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Safety Data Sheet EN

Diethanolamine pure

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Diethanolamine pure
Chemical Name
Diethanolamine

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Chemical used in synthesis and/or formulation of industrial products, Chemical

Uses advised against

Due to the possibility of nitrosamine formation in water-miscible or water-based cooling lubricants should not contain more than 0,25% Diethanolamine in its application state.

Manufacturers & Suppliers

B

BASF Australia Limited (ABN 62 008 437 867)

manufacturer

Level 12, 28 Freshwater Place Southbank Victoria 3006, AUSTRALIA

+61 3 8855-6600

Emergency Contacts

BASF

1800 803 440

24h

BASF

+61 3 8855 6666

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4
Skin Irrit. Cat. 2
Eye Dam. Cat. 1
Repr. Cat. 2
Repr. Cat. 2
STOT RE Cat. 2
Aquatic Acute Cat. 2

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H361 Suspected of damaging fertility. Suspected of damaging the unborn child.
H373 May cause damage to organs (Kidney, Liver, Blood, Central nervous system) through prolonged or repeated exposure.
H401 Toxic to aquatic life.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/gas/mist/vapours.
P264 Wash contaminated body parts thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing and eye protection or face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or physician.
P330 Rinse mouth.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P405 Store locked up.
P501 Dispose of contents and container to hazardous or special waste collection point.
IF ON SKIN (or hair): Wash with plenty of soap and water.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

amine

Chemical Name CAS Number Concentration Hazardous
2,2'-iminodiethanol 111-42-2 99.6 - 99.9% Yes
2-aminoethanol 141-43-5 0.3% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.

Skin contact

Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

Eye contact

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

Ingestion

Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

Medical Treatment

Treat according to symptoms (decontamination, vital functions), no known specific antidote.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

water spray, dry powder, foam, carbon dioxide

Specific hazards

nitrogen oxides, carbon oxides

Firefighter Protection

Wear self-contained breathing apparatus and chemical-protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid contact with the skin, eyes and clothing. Avoid breathing dust/fume/gas/mist/vapours/spray. Handle in accordance with good industrial hygiene and safety practice.

Small spill

For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).

Large spill

For large amounts: Pump off product.

Environmental

Do not discharge into drains/surface waters/groundwater.

Cleanup methods

Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations.

Materials: water and detergents

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke.

Storage

Segregate from acids and acid forming substances. Storage temperature: < 40 °C. May discolour after lengthy storage.

Hygiene

When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.

Fire prevention

fire extinguishers should be kept handy.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Chemical resistant protective gloves (EN ISO 374-1). Performance level 6, corresponding to a breakthrough time of >480 min according to EN ISO 374-1. Recommended materials: fluoroelastomer (FKM) - 0.7 mm coating thickness, Polyethylene-Laminate (PE laminate) - ca. 0.1 mm coating thickness, butyl rubber (butyl) - 0.7 mm coating thickness, polyvinylchloride (PVC) - 0.7 mm coating thickness, nitrile rubber (NBR) - 0.4 mm coating thickness, chloroprene rubber (CR) - 0.5 mm coating thickness. Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Wear chemical resistant protective gloves.

Eyes

Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Respiratory

Breathing protection if breathable aerosols/dust are formed. Combination filter for gases/vapours of organic compounds and solid and liquid particles (f.e. EN 14387 Type A-P2)

Skin/Body

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Molecular Weight
105.14 g/mol
Softening Point
---
Kinematic Viscosity
357.2 mm2/s (30 °C)
Crystallisation Point
---
Flammability
not flammable
Odor Threshold
Not determined due to potential health hazard by inhalation.
Solidification Point
---
Vapor Pressure
0.000085 hPa (20 °C)
Odor
mild, ammonia-like
Vapor Density
---
Melting Point
27.4 °C
Relative Density
1.09 (20 °C)
Ph
11.3 (100 g/l, 30 °C)
Solubility In Water
miscible
Solubility
---
Upper Explosive Limit
10.6 % (V) (193 °C)
Evaporation Rate
---
Relative Evaporation Rate
---
Partition Coefficient
-2.18 (25 °C; pH value: 7.1)
Dynamic Viscosity
390.9 mPa.s (30 °C)
Lower Explosive Limit
2.1 % (V) (156 °C)
Cloud Point
---
Freezing Point
---
Colour Intensity
---
Density
1.0953 g/cm3 (23.8 °C)
Boiling Point
269.9 °C (1,013 hPa)
Physical State Data
liquid
Bulk Density
1.09 g/cm3 (20 °C)
Properties Status
---
Decomposition Temperature
125 °C, 40 kJ/kg (DSC (OECD 113)); 310 °C, > 380 kJ/kg (DSC (OECD 113))
Auto Ignition Temperature
375 °C
Solubility In Fat
---
State Under Standard Conditions
---
Metal Corrosion
---
Flash Point
176 °C
Voc Content
---
Form
liquid, solidified
Appearance
---
Physical State
liquid, solidified
Explosive Limits
---
Colour
colourless
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Hazardous reactions

Reacts with acids. The progress of reaction is exothermic. Reacts with oxidizing agents. Reacts with halogenated compounds. Reacts with acid chlorides. Incompatible with acid chlorides and acid anhydrides. In the presence of nitrosating agents this substance can form nitrosamines.

Avoid

Temperature: 60 °C. Avoid excessive temperatures.

Incompatible

oxidizing agents, nitrosating agents, acid forming substances, acids, isocyanates, acid chlorides, acid anhydrides

Decomposition

nitrosamines, No hazardous decomposition products if stored and handled as prescribed/indicated. Possible thermal decomposition products: carbon oxides, nitrogen oxides, nitrous gases, The substances/groups of substances mentioned can be released in case of fire.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
Not applicable
Shipping Name
Not applicable
Transport Class
Not applicable
Packing Group
Not applicable
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Diethanolamine pure?

The signal word is danger.

What is the physical form of Diethanolamine pure?

Diethanolamine pure is a liquid, solidified with colourless color. It has mild, ammonia-like odor.

What is Diethanolamine pure used for?

Chemical used in synthesis and/or formulation of industrial products, Chemical

What are the hazard statements for Diethanolamine pure?

This substance has 6 hazard statements:

  • H302: Harmful if swallowed.
  • H315: Causes skin irritation.
  • H318: Causes serious eye damage.
  • H361: Suspected of damaging fertility. Suspected of damaging the unborn child.
  • H373: May cause damage to organs (Kidney, Liver, Blood, Central nervous system) through prolonged or repeated exposure.
  • H401: Toxic to aquatic life.

What is the melting point of Diethanolamine pure?

The melting point is 27.4 °C and the boiling point is 269.9 °C (1,013 hPa).

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