CN70455

Remove exposed person to fresh air if adverse effects are observed.

Take off contaminated clothing and wash before re-use. Wash skin thoroughly with soap and water. Launder contaminated clothing before reuse.

Symptoms: Skin irritation, symptoms occur.

Rinse cautiously with water for several minutes. Flush thoroughly with water. Remove contact lenses, if present and easy to do. Continue rinsing.

Symptoms: Irritation, persistent eye irritation.

Rinse mouth.

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Do not use water jet as an extinguisher, as this will spread the fire.

A solid stream of water will spread the burning material. Material creates a special hazard because it floats on water. See section 10 for additional information.

No data available.

Dike far ahead of larger spill for later recovery and disposal.

Avoid release to the environment. Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so.

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

When heating to normal handling temperatures, avoid local overheating. Heating above the maximum handling temperature can generate hazardous decomposition products (see Section 10). Additional handling information may be found in the American Chemistry Council document "Safe Handling Guidelines for ZDDP Components and Blends" (www.americanchemistry.com). Avoid contact with skin. Avoid contact with eyes. In case of spills, beware of slippery floors and surfaces.

Avoid excessive heat. Do not store near flammable agents. Store away from incompatible materials. See section 10 for incompatible materials. Odorous and toxic fumes may form from the decomposition of this product if stored at temperatures in excess of 113 deg F (45 deg C) for extended periods of time or if heat sources in excess of 250 deg F (121 deg C) are used.

Observe good industrial hygiene practices. Wash hands thoroughly after handling. Launder contaminated clothing before reuse.

Use grounding and bonding connection when transferring material. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures.

Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. The correct choice of protective gloves depends upon the chemicals being handled, and the conditions of work and use. Most gloves provide protection for only a limited time before they must be discarded and replaced (even the best chemically resistant gloves will break down after repeated chemical exposures). Gloves should be chosen in consultation with the supplier / manufacturer and taking account of a full assessment of the working conditions. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For applications involving mechanical risks with potential for abrasion or puncture, the standards set out in EN 388 should be considered. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. If suitable gloves are not available to offer that level of protection, gloves with shorter breakthrough times may be acceptable as long as appropriate glove maintenance and replacement regimes are determined and adhered to. For short-term, transient exposures and splash protection, gloves with shorter breakthrough times may commonly be used. Therefore, appropriate maintenance and replacement regimes must be determined and rigorously followed. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm. It is important to note that glove thickness is not the only predictor of glove resistance to a specific chemical, as the permeation efficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection should also be based on consideration of the task requirements and knowledge of breakthrough times. Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the manufacturers' technical data should always be taken into account to ensure selection of the most appropriate glove for the task. Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example: Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these gloves are only likely to give short duration protection and would normally be just for single use applications, before being disposed of. Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there is abrasion or puncture potential.

Wear tight-fitting goggles or face shield. Safety glasses. If potential for splash or mist exists, wear chemical goggles or faceshield. Eye protection should meet the standards set out in EN 166.

A respiratory protection program compliant with all applicable regulations must be followed whenever workplace conditions require the use of a respirator. Use respirator with an organic vapor and dust/mist cartridge if the recommended exposure limit is exceeded. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment. The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions. Please refer to the relevant EN standards for the RPE selected.

Wear apron or protective clothing in case of contact. Do not wear rings, watches or similar apparel that could entrap the material.

No data available. See section 6 for details.

Material is stable under normal conditions.

No data available.

Will not occur.

Do not expose to excessive heat, ignition sources, or oxidizing materials.

Strong oxidizing agents. Strong mineral acids and strong oxidizing agents.

If heated to decomposition, the following substances may be formed: Hydrogen sulfide Alkyl mercaptans and sulfides may also be released. Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, nitrogen oxides, and other products of incomplete combustion.