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Safety Data Sheet EN

Imidazole

CAS 288-32-4
EC 206-019-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Imidazole
Product Code
I2399
Chemical Name
1-Imidazole
Synonyms
Glyoxaline

Regulatory Identifiers

CAS Number
288-32-4 Check regulations →
EC Number
206-019-2 Check regulations →
REACH No.
01-2119485825-24

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science N.V.

national supplier

Haarlerbergweg 21 A 1101 CH AMSTERDAM

+31 078 620-5411

Emergency Contacts

CHEMTREC

+(31)-858880596

Alarmnummer

112

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Skin Corr. Cat. 1C H314
Eye Dam. Cat. 1 H318
Repr. Cat. 1B H360D

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H360D May damage the unborn child.

Precautionary Statements

P260 Do not breathe dusts or mists.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Synonyms : 1,3-Diaza-2,4-cyclopentadiene Glyoxaline

Chemical Name CAS Number Concentration Hazardous
Imidazole EC: 206-019-2 288-32-4 100% Yes

Notes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately.

Immediate Medical Attention

No data available

Medical Treatment

No data available

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water Foam Carbon dioxide (CO2) Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides Nitrogen oxides (NOx) Hydrogen cyanide (hydrocyanic acid) Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Suppress (knock down) gases/vapors/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Collect, bind, and pump off spills. Take up carefully. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Nitrile rubber gloves, minimum layer thickness: 0.11 mm, breakthrough time: 480 min. Material tested: KCL 741 Dermatril® L. Recommendations apply to product as stated in SDS and for designated use. For other conditions, contact supplier of CE-approved gloves (e.g., KCL GmbH). Compliance with EN374 mentioned.

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles.

Respiratory

Required when dusts are generated. Recommendations on filtering respiratory protection are based on standards: DIN EN 143, DIN 14387. Recommended Filter type: Filter type P3. Maintenance, cleaning and testing of respiratory protective devices must be carried out according to producer's instructions and properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
crystalline
Physical State Data
solid
State Under Standard Conditions
---
Appearance
crystalline, whitelight yellow
Colour
whitelight yellow
Colour Intensity
---
Form
crystalline
Odor
amine-like
Odor Threshold
No data available
Ph
10,5 at 67 g/l at 20 °C
Melting Point
88 - 91 °C
Boiling Point
256 °C
Flash Point
145 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
0,003 hPa at 20 °C
Vapor Density
No data available
Relative Density
No data available
Bulk Density
---
Density
---
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
log Pow: -0,02 - OECD Test Guideline 107 - Bioaccumulation is n-octanol/water not expected., (Lit.)
Solubility In Water
No data available
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
2,696 mPa.s at 100 °C
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature) .

Reactivity

Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Hazardous reactions

Violent reactions possible with: Strong oxidizing agents Acid chlorides Acid anhydrides acids

Avoid

Strong heating.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

Disposal

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3263
Shipping Name
CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (Imidazole)
Transport Class
8
Packing Group
III
ADR

No data available

IMDG

No data available

IATA

No data available

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Imidazole known by?

Imidazole is also known as: Glyoxaline

What is the hazard signal word for Imidazole?

The signal word is danger.

What is the physical form of Imidazole?

Imidazole is a crystalline appearing as crystalline, whitelight yellow with whitelight yellow color. It has amine-like odor.

What is Imidazole used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Imidazole?

This substance has 3 hazard statements:

  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H360D: May damage the unborn child.

What is the melting point of Imidazole?

The melting point is 88 - 91 °C and the boiling point is 256 °C.

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