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Safety Data Sheet EN

Manganese (IV) oxide

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Manganese (IV) oxide
Product Code
10805

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

Alfa Aesar, A Johnson Matthey Company logo

Alfa Aesar, A Johnson Matthey Company

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

http://www.alfa.com

Emergency Contacts

Health, Safety and Environmental Department

(978) 521-6300

During normal hours

CHEMTREC

(800) 424-9300

After normal hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3
Acute Tox. Cat. 4

GHS Pictograms

GHS06 - Acute toxicity

GHS06

Hazard Statements

H301 Toxic if swallowed.
H332 Harmful if inhaled.

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P304 + P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P341 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P321 Specific treatment (see label).
P330 Rinse mouth.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Chemical characterization: Description: (CAS#) Manganese (IV) oxide (CAS# 1313-13-9): 100%

Chemical Name CAS Number Concentration Hazardous
Manganese (IV) oxide EC: 215-202-6 1313-13-9 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.

Skin contact

Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Ingestion

Seek immediate medical advice.

Immediate Medical Attention

Seek immediate medical advice.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Product is not flammable. Use fire fighting measures that suit the surrounding fire.

Specific hazards

Promotes fire. This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.

Firefighter Protection

Wear self-contained respirator. Wear fully protective impervious suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation

Environmental

Do not allow material to be released to the environment without proper governmental permits.

Cleanup methods

Dispose contaminated material as waste according to item 13.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep container tightly sealed. Store in cool, dry place in tightly closed containers. Ensure good ventilation at the workplace.

Storage

Store in cool, dry conditions in well sealed containers. Keep container tightly sealed.

Fire prevention

Substance/product can reduce the ignition temperature of flammable substances. This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves

Eyes

Safety glasses

Respiratory

Use suitable respirator when high concentrations are present.

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Powder
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
Black
Colour Intensity
---
Form
Powder
Odor
Odorless
Odor Threshold
---
Ph
---
Melting Point
535°C (995°F) (dec)
Boiling Point
Not determined
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
Not determined
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
5.026 g/cm³
Flammability
---
Upper Explosive Limit
Not determined
Lower Explosive Limit
Not determined
Explosive Limits
---
Auto Ignition Temperature
Not determined
Decomposition Temperature
Not determined
Solubility
---
Partition Coefficient
---
Solubility In Water
Insoluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Decomposition will not occur if used and stored according to specifications.

Reactivity

Reacts with reducing agents, Reacts with flammable substances

Hazardous reactions

Reacts with reducing agents, Reacts with flammable substances

Avoid

Decomposition will not occur if used and stored according to specifications.

Incompatible

Reducing agents, easily oxidized materials, Acids, Aluminum/aluminum alloys, Interhalogens

Decomposition

Toxic metal oxide fume

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Consult state, local or national regulations to ensure proper disposal.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

For use only by technically qualified individuals.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Manganese (IV) oxide?

The signal word is danger.

What is the physical form of Manganese (IV) oxide?

Manganese (IV) oxide is a powder with black color. It has odorless odor.

What are the hazard statements for Manganese (IV) oxide?

This substance has 2 hazard statements:

  • H301: Toxic if swallowed.
  • H332: Harmful if inhaled.

What is the melting point of Manganese (IV) oxide?

The melting point is 535°C (995°F) (dec) and the boiling point is Not determined.