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Safety Data Sheet EN

Hydroquinone

CAS 123-31-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hydroquinone
Product Code
H329-500
Synonyms
1,4-Dihydroxybenzene; 1,4-Benzenediol

Regulatory Identifiers

CAS Number
123-31-9 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Not for food, drug, pesticide or biocidal product use

Manufacturers & Suppliers

F

Fisher Scientific

distributor

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

Emergency Contacts

CHEMTREC®

800-424-9300

CHEMTREC®

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4
Eye Dam. Cat. 1
Skin Sens. Cat. 1
Muta. Cat. 2
Carc. Cat. 2
STOT SE Cat. 3

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

EUH014 May form combustible dust concentrations in air
H302 Harmful if swallowed
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H351 Suspected of causing cancer

Precautionary Statements

P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash face, hands and any exposed skin thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves
P281 Use personal protective equipment as required
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P304 + P341 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P308 + P313 IF exposed or concerned: Get medical attention/advice
P310 Immediately call a POISON CENTER or doctor/physician
P330 Rinse mouth
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention
P363 Wash contaminated clothing before reuse
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
Hydroquinone 123-31-9 99% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If breathing is difficult, give oxygen. Obtain medical attention.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention.

Symptoms: May cause allergic skin reaction. Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Symptoms: Causes eye burns.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable media

No information available

Specific hazards

Fine dust dispersed in air may ignite. Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources of ignition. Do not allow run-off from fire fighting to enter drains or water courses.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment. Ensure adequate ventilation. Avoid dust formation.

Environmental

Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Avoid release to the environment.

Cleanup methods

Sweep up or vacuum up spillage and collect in suitable container for disposal.

Materials: suitable container

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment. Ensure adequate ventilation. Avoid dust formation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place.

Hygiene

Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.

Eyes

Tightly fitting safety goggles.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Skin/Body

Long sleeved clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Off-white
Colour
---
Colour Intensity
---
Form
---
Odor
Odorless
Odor Threshold
No information available
Ph
3.75 - 70 g/l aq.sol
Melting Point
170 - 174 °C / 338 - 345.2 °F
Boiling Point
285 - 287 °C / 545 - 548.6 °F @ 760 mmHg
Flash Point
165 °C / 329 °F
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable
Vapor Pressure
1 mmHg @ 132 °C
Vapor Density
Not applicable
Relative Density
1.320
Bulk Density
---
Density
---
Flammability
No information available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
520 °C / 968 °F
Decomposition Temperature
No information available
Solubility
soluble
Partition Coefficient
No data available
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
110.11
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. None under normal processing.

Avoid

Avoid dust formation. Incompatible products. Excess heat.

Incompatible

Strong oxidizing agents, Strong bases, Alkaline

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO₂)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3077
Shipping Name
Environmentally hazardous substance, solid, n.o.s.
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Hydroquinone known by?

Hydroquinone is also known as: 1,4-Dihydroxybenzene; 1,4-Benzenediol

What is the hazard signal word for Hydroquinone?

The signal word is danger.

What is the physical form of Hydroquinone?

Hydroquinone is a solid appearing as off-white . It has odorless odor.

What is the solubility of Hydroquinone?

soluble

What is Hydroquinone used for?

Laboratory chemicals.

What are the hazard statements for Hydroquinone?

This substance has 7 hazard statements:

  • EUH014: May form combustible dust concentrations in air
  • H302: Harmful if swallowed
  • H317: May cause an allergic skin reaction
  • H318: Causes serious eye damage
  • H335: May cause respiratory irritation
  • H341: Suspected of causing genetic defects
  • H351: Suspected of causing cancer

What is the melting point of Hydroquinone?

The melting point is 170 - 174 °C / 338 - 345.2 °F and the boiling point is 285 - 287 °C / 545 - 548.6 °F @ 760 mmHg.