No data available
Density
1,03 g/mL at 25 °C
Crystallisation Point
---
Lower Explosive Limit
No data available
Solidification Point
---
Cloud Point
---
Colour
---
Relative Density
No data available
Vapor Density
5,25 - (Air = 1.0)
Kinematic Viscosity
No data available
Auto Ignition Temperature
No data available
Solubility
soluble
Softening Point
---
Voc Content
---
Flash Point
79 °C
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Self-Accelerating decomposition temperature (SADT) 70°C The product is chemically stable under standard ambient conditions (room temperature) .

Reactivity

Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical.

Hazardous reactions

No data available

Avoid

Do not expose to temperatures above: 40°C Strong heating.

Incompatible

Powdered metals, Organic materials, Heavy metal salts, metal salts, Combustible material, Acids, Alkalis, Reducing agents, Rust, charcoal, Amines, Copper, Lead, Cobalt/cobalt oxidesStrong oxidizing agents

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3109
IATA

“Keep away from heat” label required.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Cumene hydroperoxide?

The signal word is danger.

What is the physical form of Cumene hydroperoxide?

Cumene hydroperoxide is a liquid appearing as liquid . It has no data available odor.

What is the solubility of Cumene hydroperoxide?

soluble

What is Cumene hydroperoxide used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Cumene hydroperoxide?

This substance has 8 hazard statements:

  • H242: Heating may cause a fire.
  • H302 + H312: Harmful if swallowed or in contact with skin.
  • H304: May be fatal if swallowed and enters airways.
  • H314: Causes severe skin burns and eye damage.
  • H331: Toxic if inhaled.
  • H335: May cause respiratory irritation.
  • H373: May cause damage to organs (Lungs) through prolonged or repeated exposure if inhaled.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Cumene hydroperoxide?

The melting point is No data available and the boiling point is 100 - 101 °C.

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