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Safety Data Sheet EN

BUTYLGLYCOL

CAS 111-76-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
BUTYLGLYCOL
Chemical Name
2-butoxyethanol; ethylene glycol monobutyl ether butyl cellosolve

Regulatory Identifiers

CAS Number
111-76-2 Check regulations →

Identified Uses

process chemical, solvent(s)

Manufacturers & Suppliers

B

BASF SE

manufacturer

67056 Ludwigshafen, GERMANY

+49 621 60-42151

Emergency Contacts

International emergency number

+49 180 2273-112

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 4
Eye Irrit. Cat. 2A
Acute Tox. Cat. 4
Skin Irrit. Cat. 2

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H227 Combustible liquid.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P264 Wash contaminated body parts thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves and eye protection or face protection.
P280 Wear eye protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P330 Rinse mouth.
P332 + P313 If skin irritation occurs: Get medical attention.
P337 + P313 If eye irritation persists: Get medical attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P370 + P378 In case of fire: Use alcohol-resistant foam, carbon dioxide, dry powder or water spray for extinction.
P403 Store in a well-ventilated place.
P501 Dispose of contents and container to hazardous or special waste collection point.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
2-Butoxyethanol EC: 203-905-0 111-76-2 99 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Keep patient calm, remove to fresh air, seek medical attention.

Skin contact

Wash thoroughly with soap and water

Eye contact

Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

Ingestion

Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

Immediate Medical Attention

Seek medical attention.

Medical Treatment

Treat according to symptoms (decontamination, vital functions), no known specific antidote.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

dry powder, water spray, carbon dioxide, alcohol-resistant foam

Unsuitable media

water jet

Specific hazards

Flammable liquid.

Instructions

Cool endangered containers with water-spray. See SDS section 7 - Handling and storage. Extend fire extinguishing measures to the surroundings. Fight fire from maximum distance.

Firefighter Protection

Wear a self-contained breathing apparatus. Special protective equipment for firefighters

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Shut off or stop source of leak. Shut off or stop released substance/product under safe conditions. Pack in tightly closed containers for disposal.

Large spill

For large amounts: Pump off product.

Environmental

Discharge into the environment must be avoided.

Cleanup methods

For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).

Materials: sand, sawdust, general-purpose binder, kieselguhr

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Ensure thorough ventilation of stores and work areas. Prevent contact with air/oxygen (formation of peroxide).

Storage

Keep container tightly closed in a cool, well-ventilated place.

Fire prevention

Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Chemical resistant protective gloves (EN ISO 374-1). Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN ISO 374-1): butyl rubber (butyl) - 0.7 mm coating thickness. Manufacturer's directions for use should be observed because of great diversity of types. Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eyes

Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Respiratory

Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)

Skin/Body

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Explosive Limits
---
Decomposition Temperature
No decomposition if stored and handled as prescribed/indicated.
Metal Corrosion
---
Odor Threshold
not determined
Solidification Point
---
Upper Explosive Limit
10,6 % (V)
Relative Evaporation Rate
---
Cloud Point
---
Crystallisation Point
---
Properties Status
---
Auto Ignition Temperature
232 °C
Melting Point
-74,8 °C
Appearance
---
Solubility In Fat
---
Boiling Point
173,5 °C
Freezing Point
---
Physical State
liquid
Density
0,9000 g/cm3
Physical State Data
liquid
Odor
ether-like
Ph
miscible, neutral
Solubility In Water
900 g/l
Molecular Weight
118,18 g/mol
Bulk Density
---
Dynamic Viscosity
3,3 mPa.s
Colour
colourless
Flash Point
67 °C
Flammability
Combustible liquid.
Vapor Pressure
0,8 hPa; 1,17 hPa
State Under Standard Conditions
---
Colour Intensity
---
Form
liquid
Solubility
organic solvents soluble
Partition Coefficient
0,81
Vapor Density
---
Voc Content
---
Kinematic Viscosity
3,642 mm2/s
Softening Point
---
Relative Density
0,9000
Lower Explosive Limit
1,1 % (V)
Evaporation Rate
Value can be approximated from Henry's Law Constant or vapor pressure.
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable if stored and handled as prescribed/indicated.

Reactivity

No hazardous reactions if stored and handled as prescribed/indicated., When heated can give off ignitable vapours. Corrosion to metals: No corrosive effect on metal. Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.

Hazardous reactions

Reacts with light metals, with evolution of hydrogen. Reacts with strong oxidizing agents.

Avoid

No special precautions other than good housekeeping of chemicals.

Incompatible

strong oxidizing agents

Decomposition

No hazardous decomposition products if stored and handled as prescribed/indicated.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Must be disposed of or incinerated in accordance with local regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
ID9003
Shipping Name
SUBSTANCES WITH FLASH-POINT BETWEEN 60°C - 100°C (ETHYLENE GLYCOL MONOBUTYL ETHER)
Transport Class
9, N3, F
Packing Group
Not applicable
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety data sheet according to the United Nations' Globally Harmonized System (UN GHS)

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for BUTYLGLYCOL?

The signal word is warning.

What is the physical form of BUTYLGLYCOL?

BUTYLGLYCOL is a liquid with colourless color. It has ether-like odor.

What is the solubility of BUTYLGLYCOL?

organic solvents soluble

What is BUTYLGLYCOL used for?

process chemical, solvent(s)

What are the hazard statements for BUTYLGLYCOL?

This substance has 4 hazard statements:

  • H227: Combustible liquid.
  • H302: Harmful if swallowed.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.

What is the melting point of BUTYLGLYCOL?

The melting point is -74,8 °C and the boiling point is 173,5 °C.