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Safety Data Sheet EN

CombiPrimer primers red & grey

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
CombiPrimer primers red & grey
Product Form
Liquid.
Product Code
3369 / 3380

Regulatory Identifiers

CAS Number
N/A
UFI Code
A630-V02Q-R00P-9WN7

Identified Uses

Consumer use Industrial use Professional use

Uses advised against

None identified.

Manufacturers & Suppliers

R

RUST-OLEUM EUROPE Martin Mathys NV

Kolenbergstraat 23, B-3545 Zelem, Belgium

+32 (0) 13 460 200

T

Tor Coatings Limited

Unit 21, White Rose Way, Follingsby Park, Gateshead, Tyne & Wear, NE10 8YX United Kingdom

+44 (0) 191 4106611

Emergency Contacts

Emergency Contact

+44 870 8200418

24 / 7

Emergency Contact

+44 2038073798

24 / 7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3 H226
STOT SE Cat. 3 H336
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H226 Flammable liquid and vapour.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P391 Collect spillage.
P403 + P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.

Chemical Name CAS Number Concentration Hazardous
trizinc bis(orthophosphate) EC: 231-944-3 7779-90-0 5% Yes
hydrocarbons, C9-C10, n-/iso-/ cyclo-alkanes, < 2% aromatics --- 10 - 20% Yes
hydrocarbons, C9-C11, n-/iso-/ cyclo-alkanes, < 2% aromatics EC: 919-857-5 --- 10% Yes
hydrocarbons, isoalkanes, C7-C9 64741-66-8 10% Yes
1-methoxy-2-propanol EC: 203-539-1 107-98-2 3% Yes
zinc oxide EC: 215-222-5 1314-13-2 1% Yes

See Section 16 for the full text of the H statements declared above. Occupational exposure limits, if available, are listed in Section 8.

Notes

The Annex VI classification of titanium dioxide does not apply to this mixture according to Note 10. List numbers have no legal significance.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Adverse symptoms may include the following: nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness

Skin contact

Wash skin thoroughly with soap and water or use recognised skin cleanser. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: Adverse symptoms may include the following: irritation, dryness, cracking

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Symptoms: No specific data.

Ingestion

Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: No specific data.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical,CO₂,water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Specific hazards

Flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapour/gas is heavier than air and will spread along the ground. Vapours may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.

Cleanup methods

Collect spillage.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Do not store above the following temperature: 35°C (95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. > 8 hours (breakthrough time): nitrile rubber (0.5mm) The recommendation for the type or types of glove to use when handling this product is based on information from the following source: EN374. The user must check that the final choice of type of glove selected for handling this product is the most appropriate and takes into account the particular conditions of use, as included in the user's risk assessment.

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Use eye protection according to EN 166. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Recommended: organic vapour filter (Type A) (EN 140)

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods. Recommended: Personnel should wear antistatic clothing made of natural fibres or of high-temperature-resistant synthetic fibres. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Various
Colour Intensity
---
Form
---
Odor
Hydrocarbon. [Slight]
Odor Threshold
Not available.
Ph
Not applicable.
Melting Point
-20°C
Boiling Point
>160°C (>320°F)
Flash Point
Closed cup: 40°C (104°F)
Freezing Point
-20C [Literature]
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
0,2 (butyl acetate = 1)
Vapor Pressure
0,7 kPa (5,25 mm Hg) [calculated.]
Vapor Density
>1 [Air = 1]
Relative Density
Not available.
Bulk Density
---
Density
1,18 to 1,251 g/cm [20C (68F)] [DIN 53217]
Flammability
Flammable in the presence of the following materials or conditions: open flames, sparks and static discharge, heat and shocks and mechanical impacts. Vapour may travel a considerable distance to source of ignition and flash back.
Upper Explosive Limit
8%
Lower Explosive Limit
0,6%
Explosive Limits
---
Auto Ignition Temperature
250°C (482°F)
Decomposition Temperature
Not available.
Solubility
Media Result cold water Not soluble hot water Not soluble acetone Partially soluble
Partition Coefficient
Not applicable.
Solubility In Water
Not available.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Dynamic (room temperature): 950 to 1150 mPas [ASTM D562 [KU]]
Kinematic Viscosity
Kinematic (room temperature): 759 to 975 mm [2] /s [calculated.] Kinematic (40C): >20,5 mm [2] /s [calculated.]
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapour to accumulate in low or confined areas.

Incompatible

oxidising materials

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimised wherever possible. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Disposal

Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

Waste Codes

08 01 11* waste paint and varnish containing organic solvents or other hazardous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1263
Shipping Name
Paint
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for CombiPrimer primers red & grey?

The signal word is warning.

What is the physical form of CombiPrimer primers red & grey?

CombiPrimer primers red & grey is a liquid. with various color. It has hydrocarbon. [slight] odor.

What is the solubility of CombiPrimer primers red & grey?

Media Result cold water Not soluble hot water Not soluble acetone Partially soluble

What is CombiPrimer primers red & grey used for?

Consumer use Industrial use Professional use

What are the hazard statements for CombiPrimer primers red & grey?

This substance has 3 hazard statements:

  • H226: Flammable liquid and vapour.
  • H336: May cause drowsiness or dizziness.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of CombiPrimer primers red & grey?

The melting point is -20°C and the boiling point is >160°C (>320°F).

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