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Safety Data Sheet EN

Dibutyl maleate for synthesis

CAS 105-76-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Dibutyl maleate for synthesis
Product Code
8.18688
Chemical Name
Dibutyl maleate

Regulatory Identifiers

CAS Number
105-76-0 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Chemical for synthesis

Manufacturers & Suppliers

S

Sigma-Aldrich Ireland Limited

national supplier

Vale Road, Arklow, CO WICKLOW, CO WICKLOW, IRELAND

+353 402-20300

Emergency Contacts

CHEMTREC

+(353)-19014670

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Sens. Cat. 1 H317
STOT RE Cat. 2 H373
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H317 May cause an allergic skin reaction.
H373 May cause damage to organs (Kidney) through prolonged or repeated exposure if swallowed.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P314 Get medical advice/ attention if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
di-n-butyl maleate EC: 203-328-4 105-76-0 100% Yes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Remove contact lenses.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2), Foam, Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides. Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up with liquid-absorbent material (e.g. Chemizorb®).

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

For precautions see section 2.2.

Storage

Tightly closed. Recommended storage temperature see product label.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: butyl-rubber, Minimum layer thickness: 0.7 mm, Break through time: 480 min, Material tested: Butoject® (KCL 898). Splash contact: Material: Chloroprene, Minimum layer thickness: 0.65 mm, Break through time: 120 min, Material tested: KCL 720 Camapren®. Compliance with EN374.

Eyes

Safety glasses, tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Required when vapours/aerosols are generated. Recommended Filter type: Filter type ABEK. Standards: DIN EN 143, DIN 14387.

Skin/Body

Protective clothing.

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Melting Point
No data available
Evaporation Rate
No data available
Cloud Point
---
Boiling Point
280 - 282 °C at 1,013 hPa
Physical State
oily to liquid
Vapor Pressure
No data available
Voc Content
---
Odor
No data available
Upper Explosive Limit
3.4 % (V)
Form
oily to liquid
Vapor Density
No data available
Freezing Point
No data available
Solidification Point
---
Relative Density
No data available
Appearance
Form: oily to liquid Color: colorless
Metal Corrosion
---
Solubility
---
Dynamic Viscosity
No data available
Flammability
No data available
Colour Intensity
---
Colour
colorless
Relative Evaporation Rate
---
Partition Coefficient
No data available
Solubility In Fat
---
Decomposition Temperature
No data available
Ph
No data available
Softening Point
---
Crystallisation Point
---
Bulk Density
---
State Under Standard Conditions
---
Properties Status
---
Lower Explosive Limit
0.5 % (V)
Molecular Weight
---
Physical State Data
liquid
Auto Ignition Temperature
No data available
Solubility In Water
No data available
Kinematic Viscosity
No data available
Explosive Limits
---
Flash Point
120 °C - DIN 51758
Odor Threshold
No data available
Density
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical.

Hazardous reactions

increased reactivity with: Strong oxidizing agents

Avoid

Strong heating.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Waste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste.

Disposal

Leave chemicals in original containers. No mixing with other waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (di-n-butyl maleate)
Transport Class
9
Packing Group
III
ADR

EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

IMDG

EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

IATA

EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed

Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Dibutyl maleate for synthesis?

The signal word is warning.

What is the physical form of Dibutyl maleate for synthesis?

Dibutyl maleate for synthesis is a oily to liquid appearing as form: oily to liquid color: colorless with colorless color. It has no data available odor.

What is Dibutyl maleate for synthesis used for?

Chemical for synthesis

What are the hazard statements for Dibutyl maleate for synthesis?

This substance has 3 hazard statements:

  • H317: May cause an allergic skin reaction.
  • H373: May cause damage to organs (Kidney) through prolonged or repeated exposure if swallowed.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Dibutyl maleate for synthesis?

The melting point is No data available and the boiling point is 280 - 282 °C at 1,013 hPa.