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Safety Data Sheet EN

VIGOR ZN 302 SR BASE BLUEGREEN

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
VIGOR ZN 302 SR BASE BLUEGREEN
Product Code
00280307

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Professional applications, Used by spraying. Coating.

Uses advised against

Product is not intended, labelled or packaged for consumer use.

Manufacturers & Suppliers

P

PPG AC - France Freitag

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Immeuble Union Square 1, Rue de l’Union CS10055 92565 RUEIL MALMAISON CEDEX France

+33(0)1.57.61.03.20

Emergency Contacts

Supplier

+31 (0)20 4075210

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3 H226
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317
Carc. Cat. 2 H351
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing and eye or face protection.
P391 Collect spillage.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.
Not applicable.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.

Chemical Name CAS Number Concentration Hazardous
zinc powder zinc dust (stabilised) EC: 231-175-3 7440-66-6 50 - 75% Yes
4-methylpentan-2-one EC: 203-550-1 108-10-1 10 - 20% Yes
xylene EC: 215-535-7 1330-20-7 5 - 10% Yes
Epoxy Resin (700<MW <=1100) 25036-25-3 5 - 10% Yes
Cement, portland, chemicals EC: 266-043-4 65997-15-1 1 - 3% Yes
bis-[4-(2,3-epoxipropoxi)phenyl]propane EC: 216-823-5 1675-54-3 1 - 5% Yes
ethylbenzene EC: 202-849-4 100-41-4 1 - 3.8% Yes
zinc oxide EC: 215-222-5 1314-13-2 1% Yes

See Section 16 for the full text of the H statements declared above. Occupational exposure limits, if available, are listed in Section 8.

Notes

Xylene: Several REACH registrations cover the REACH registered substance with xylene isomers, ethylbenzene (and toluene). The other REACH Registrations include: 01-2119555267-33 reaction mass of ethylbenzene and m-xylene and p- xylene, 01-2119486136-34 Aromatic hydrocarbons, C8, 01-2119539452-40 reaction mass of ethylbenzene and xylene. SUB codes represent substances without registered CAS Numbers.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Skin contact

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

Symptoms: Adverse symptoms may include the following: irritation, redness, dryness, cracking

Eye contact

Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.

Symptoms: Adverse symptoms may include the following: pain or irritation, watering, redness

Ingestion

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

Immediate Medical Attention

Seek immediate medical advice for eye contact or if swallowed. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Medical Treatment

Treat symptomatically. No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical,CO₂,water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Specific hazards

Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material. Contain and collect spillage with non-combustible, absorbent material.

Materials: water, inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

Related Substances

Similar chemicals with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store between the following temperatures: 0 to 35°C (32 to 95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Eliminate all ignition sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. When prolonged or frequently repeated contact may occur, a glove with a protection class of 6 (breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30 minutes according to EN 374) is recommended. The user must check that the final choice of type of glove selected for handling this product is the most appropriate and takes into account the particular conditions of use, as included in the user's risk assessment. Gloves: butyl rubber

Eyes

Chemical splash goggles. Use eye protection according to EN 166.

Respiratory

Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Wear a respirator conforming to EN140. Filter type: organic vapor (Type A) and particulate filter P3

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Kinematic Viscosity
>21 mm2/s (40°C)
Solubility
---
Flash Point
23°C
Odor Threshold
Not available.
Molecular Weight
---
Physical State Data
liquid
Boiling Point
>37.78°C
Dynamic Viscosity
---
Metal Corrosion
---
Physical State
Liquid.
Relative Evaporation Rate
---
Vapor Density
Highest known value: 11.7 (Air = 1) (bis-[4-(2,3-epoxipropoxi)phenyl]propane). Weighted average: 4.42 (Air = 1)
Softening Point
---
Partition Coefficient
Not applicable.
Evaporation Rate
Highest known value: 1.7 (4-methylpentan-2-one) Weighted average: 1.3 compared with butyl acetate
Properties Status
---
Ph
Not applicable. insoluble in water.
Density
---
Upper Explosive Limit
7.5%
Solubility In Water
Not soluble (cold water)
Odor
Aromatic. [Slight]
Explosive Limits
---
Flammability
Not available.
Lower Explosive Limit
1.4%
Voc Content
---
Bulk Density
---
Freezing Point
8 to 12°C (46.4 to 53.6°F)
Colour Intensity
---
Cloud Point
---
State Under Standard Conditions
---
Auto Ignition Temperature
432°C (809.6°F)
Colour
Not available.
Solidification Point
---
Melting Point
-78.68°C (-109.6°F)
Appearance
Not available.
Form
---
Solubility In Fat
---
Vapor Pressure
15.75 mm Hg (2.1 kPa) at 20˚C (for 4-methylpentan-2-one)
Decomposition Temperature
Stable under recommended storage and handling conditions (see Section 7).
Relative Density
2.02
Crystallisation Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

When exposed to high temperatures may produce hazardous decomposition products.

Incompatible

oxidizing agents, strong alkalis, strong acids.

Decomposition

carbon oxides halogenated compounds metal oxide/oxides

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Waste Codes

00280307 EWC
08 01 11* waste paint and varnish containing organic solvents or other hazardous substances EWC
15 01 06 mixed packaging EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1263
Shipping Name
PAINT
Transport Class
3
Packing Group
III
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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for VIGOR ZN 302 SR BASE BLUEGREEN?

The signal word is warning.

What is the physical form of VIGOR ZN 302 SR BASE BLUEGREEN?

VIGOR ZN 302 SR BASE BLUEGREEN is a liquid. appearing as not available. with not available. color. It has aromatic. [slight] odor.

What is VIGOR ZN 302 SR BASE BLUEGREEN used for?

Professional applications, Used by spraying. Coating.

What is the melting point of VIGOR ZN 302 SR BASE BLUEGREEN?

The melting point is -78.68°C (-109.6°F) and the boiling point is >37.78°C.

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