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Safety Data Sheet EN

Pyrolysis Gasoline

CAS 68606-10-0
EC 271-726-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Pyrolysis Gasoline
Chemical Name
Gasoline, pyrolysis, debutanizer bottoms
Synonyms
DAC/RPG, DISTILLATION, RESIDUES C5-C11, Debutanized Aromatic Concentrate, Aromatic Concentrate, Aromatic Distillate, Debutanizer Bottoms, DAC, Raw Pyrolysis Gasoline, Slop Oil, Dripolene, Pygas

Regulatory Identifiers

CAS Number
68606-10-0 Check regulations →
EC Number
271-726-5 Check regulations →
REACH No.
01-2119474887-17-0015

Identified Uses

Feedstock for petrochemical manufacturing

Uses advised against

Anything other than the above

Manufacturers & Suppliers

V

Vitol Inc.

2925 Richmond Ave, 11th Floor Houston, TX 77098

(713) 230-1000

Emergency Contacts

Chemtrec

1-800-424-9300

24h

Chemtrec

800 681 9531

24h

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 1
Asp. Tox. Cat. 1
Skin Irrit. Cat. 2
STOT SE Cat. 3
Muta. Cat. 1B
Carc. Cat. 1B
Aquatic Acute Cat. 2
Aquatic Chronic Cat. 2

GHS Pictograms

GHS02 - Flammable

GHS02

GHS08 - Serious health hazard

GHS08

GHS07 - Health hazard

GHS07

Hazard Statements

H224 Extremely flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H350 May cause cancer.
H412 Harmful to aquatic life with long lasting effects.
May cause genetic defects.

Precautionary Statements

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Obtain special instructions before use.
Do not breathe vapour.
Wear protective gloves/eye protection/face protection.
IF SWALLOWED: Immediately call a POISON CENTER/doctor.
IF ON SKIN: Wash with plenty of water.
Immediately call a POISON CENTER/doctor.
Do NOT induce vomiting.
Avoid release to environment.
Dispose of contents in accordance with local, state or national legislation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Classification: OSHA HCS (29 CFR 1910.1200)

Chemical Name CAS Number Concentration Hazardous
Gasoline, pyrolysis, debutanizer bottoms EC: 271-726-5 68606-10-0 100% No
Hydrocarbons, ethylene-manuf .- by-product distn. residues EC: 272-951-1 68921-67-5 100% Yes
iso-alkaanen, cyclisch (<0,1% benzeen CAS 71-43-2) EC: 200-753-7 71-43-2 80% Yes
3a,4,7,7a- tetrahydro-4,7- methanondeen EC: 201-052-9 77-73-6 30% Yes
Toluene imp. EC: 203-625-9 108-88-3 30% Yes
Xylene EC: 905-215-1 1330-20-7 10% Yes
ethylbenzene EC: 202-849-4 100-41-4 10% Yes
cyclopentadieen EC: 208-835-4 542-92-7 10% Yes
Styrene EC: 202-851-5 100-42-5 10% Yes
n-Heptaan 99%, HPLC EC: 205-563-8 142-82-5 5% Yes
Hexane (mixture of isomers) EC: 203-777-6 110-54-3 5% Yes
Isopentane EC: 201-142-8 78-78-4 5% Yes
Isopreen EC: 201-143-3 78-79-5 5% Yes
buta-1,3-dieen EC: 203-450-8 106-99-0 5% Yes
naphthalene EC: 202-049-5 91-20-3 1% Yes
butane substance with national workplace exposure limit(s) (AT, BE, BG, DE, DK, ET, FI, FR, GB, GR, HU, IE, IT, LV. PL, PT) EC: 203-448-7 106-97-8 1% Yes
bifenyl EC: 202-163-5 92-52-4 1% Yes
PHENANTHRENE EC: 201-581-5 85-01-8 1% Yes
cyclopentane EC: 206-016-6 287-92-3 1% Yes
isopropylbenzene (cumene) EC: 202-704-5 98-82-8 1% Yes
1,2,4-trimethylbenzene EC: 202-436-9 95-63-6 1% Yes
indeen EC: 202-393-6 95-13-6 1% Yes
2-methyl-2-buteen EC: 208-156-3 513-35-9 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Apply artificial respiration only if patient is not breathing but do not use mouth to mouth resuscitation. Get medical advice/attention if you feel unwell.

Symptoms: If breathing is difficult

Skin contact

IF ON SKIN (or hair): Remove contaminated clothing immediately and wash affected skin with plenty of water or soap and water. If irritation persists, get medical attention.

