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Safety Data Sheet EN

Pebeo Graphic India Ink

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Pebeo Graphic India Ink
Synonyms
EN-FDS123 Graphic India Ink

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Paints & Varnishes for artists. Use according to manufacturer's directions.

Manufacturers & Suppliers

Jasco Pty Limited logo

Jasco Pty Limited

manufacturer

1-5 Commercial Road Kingsgrove NSW 2208 Australia

+61 2 9807 1555

http://www.jasco.com.au

Emergency Contacts

Australian Poisons Centre

13 11 26

24/7

CHEMWATCH EMERGENCY RESPONSE

+61 1800 951 288

24/7

CHEMWATCH EMERGENCY RESPONSE

+61 3 9573 3188

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Not Classified

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
diethylene glycol 111-46-6 2.5% No
1,2-benzisothiazoline-3-one 2634-33-5 0.013% No
carbon black 1333-86-4 --- No

Notes

Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 4. Classification drawn from C&L * EU IOELVs available

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary.

Skin contact

Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available).

Eye contact

Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Ingestion

If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.

Symptoms: Signs of being sleepy or with reduced awareness; i.e. becoming unconscious.

Immediate Medical Attention

Seek medical attention without delay; if pain persists or recurs seek medical attention (Eye). Seek medical attention in event of irritation (Skin). Seek medical advice (Ingestion).

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing media suitable for surrounding area.

Unsuitable media

There is no restriction on the type of extinguisher which may be used.

Specific hazards

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Instructions

Alert Fire Brigade and tell them location and nature of hazard. Use fire fighting procedures suitable for surrounding area. DO NOT approach containers suspected to be hot. If safe to do so, remove containers from path of fire.

Firefighter Protection

Wear breathing apparatus plus protective gloves in the event of a fire.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

See section 8

Small spill

Clean up all spills immediately. Avoid contact with skin and eyes. Wear impervious gloves and safety goggles. Trowel up/scrape up. Place spilled material in clean, dry, sealed container. Flush spill area with water.

Large spill

Clear area of personnel. Alert Fire Brigade and tell them location and nature of hazard. Control personal contact with the substance, by using protective equipment as required. Prevent spillage from entering drains or water ways. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Absorb remaining product with sand, earth or vermiculite and place in appropriate containers for disposal. Wash area and prevent runoff into drains or waterways. If contamination of drains or waterways occurs, advise emergency services.

Environmental

See section 12

Cleanup methods

Trowel up/scrape up. Place spilled material in clean, dry, sealed container. Flush spill area with water. Wash area and prevent runoff into drains or waterways.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. DO NOT allow material to contact humans, exposed food or food utensils. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Launder contaminated clothing before re-use. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.

Storage

Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks.

Hygiene

When handling, DO NOT eat, drink or smoke. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Launder contaminated clothing before re-use.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

General exhaust is adequate under normal operating conditions.

Hands

• Wear chemical protective gloves, e.g. PVC. • Butyl rubber gloves • Nitrile rubber gloves (Note: Nitric acid penetrates nitrile gloves in a few minutes.) Recommended materials: BUTYL (CPI: A), NITRILE (CPI: A). Ansell Glove Selection: AlphaTec® 15-554, AlphaTec® Solvex® 37-185, AlphaTec® 38-612, AlphaTec® 58-008, AlphaTec® 58-530B, AlphaTec® 58-530W, AlphaTec® 58-735, AlphaTec® 79-700, AlphaTec® Solvex® 37-675, DermaShield™ 73-711.

Eyes

• Safety glasses with side shields. • Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent] • Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].

Respiratory

Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent). Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the "Exposure Standard" (or ES), respiratory protection is required. (See provided table for protection factors). Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content.

