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Safety Data Sheet EN

1,2-Dichloroethane EMPLURA®

CAS 107-06-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
1,2-Dichloroethane EMPLURA®
Product Code
100955
Chemical Name
1,2-Dichloroethane

Regulatory Identifiers

CAS Number
107-06-2 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) No 1907/2006, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Reagent for analysis, Chemical production

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

64271 Darmstadt, Germany

+49 6151 72-0

Merck Pty. Limited logo

Merck Pty. Limited

regional supplier

Ground Floor, Building 1, 885 Mountain Highway, Bayswater VIC 3153 Australia

+61 (3) 8727 6300

http://www.merckmillipore.com

Emergency Contacts

Emergency Contact

+61 (3) 8727 6300

CHEMCALL

+64 4 917 9888

After hours

Poisons Information Centre

13 1126

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Carc. Cat. 1B H350
Acute Tox. Cat. 4 H302
Eye Irrit. Cat. 2 H319
STOT SE Cat. 3 H335
Skin Irrit. Cat. 2 H315

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapour.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H350 May cause cancer.

Precautionary Statements

P201 Obtain special instructions before use.
P210 Keep away from heat.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
1,2-Dichloroethane EC: 203-458-1 107-06-2 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air. Get medical attention.

Symptoms: Cough, respiratory paralysis, Shortness of breath

Skin contact

wash off with plenty of water. Remove contaminated clothing. Consult a physician.

Symptoms: irritant effects

Eye contact

rinse out with plenty of water. Call in ophthalmologist.

Symptoms: irritant effects

Ingestion

immediately make victim drink water (two glasses at most). Do not give milk, alcoholic beverages or castor oil. Consult a physician.

Medical Treatment

Subsequently administer: activated charcoal (20 - 40 g in 10% slurry). Laxative: Sodium sulfate (1 tablespoon/1/4 l water).

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Foam, Dry powder, Carbon dioxide (CO2)

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Vapours are heavier than air and may spread along floors. Forms explosive mixtures with air at ambient temperatures. Pay attention to flashback. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Remove container from danger zone and cool with water. Suppress (knock down) gases/vapours/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not empty into drains. Risk of explosion.

Cleanup methods

Take up with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid generation of vapours/aerosols. Observe label precautions.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Protected from light. Keep locked up or in an area accessible only to qualified or authorised persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: Glove material: Viton (R), Glove thickness: 0.70 mm, Break through time: > 480 min. splash contact: Glove material: polychloroprene, Glove thickness: 0.65 mm, Break through time: > 10 min. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 890 Vitoject® (full contact), KCL 720 Camapren® (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Safety glasses

Respiratory

required when vapours/aerosols are generated. Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Flame retardant antistatic protective clothing

Environmental

Do not empty into drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Appearance
---
Physical State
liquid
Dynamic Viscosity
0.82 - 0.84 mPa.s at 20 °C
Lower Explosive Limit
6 %(V)
Properties Status
---
Molecular Weight
---
Physical State Data
liquid
Melting Point
-35.5 °C
Vapor Density
---
Colour
colourless
Explosive Limits
---
Softening Point
---
Flash Point
13 °C Method: c.c.
Freezing Point
---
Evaporation Rate
4.1
Solubility In Water
8.7 g/l at 20 °C
Solubility
---
Boiling Point
83.5 - 84.1 °C at 1,013 hPa
Vapor Pressure
87 hPa at 20 °C
Colour Intensity
---
Crystallisation Point
---
Relative Evaporation Rate
---
Auto Ignition Temperature
No information available.
Density
1.25 g/cm³ at 20 °C
Odor
of solvents
Partition Coefficient
log Pow: 1.45 OECD Test Guideline 107 Bioaccumulation is not expected.
Upper Explosive Limit
11.4 %(V)
Metal Corrosion
---
Voc Content
---
Cloud Point
---
Decomposition Temperature
No information available.
Relative Density
No information available.
Kinematic Viscosity
---
Form
liquid
Solidification Point
---
Flammability
No information available.
Bulk Density
---
Solubility In Fat
---
Odor Threshold
No information available.
Ph
No information available.
State Under Standard Conditions
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Sensitivity to light

Reactivity

Vapours may form explosive mixture with air.

Hazardous reactions

Exothermic reaction with: Alkaline earth metals, alkali amides, Nitric acid, nitrogen oxides, Oxidizing agents, Chlorine, powdered magnesium, Zinc. Risk of explosion with: Alkali metals, powdered aluminium, Powdered metals, Potassium, nitrogen dioxide

Avoid

Warming. Exposure to light.

Incompatible

various plastics, Light metals, Iron

Decomposition

in the event of fire: See section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1184
Shipping Name
ETHYLENE DICHLORIDE
Transport Class
3 (6.1)
Packing Group
II
ADR

yes

IMDG

yes

IATA

no

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 1,2-Dichloroethane EMPLURA®?

The signal word is danger.

What is the physical form of 1,2-Dichloroethane EMPLURA®?

1,2-Dichloroethane EMPLURA® is a liquid with colourless color. It has of solvents odor.

What is 1,2-Dichloroethane EMPLURA® used for?

Reagent for analysis, Chemical production

What are the hazard statements for 1,2-Dichloroethane EMPLURA®?

This substance has 6 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H302: Harmful if swallowed.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H335: May cause respiratory irritation.
  • H350: May cause cancer.

What is the melting point of 1,2-Dichloroethane EMPLURA®?

The melting point is -35.5 °C and the boiling point is 83.5 - 84.1 °C at 1,013 hPa.