Symptoms: If irritation persists

Eye contact

IF IN EYES: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation develops and persists, get medical attention.

Symptoms: If irritation develops and persists

Ingestion

IF SWALLOWED: rinse mouth. Do NOT induce vomiting. If unconscious, place in recovery position and get medical attention immediately. Wash out mouth with water and give small quantities of water to drink. Do not give anything by mouth to an unconscious person. Get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Do not wait for symptoms to appear.

Symptoms: May be fatal if swallowed and enters airways. If unconscious.

Immediate Medical Attention

Get medical advice/attention if you feel unwell or if irritation persists/develops. Seek immediate medical assistance if swallowed, if unconscious, or if aspiration is suspected. Do not wait for symptoms to appear.

Medical Treatment

Treat symptomatically. If vomiting occurs spontaneously, keep head below hips to prevent aspiration into the lungs.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide adequate ventilation, including appropriate local extraction if dusts, fumes or vapours are likely to be evolved. Store in a cool/low-temperature, well- ventilated (dry) place away from heat and ignition sources. Guarantee that the eye flushing systems and safety showers are located close to the working place.

Hands

Wear impervious gloves (recommended: EN374). Gloves should be changed regularly to avoid permeation problems. Breakthrough time of the glove material: refer to the information provided by the gloves' producer. Protective index 6, corresponding > 480 minutes of permeation time according to EN 374. Efficiency of at least 80%).

Eyes

Use eye protection according to EN 166, designed to protect against liquid splashes.

Respiratory

When the product is heated / In case of inadequate ventilation wear respiratory protection. The use of a high efficiency filter (recommended: EN143) is recommended. Filter type A1. Closed system(s): Not normally required.

Skin/Body

Wear anti-static clothing and shoes. Small scale: Wear suitable coveralls to prevent exposure to the skin. Large scale: Chemical protection suit.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Amber liquid
Colour
Amber
Colour Intensity
---
Form
liquid
Odor
Not determined
Odor Threshold
Not determined
Ph
Not determined
Melting Point
-62 (-80 F)
Boiling Point
32 - 204 (90 - 399 F) Overpoint-Endpoint
Flash Point
> -11 C (> 12 F) Method: Tag closed cup
Freezing Point
-62 (-80 F)
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not determined
Vapor Pressure
11.00 PSI at 38 (100 F)
Vapor Density
2.8 (Air = 1.0)
Relative Density
0.825 (Air = 1.0)
Bulk Density
---
Density
---
Flammability
Not applicable - Liquid
Upper Explosive Limit
7.5 %(V)
Lower Explosive Limit
1.3% (V)
Explosive Limits
---
Auto Ignition Temperature
348 (658 F)
Decomposition Temperature
Not determined
Solubility
Soluble in hydrocarbon solvents; insoluble in water
Partition Coefficient
Not determined
Solubility In Water
insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
99%
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
0.9 cSt at 40 (104 F)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1268
Shipping Name
PETROLEUM DISTILLATES, N.O.S
Transport Class
3
Packing Group
I
ADR

See Section: 2

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Pyrolysis Gasoline known by?

Pyrolysis Gasoline is also known as: DAC/RPG, DISTILLATION, RESIDUES C5-C11, Debutanized Aromatic Concentrate, Aromatic Concentrate, Aromatic Distillate, Debutanizer Bottoms, DAC, Raw Pyrolysis Gasoline, Slop Oil, Dripolene, Pygas

What is the hazard signal word for Pyrolysis Gasoline?

The signal word is danger.

What is the physical form of Pyrolysis Gasoline?

Pyrolysis Gasoline is a liquid appearing as amber liquid with amber color. It has not determined odor.

What is the solubility of Pyrolysis Gasoline?

Soluble in hydrocarbon solvents; insoluble in water

What is Pyrolysis Gasoline used for?

Feedstock for petrochemical manufacturing

What are the hazard statements for Pyrolysis Gasoline?

This substance has 7 hazard statements:

  • H224: Extremely flammable liquid and vapour.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H336: May cause drowsiness or dizziness.
  • H350: May cause cancer.
  • H412: Harmful to aquatic life with long lasting effects.
  • May cause genetic defects.

What is the melting point of Pyrolysis Gasoline?

The melting point is -62 (-80 F) and the boiling point is 32 - 204 (90 - 399 F) Overpoint-Endpoint.

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