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Safety Data Sheet EN

CNP PM NF cement

EC 266-043-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
CNP PM NF cement
Chemical Name
Cement volgens EN 197–1
Synonyms
natural quick setting cement

Regulatory Identifiers

CAS Number
N/A
EC Number
266-043-4 Check regulations →

Identified Uses

Concrete, mortar, grout, construction products

Manufacturers & Suppliers

S

S.A. VICAT

manufacturer

Direction Commerciale Ciments et Liants Hydrauliques 4 rue Aristide Bergès BP 137 38081 L'ISLE D'ABEAU Cédex FRANCE

+33 4 74 27 40 10

Emergency Contacts

National Poisons Information Service (Birmingham Centre)

+44 870 600 6266

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2 H315
Skin Sens. Cat. 1 H317
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H335 May cause respiratory irritation

Precautionary Statements

P102 Keep out of reach of children
P260 Do not breathe dust.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338 + P310 IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
P501 Dispose of contents/container to a suitable waste collection point.
IF ON SKIN : Wash with plenty of soap and water. If skin irritation or rash occurs : Get medical advice/attention
IF INHALED : Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Natural quick setting cement, that sets and hardens quickly, is produced exclusively by cooking argillaceous limestone of regular composition at moderate temperature (1000 to 1200 °C), extracted from homogenous beds and subject to very fine milling. It is composed mainly of tricalcium silicate (3CaO.SiO2 ) (CAS : 12168-853, EINECS : 235-336-9), dicalcium silicate (2CaO.SiO2) (CAS : 10034-77-2, EINECS : 233-107-8), tricalcium aluminate (3CaO.Al2O3) (CAS : 12042-78-3, EINECS : 234-932-6) and calcium ferroaluminate (4CaO.Al2O3.Fe2O3) (CAS : 12068-35-8, EINECS : 235-094-4), calcite (CaCO3) (CAS : 471-31-1, EINECS : 207-439-9), de spurrite (Ca5(SiO4)2(CO3)) (CAS : 11140-12-8) and small quantities of lime, magnesia, sodium sulphate, potassium and calcium and traces of other elements. Natural quick setting cement contains small quantities of insolubles in which free silica may possibly be found (CAS: 14808-60-4; EINECS ; 238-878-4) CNP PM NF quick setting cement complies naturally with the requirements of directive 2003/53/CE and as a consequence, does not require the addition of soluble chromium VI reducing agent

Chemical Name CAS Number Concentration Hazardous
Clinker of natural quick setting cement EC: 266-043-4 65997-15-1 100% Yes
N/A --- --- No
dicalcium silicate EC: 233-107-8 10034-77-2 --- No
tricalcium aluminate EC: 234-932-6 12042-78-3 --- No
calcium ferroaluminate EC: 235-094-4 12068-35-8 --- No
calcite EC: 207-439-9 471-31-1 --- No
spurrite 11140-12-8 --- No
N/A --- --- No
N/A --- --- No
N/A --- --- No
N/A --- --- No
N/A --- --- No
free silica EC: 238-878-4 14808-60-4 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Where significant accidental inhalation occurs, take the individual into the fresh air. The throat and nostrils should clear themselves. Consult a doctor if persistent irritation occurs, or in case the subsequent appearance of discomfort, coughing or any other symptoms.

Symptoms: Cement may irritate the throat and respiratory tract. Coughs, sneezing and respiratory discomfort may appear in circumstances where the limit value of occupational exposure is exceeded.

Skin contact

If the cement is dry: Wipe off as much as possible. Rinse with plenty of water. If the cement is mixed: Rinse with plenty of water. Remove clothing, shoes, watches and other objects that have become contaminated and clean thoroughly before reuse. In case of irritation, redness or burns, consult a doctor.

Symptoms: Contact with the skin: of dry cement in contact with slightly wet skin or exposure to wet or mixed cement may lead to thickening of the skin and the appearance of fissures or cracks. Prolonged contact combined with abrasions may cause severe burns.

Eye contact

Do not rub in order to avoid further damage to the cornea. If need be, remove contact lenses, then rinse immediately with copious amounts of clean water for at least 15 minutes, keeping the eyelids wide apart in order to eliminate any residue. If possible, use isotonic water (0.9% NaCL). Consult an occupational doctor or ophthalmologist.

Symptoms: Direct contact may damage the cornea due to rubbing, may cause immediate or subsequent irritation or inflammation. Larger quantities of dry cement or splashes of mixed cement may lead to consequences ranging from moderate irritation (conjunctivitis or blepharitis) to chemical burns and blindness.

Ingestion

In case of significant accidental ingestion do not induce vomiting. If the person is conscious, rinse their mouth with water. Call a doctor immediately or an anti-poison centre.

Symptoms: Burns to mouth, oesophagus and gastrointestinal tract, nausea, vomiting.

Immediate Medical Attention

Consult a doctor if persistent irritation occurs, or in case the subsequent appearance of discomfort, coughing or any other symptoms (inhalation). In case of irritation, redness or burns, consult a doctor (skin). Consult an occupational doctor or ophthalmologist (eye). Call a doctor immediately or an anti-poison centre (ingestion).

