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Safety Data Sheet EN

Hydroxylamine hydrochloride

CAS 5470-11-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hydroxylamine hydrochloride
Product Code
255580

Regulatory Identifiers

CAS Number
5470-11-1 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Uses advised against

The product is being supplied under the TSCA R&D Exemption (40 CFR Section 720.36). It is the recipient’s responsibility to comply with the requirements of the R&D exemption. The product may not be used for a non-exempt commercial purpose under TSCA unless appropriate consent is granted in writing by MilliporeSigma.

Manufacturers & Suppliers

S

Sigma-Aldrich Inc.

national supplier

3050 SPRUCE ST ST. LOUIS MO 63103 UNITED STATES

+1 314 771-5765

Emergency Contacts

CHEMTREC

800-424-9300

24 Hours/day; 7 Days/week

CHEMTREC

+1-703-527-3887

24 Hours/day; 7 Days/week

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Met. Corr. Cat. 1 H290
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2A H319
Skin Sens. Cat. 1 H317
Carc. Cat. 2 H351
STOT RE Cat. 2 H373
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H290 May be corrosive to metals.
H302 + H312 Harmful if swallowed or in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs (spleen) through prolonged or repeated exposure if swallowed.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original container.
P260 Do not breathe dust.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing must not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P390 Absorb spillage to prevent material damage.
P391 Collect spillage.
P405 Store locked up.
P406 Store in corrosive resistant container with a resistant inner liner.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth.
IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Hydroxylammonium chloride EC: 226-798-2 5470-11-1 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

Immediate Medical Attention

No data available

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Nitrogen oxides (NOx) Hydrogen chloride gas Ambient fire may liberate hazardous vapours. Container explosion may occur under fire conditions. May explode when heated.

Instructions

Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up dry. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

No metal containers. Tightly closed and away from sources of ignition and heat. Observe national regulations. Air and moisture sensitive.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.

Fire prevention

away from sources of ignition and heat.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g., KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L. Splash contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L.

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

Recommended Filter type: Filter type P3. The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Kinematic Viscosity
---
Ph
2.5 - 3.5 at 50 g/l at 20 °C (68 °F)
Boiling Point
No data available
Metal Corrosion
---
Vapor Pressure
0.001 hPa at 50 °C (122 °F)
Relative Density
No data available
Crystallisation Point
---
Colour
white
Vapor Density
No data available
Auto Ignition Temperature
No data available
Softening Point
---
Solubility In Water
ca.470 g/l at 20 °C (68 °F)
Physical State
solid
Appearance
Crystalline powder, Chunks
Colour Intensity
---
Freezing Point
No data available
Bulk Density
---
Dynamic Viscosity
---
Evaporation Rate
No data available
Flash Point
()Not applicable
Solubility In Fat
---
Form
Crystalline powder, Chunks
Solidification Point
---
Density
1.67 g/cm3 at 25 °C (77 °F) - lit.
Upper Explosive Limit
No data available
State Under Standard Conditions
---
Partition Coefficient
- Not applicable for inorganic substances
Melting Point
155 - 157 °C (311 - 315 °F) - dec.
Voc Content
---
Cloud Point
---
Flammability
The product is not flammable. - Flammability (solids)
Lower Explosive Limit
No data available
Physical State Data
solid
Properties Status
---
Explosive Limits
---
Solubility
---
Odor
slight chlorine
Molecular Weight
---
Odor Threshold
No data available
Relative Evaporation Rate
---
Decomposition Temperature
> 150 °C (> 302 °F)
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature) .

Reactivity

sensitive to shock Risk of dust explosion.

Hazardous reactions

Violent reactions possible with: alkaline substances Possible formation of: hydroxylamine Risk of explosion with: fire-promoting substances Oxidizing agents

Avoid

Air Exposure to moisture. May be unstable at temperatures above: 75° C Heating (decomposition). no information available

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3260
Shipping Name
Corrosive solid, acidic, inorganic, n.o.s.
Transport Class
8
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hydroxylamine hydrochloride?

The signal word is warning.

What is the physical form of Hydroxylamine hydrochloride?

Hydroxylamine hydrochloride is a solid appearing as crystalline powder, chunks with white color. It has slight chlorine odor.

What is Hydroxylamine hydrochloride used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Hydroxylamine hydrochloride?

This substance has 9 hazard statements:

  • H290: May be corrosive to metals.
  • H302 + H312: Harmful if swallowed or in contact with skin.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H351: Suspected of causing cancer.
  • H373: May cause damage to organs (spleen) through prolonged or repeated exposure if swallowed.
  • H400: Very toxic to aquatic life.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Hydroxylamine hydrochloride?

The melting point is 155 - 157 °C (311 - 315 °F) - dec. and the boiling point is No data available.

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