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Safety Data Sheet EN

Chlorine

CAS 7782-50-5
EC 231-959-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Chlorine
Product Code
295132
Chemical Name
Chlorine

Regulatory Identifiers

CAS Number
7782-50-5 Check regulations →
EC Number
231-959-5 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street SAINT LOUIS MO 63103 USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Ox. Gas Cat. 1 H270
Gases under pressure H280
Acute Tox. Cat. 3 H331
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2A H319
STOT SE Cat. 3 H335
Aquatic Acute Cat. 1 H400

GHS Pictograms

GHS03 - Oxidizing

GHS03

GHS04 - Compressed gas

GHS04

GHS06 - Acute toxicity

GHS06

GHS09 - Environmental hazard

GHS09

Hazard Statements

H270 May cause or intensify fire; oxidizer.
H280 Contains gas under pressure; may explode if heated.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.

Precautionary Statements

P220 Keep/Store away from clothing/ combustible materials.
P244 Keep reduction valves free from grease and oil.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear eye protection/ face protection.
P280 Wear protective gloves.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P370+P376 In case of fire: Stop leak if safe to do so.
P391 Collect spillage.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Chlorine EC: 231-959-5 7782-50-5 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Ingestion

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Material: Fluorinated rubber. Minimum layer thickness: 0.7 mm. Break through time: 480 min. Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M). Data source: KCL GmbH, test method: EN374. If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves.

Eyes

Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Molecular Weight
---
Boiling Point
-34 C (-29 F) - lit.
Softening Point
---
State Under Standard Conditions
---
Auto Ignition Temperature
No data available
Vapor Density
2.44 - (Air = 1.0)
Physical State Data
gas
Cloud Point
---
Appearance
---
Odor
pungent
Solubility In Fat
---
Colour Intensity
---
Crystallisation Point
---
Freezing Point
-101 C (-150 F) - lit.
Odor Threshold
No data available
Relative Evaporation Rate
---
Lower Explosive Limit
No data available
Decomposition Temperature
No data available
Solubility In Water
ca.10 g/l at 20 C (68 F)
Metal Corrosion
---
Bulk Density
---
Dynamic Viscosity
No data available
Evaporation Rate
No data available
Density
---
Form
Compressed gas
Physical State
Compressed gas
Solidification Point
---
Properties Status
---
Explosive Limits
---
Voc Content
---
Upper Explosive Limit
No data available
Melting Point
-101 C (-150 F) - lit.
Colour
yellow
Relative Density
1.563 g/cm3 at -33.99 C (-29.18 F)
Ph
1.8 at 6.4 g/l at 20 C (68 F)
Partition Coefficient
No data available
Solubility
---
Flammability
No data available
Vapor Pressure
6,399 hPa (4,800 mmHg) at 20 C (68 F)
Kinematic Viscosity
No data available
Flash Point
Not applicable
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1017
Shipping Name
Chlorine
Transport Class
2.3
IMDG

F-C, S-U

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Chlorine?

The signal word is danger.

What is the physical form of Chlorine?

Chlorine is a compressed gas with yellow color. It has pungent odor.

What is Chlorine used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Chlorine?

This substance has 7 hazard statements:

  • H270: May cause or intensify fire; oxidizer.
  • H280: Contains gas under pressure; may explode if heated.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H331: Toxic if inhaled.
  • H335: May cause respiratory irritation.
  • H400: Very toxic to aquatic life.

What is the melting point of Chlorine?

The melting point is -101 C (-150 F) - lit. and the boiling point is -34 C (-29 F) - lit..

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