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Any extinguishing agent can be used

Specific hazards

Cement is neither combustible, nor explosive and will not aid or feed the combustion of other materials

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Do not allow product to spread into the environment Do not pour down the drains, into the sewer system or into water courses (eg. streams)

Cleanup methods

Clean up dry cement using methods that do not cause the dispersion of the dry product into the air, for example: - suction cleaners (portable industrial strength, equipped with an effective air particle filter (HEPA filter) or some other equivalent technique) - floorcloths, damp brushes or hosepipe with spray attachment (set to "fine spray" in order to avoid dispersing the product into the air) Recover the resulting slurry If the product cannot be removed dry using a suction cleaner or made wet, make sure that staff responsible for sweeping it up dry wear appropriate individual protection equipment and that further dispersion of dust is prevented Place the recovered product in a closed container. Arrange for its collection before disposing of it as indicated in section 13 Recover waste cement and place it in a closed container. Wait until it sets and becomes solid before disposing of it as indicated in section 13

Materials: suction cleaners (portable industrial strength, equipped with an effective air particle filter (HEPA filter) or some other equivalent technique), floorcloths, damp brushes or hosepipe with spray attachment

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid the formation or spread of dust in the atmosphere; Avoid contact with skin and eyes; Do not breathe dust

Storage

Bulk cement must be stored in silos that are watertight, dry, clean and protected from all contamination. Cement in bags must be stored with the bags closed, off the ground, and in a cool and dry atmosphere, protected from excessive draught which would lead to a deterioration of the quality of the product

Hygiene

Do not eat, drink or smoke while handling cement in order to avoid all contact with the skin or mouth. Wash your hands immediately after handling cement or products containing cement. Remove clothing, shoes, watches and other contaminated objects and wash them separately and thoroughly before reuse

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure good ventilation of the work station

Hands

Protective gloves made from waterproof nitrile rubber or neoprene, using material containing little soluble Cr (VI), with a cotton lining. These gloves must be waterproof and resistant to wear and alkalis. Gloves are only effective as long as cement particles do not penetrate between the gloves and the skin. The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and the resultant standard EN 374

Eyes

Handling of dry or mixed cement: Approved goggles or watertight goggles complying with NF EN 166

Respiratory

Suitable anti-dust mask. Filter type FFP2

Skin/Body

Protective clothing with long elasticated cuffs and closed neck. Boots . Take care that mixed cement does not penetrate inside your boots. For work where kneeling in involved, waterproof knee-pads are required. As far as possible, avoid kneeling on mortar or fresh concrete (eg: when concreting a floor, laying screed, ...)

Environmental

Take all necessary precautions to avoid the accidental release of the product outside, due to the rupture of containers or transfer systems

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Dry cement is a fine inorganic substance (powder)
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
buff
Colour Intensity
---
Form
powder
Odor
---
Odor Threshold
Not determined
Ph
11-13,5 (Aqueous solution)
Melting Point
> 1000 °C
Boiling Point
Not applicable
Flash Point
Not applicable (non-flammable solid)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable
Vapor Pressure
Not determined
Vapor Density
Not applicable
Relative Density
---
Bulk Density
0,8 - 1,1 g/cm³ (20 °C)
Density
2,80 - 3,20 g/cm³ (20 °C)
Flammability
Not applicable (non-flammable solid)
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
Not applicable
Decomposition Temperature
Not determined
Solubility
---
Partition Coefficient
Not applicable (inorganic substance)
Solubility In Water
Slightly soluble : 0.1 - 1.5 g/l (20 °C)
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Not applicable
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Dry cement remains stable as long as it is stored correctly (see section 7) and is compatible with most other building materials. When mixed with water, cement hardens into a stable mass which does not react in ordinary environments. Wet cement is alkaline and incompatible with acids, with ammonium salts, with aluminium or other non-noble metals. Cement dissolves in hydrofluoric acid to produce corrosive silicon tetrafluoride gas. Cement reacts with water to form silicates and calcium hydroxide. Silicates in cement react with powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen difluoride

Reactivity

To our knowledge, the product does not present any particular risk. When mixed with water, the product will harden into a stable mass that is not reactive in normal environments

Hazardous reactions

None, to our knowledge

Avoid

Damp may cause cement to harden (formation of lumps) and a loss of quality of the product

Incompatible

Aluminium ( Formation of hydrogen in mixed cement in case of uncontrolled used ), Acids, Ammonium salts

Decomposition

None, to our knowledge. Cements do not break down into dangerous sub-products and are not subject to polymerization

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
Not restricted
Shipping Name
Not restricted
Transport Class
Not restricted
Packing Group
Not restricted
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is CNP PM NF cement known by?

CNP PM NF cement is also known as: natural quick setting cement

What is the hazard signal word for CNP PM NF cement?

The signal word is danger.

What is the physical form of CNP PM NF cement?

CNP PM NF cement is a dry cement is a fine inorganic substance (powder) with buff color.

What is CNP PM NF cement used for?

Concrete, mortar, grout, construction products

What are the hazard statements for CNP PM NF cement?

This substance has 4 hazard statements:

  • H315: Causes skin irritation
  • H317: May cause an allergic skin reaction
  • H318: Causes serious eye damage
  • H335: May cause respiratory irritation

What is the melting point of CNP PM NF cement?

The melting point is > 1000 °C and the boiling point is Not applicable.

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