Skin/Body

• Wear safety footwear or safety gumboots, e.g. Rubber • Overalls. • P.V.C apron. • Barrier cream.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Non Slump Paste
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Liquid; mixes with water.
Colour
---
Colour Intensity
---
Form
---
Odor
Not Available
Odor Threshold
Not Available
Ph
Not Available
Melting Point
Not Available
Boiling Point
Not Available
Flash Point
Not Applicable
Freezing Point
Not Available
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not Available
Vapor Pressure
Not Available
Vapor Density
Not Available
Relative Density
1.07
Bulk Density
---
Density
---
Flammability
Not Applicable
Upper Explosive Limit
Not Applicable
Lower Explosive Limit
Not Applicable
Explosive Limits
---
Auto Ignition Temperature
Not Available
Decomposition Temperature
Not Available
Solubility
---
Partition Coefficient
Not Available
Solubility In Water
Miscible
Solubility In Fat
---
Molecular Weight
Not Applicable
Voc Content
Not Applicable
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Not Available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Product is considered stable. Unstable in the presence of incompatible materials.

Reactivity

See section 7

Hazardous reactions

Hazardous polymerisation will not occur.

Avoid

See section 7

Incompatible

See section 7

Decomposition

See section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Toxicity | Pebeo Graphic India Ink | Endpoint | Test Duration (hr) | Species | Value | Source | | --- | --- | --- | --- | --- | --- | | | Not Available | Not Available | Not Available | Not Available | Not Available | | diethylene glycol | Endpoint | Test Duration (hr) | Species | Value | Source | | | EC50 | 72h | Algae or other aquatic plants | >6500<13000mg/l | 2 | | | NOEC(ECx) | 192h | Algae or other aquatic plants | 800mg/l | 1 | | | EC50 | 48h | Crustacea | >100mg/l | 2 | | | LC50 | 96h | Fish | >100mg/l | 4 | | | EC50 | 96h | Algae or other aquatic plants | 4566mg/l | 2 | | 1,2-benzisothiazoline-3-one | Endpoint | Test Duration (hr) | Species | Value | Source | | | EC50 | 72h | Algae or other aquatic plants | 0.07mg/L | 2 | | | EC50 | 48h | Crustacea | 0.097mg/L | 4 | | | LC50 | 96h | Fish | 0.067-0.29mg/L | 4 | | | NOEC(ECx) | 72h | Algae or other aquatic plants | 0.04mg/L | 2 | | carbon black | Endpoint | Test Duration (hr) | Species | Value | Source | | | EC50 | 72h | Algae or other aquatic plants | >0.2mg/l | 2 | | | EC50 | 48h | Crustacea | 33.076-41.968mg/l | 4 | | | LC50 | 96h | Fish | >100mg/l | 2 | | | NOEC(ECx) | 24h | Crustacea | 3200mg/l | 1 | | Legend: | Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data | | | | |

Persistence and degradability

Persistence and degradability | Ingredient | Persistence: Water/Soil | Persistence: Air | | --- | --- | --- | | diethylene glycol | LOW | LOW |

Bioaccumulative potential

Bioaccumulative potential | Ingredient | Bioaccumulation | | --- | --- | | diethylene glycol | LOW (BCF = 180) |

Mobility in soil

Mobility in soil | Ingredient | Mobility | | --- | --- | | diethylene glycol | HIGH (Log KOC = 1) |
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Bury or incinerate residue at an approved site.

Disposal

Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Authority for disposal. Bury or incinerate residue at an approved site.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Not Applicable

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Pebeo Graphic India Ink known by?

Pebeo Graphic India Ink is also known as: EN-FDS123 Graphic India Ink

What is the hazard signal word for Pebeo Graphic India Ink?

The signal word is no signal word.

What is the physical form of Pebeo Graphic India Ink?

Pebeo Graphic India Ink is a non slump paste appearing as liquid; mixes with water. . It has not available odor.

What is Pebeo Graphic India Ink used for?

Paints & Varnishes for artists. Use according to manufacturer's directions.

What is the melting point of Pebeo Graphic India Ink?

The melting point is Not Available and the boiling point is Not Available.