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Safety Data Sheet EN

Methyl Ethyl Ketone

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Methyl Ethyl Ketone
Product Code
M209SS-200

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Laboratory chemicals.

Uses advised against

Not for food, drug, pesticide or biocidal product use

Manufacturers & Suppliers

F

Fisher Scientific

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One Reagent Lane Fair Lawn, NJ 07410

(201) 796-7100

Emergency Contacts

CHEMTREC

800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2
Eye Irrit. Cat. 2
STOT SE Cat. 3
STOT RE Cat. 2

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapor
H319 Causes serious eye irritation
H336 May cause drowsiness or dizziness
May cause damage to organs through prolonged or repeated exposure

Precautionary Statements

Wash face, hands and any exposed skin thoroughly after handling
Do not breathe dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/protective clothing/eye protection/face protection
Keep cool
Get medical attention/advice if you feel unwell
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention
In case of fire: Use CO2, dry chemical, or foam for extinction
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Dispose of contents/container to an approved waste disposal plant

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Manage SDS
03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Methylethyl ketone 78-93-3 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. Get medical attention if symptoms occur. If not breathing, give artificial respiration.

Symptoms: Breathing difficulties. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Get medical attention if symptoms occur.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention.

Ingestion

Do not induce vomiting. Obtain medical attention.

Symptoms: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting

Immediate Medical Attention

Obtain medical attention for eye contact and ingestion. Get medical attention if symptoms occur for skin and inhalation. If not breathing, give artificial respiration for inhalation.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO 2, dry chemical, dry sand, alcohol-resistant foam. Cool closed containers exposed to fire with water spray.

Unsuitable media

Water may be ineffective

Specific hazards

Flammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated. Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources of ignition.

Instructions

Cool closed containers exposed to fire with water spray.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment. Remove all sources of ignition. Take precautionary measures against static discharges. Avoid contact with skin, eyes and clothing. Ensure adequate ventilation.

Environmental

Avoid release to the environment. See Section 12 for additional ecological information.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Use spark-proof tools and explosion-proof equipment.

Materials: inert absorbent material

Related Substances

Similar chemicals with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Avoid ingestion and inhalation.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Keep away from heat and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location.

Hands

Wear appropriate protective gloves

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Skin/Body

Wear appropriate protective clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Colour Intensity
---
Solubility In Fat
---
Flammability
Not applicable
Auto Ignition Temperature
404 °C / 759.2 °F
Kinematic Viscosity
---
Colour
Colorless
Melting Point
-87 °C / -124.6 °F
Partition Coefficient
No data available
Solubility In Water
Soluble in water
Odor Threshold
No information available
Metal Corrosion
---
Bulk Density
---
Ph
No information available
Decomposition Temperature
No information available
State Under Standard Conditions
---
Relative Evaporation Rate
---
Physical State Data
liquid
Lower Explosive Limit
1.4 vol %
Vapor Density
2.41
Relative Density
0.806
Softening Point
---
Molecular Weight
72.11
Crystallisation Point
---
Evaporation Rate
3.7
Density
---
Boiling Point
80 °C / 176 °F
Dynamic Viscosity
0.42 mPa.s @ 15°C
Cloud Point
---
Solubility
Soluble in water
Upper Explosive Limit
11.4 vol %
Freezing Point
---
Physical State
Liquid
Flash Point
-7 °C / 19.4 °F
Solidification Point
---
Voc Content
---
Odor
Characteristic - sweet
Appearance
Colorless
Properties Status
---
Explosive Limits
---
Vapor Pressure
105 mbar @ 20 °C
Form
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Hygroscopic.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous polymerization does not occur.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition. Exposure to moist air or water.

Incompatible

Strong oxidizing agents, Strong acids, Strong bases, Strong reducing agents, Ammonia, copper, Amines

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO2)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Ecotoxicity

Component Freshwater Algae Freshwater Fish Microtox Water Flea Methyl ethyl ketone Not listed Lepomis macrochirus: EC50 = 3403 mg/L 30 min EC50: 4025 - 6440 mg/L, 48h Static (Daphnia magna) LC50=3,22 g/L 96 h EC50 = 3403 mg/L 30 min EC50 = 3426 mg/L 5 min EC50: = 5091 mg/L, 48h (Daphnia magna) EC50: > 520 mg/L, 48h (Daphnia magna)

Methyl ethyl ketone shows acute toxicity to fish (Lepomis macrochirus LC50=3.22 g/L 96h, EC50=3403 mg/L 30min), water fleas (Daphnia magna EC50 ranging from 4025-6440 mg/L 48h, 5091 mg/L 48h, and >520 mg/L 48h), and bacteria (Microtox EC50=3403 mg/L 30min, 3426 mg/L 5min). No data is listed for freshwater algae.

Persistence and Degradability

Persistence is unlikely based on information available.

Persistence is unlikely based on available information.

Bioaccumulation/ Accumulation

No information available. Component log Pow Methyl ethyl ketone 0.29

No specific bioaccumulation information is available, but the log Pow for Methyl ethyl ketone is 0.29, suggesting low bioaccumulative potential.

Mobility

Will likely be mobile in the environment due to its volatility.

The substance is likely to be mobile in the environment due to its volatility.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Waste Codes

U159 Methyl ethyl ketone RCRA
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1193
Shipping Name
Ethyl methyl ketone
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

All of the components in the product are on the following Inventory lists: X = listed

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Methyl Ethyl Ketone?

The signal word is danger.

What is the physical form of Methyl Ethyl Ketone?

Methyl Ethyl Ketone is a liquid appearing as colorless with colorless color. It has characteristic - sweet odor.

What is the solubility of Methyl Ethyl Ketone?

Soluble in water

What is Methyl Ethyl Ketone used for?

Laboratory chemicals.

What are the hazard statements for Methyl Ethyl Ketone?

This substance has 4 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H319: Causes serious eye irritation
  • H336: May cause drowsiness or dizziness
  • May cause damage to organs through prolonged or repeated exposure

What is the melting point of Methyl Ethyl Ketone?

The melting point is -87 °C / -124.6 °F and the boiling point is 80 °C / 176 °F.

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