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Safety Data Sheet EN

Zinc Clad® R Plus Comp. A

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Zinc Clad® R Plus Comp. A
Product Code
000000000000606965

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Coatings and paints, thinners, paint removers

Uses advised against

Reserved for industrial and professional use.

Manufacturers & Suppliers

S

Sherwin-Williams Coatings Deutschland GmbH

manufacturer

Rieter Tal 1, 71665 Vaihingen / Enz

+4970421090

Emergency Contacts

Supplier

+49 (0) 7042 109-0

Emergency contact available 24 hours a day

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3 H226
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H226 Flammable liquid and vapor.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing mist or vapors.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P391 Collect spillage.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
zinc powder — zinc dust (pyro-phoric) EC: 231-175-3 7440-66-6 70 - 90% Yes
reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight 700 - 1100) EC: 500-033-5 25068-38-6 5 - 10% Yes
xylene EC: 215-535-7 1330-20-7 2.5 - 10% Yes
1-methoxy-2-propanol EC: 203-539-1 107-98-2 1 - 10% Yes
4-morpholinecarbaldehyde EC: 224-518-3 4394-85-8 0.1 - 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician.

Symptoms: Mucous membrane and respiratory system irritation, headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness.

Skin contact

If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes.

Symptoms: Removal of natural fat from the skin, resulting in non-allergic contact dermatitis, absorption through the skin, skin irritation, allergic skin reaction.

Eye contact

Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.

Symptoms: Irritation, reversible damage, serious eye irritation.

Ingestion

Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Alcohol-resistant foam, Carbon dioxide (CO2), Dry chemical

Unsuitable media

High volume water jet

Specific hazards

Do not allow run-off from fire fighting to enter drains or water courses.

Firefighter Protection

Wear self-contained breathing apparatus for firefighting if necessary.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.

Environmental

Prevent product from entering drains. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).

Materials: non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Good housekeeping standards, regular safe removal of waste materials and regular maintenance of spray booth filters will minimise the risks of spontaneous combustion and other fire hazards. Avoid formation of aerosol. Do not breathe vapors/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitization problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.

Storage

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Hygiene

When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.

Fire prevention

Do not spray on a naked flame or any incandescent material. Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits.

Hands

Chemical resistant gloves made of butyl rubber or nitrile rubber category III according to EN 374. Glove length: Standard glove type. Guideline: Equipment should conform to EN 374. Protective equipment only chosen according to specific regulatory requirements after a risk assessment. Follow the instructions for use issued by the producer. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Eyes

Eye wash bottle with pure water. Safety glasses with side-shields conforming to EN166. Tightly fitting safety goggles. Wear face-shield and protective suit for abnormal processing problems.

Respiratory

Equipment should conform to EN 14387. General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Filter type: Combined particulates and organic vapor type (A-P).

Skin/Body

Protective equipment only chosen according to specific regulatory requirements after a risk assessment. Equipment should conform to EN 14605. Impervious clothing. Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Environmental

The product should not be allowed to enter drains, water courses or the soil.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
various, colorless
Colour Intensity
---
Form
liquid
Odor
slight
Odor Threshold
No data available
Ph
Not applicable substance/mixture is non-soluble (in water)
Melting Point
---
Boiling Point
---
Flash Point
closed cup: ca. 26 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
14,5297 hPa
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
2,55 g/cm3 (20 °C)
Flammability
---
Upper Explosive Limit
11,5 %(V)
Lower Explosive Limit
1 %(V)
Explosive Limits
---
Auto Ignition Temperature
ca. 270 °C
Decomposition Temperature
Not relevant/applicable due to the nature of the product.
Solubility
---
Partition Coefficient
Not relevant/applicable due to the nature of the product.
Solubility In Water
insoluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
> 20,5 mm2/s (40 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

No decomposition if stored and applied as directed.

Reactivity

No hazards to be specially mentioned.

Hazardous reactions

No dangerous reaction known under conditions of normal use.

Avoid

Temperatures greater than recommended storage temperature. Heat, flames and sparks.

Incompatible

Strong acids and strong bases, Strong oxidizing agents

Decomposition

No decomposition if stored and applied as directed.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1263
Shipping Name
PAINT
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Zinc Clad® R Plus Comp. A?

The signal word is warning.

What is the physical form of Zinc Clad® R Plus Comp. A?

Zinc Clad® R Plus Comp. A is a liquid with various, colorless color. It has slight odor.

What is Zinc Clad® R Plus Comp. A used for?

Coatings and paints, thinners, paint removers

What are the hazard statements for Zinc Clad® R Plus Comp. A?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapor.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H410: Very toxic to aquatic life with long lasting effects.