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Safety Data Sheet EN

Tri-o-tolyl phosphate

CAS 78-30-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Tri-o-tolyl phosphate
Product Code
51885

Regulatory Identifiers

CAS Number
78-30-8 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street, SAINT LOUIS MO 63103, USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
STOT SE Cat. 1 H370
Aquatic Acute Cat. 2 H401
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed.
H370 Causes damage to organs.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P307 + P311 IF exposed: Call a POISON CENTER or doctor/ physician.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Tri-o-tolyl phosphate 78-30-8 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

Eye contact

Flush eyes with water as a precaution.

Ingestion

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Firefighter Protection

Wear self-contained breathing apparatus for firefighting if necessary.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas.

Environmental

Discharge into the environment must be avoided.

Cleanup methods

Soak up with inert absorbent material

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.

Storage

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Handle in accordance with good industrial hygiene and safety practice.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

Eyes

Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate. Use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Form: liquid Colour: light yellow
Colour
light yellow
Colour Intensity
---
Form
liquid
Odor
odourless
Odor Threshold
No data available
Ph
No data available
Melting Point
11 °C (52 °F)
Boiling Point
476.49 °C (889.68 °F) at 1,013 hPa (760 mmHg)
Flash Point
110 °C (230 °F)
Freezing Point
11 °C (52 °F)
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
No data available
Vapor Density
No data available
Relative Density
1.2 g/cm³
Bulk Density
---
Density
---
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
No data available
Partition Coefficient
log Pow: 4.347
Solubility In Water
No data available
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

No data available

Hazardous reactions

No data available

Avoid

No data available

Incompatible

Strong oxidizing agents

Decomposition

Hazardous decomposition products formed under fire conditions. - Carbon oxides, Oxides of phosphorus

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Offer surplus and non-recyclable solutions to a licensed disposal company.

Disposal

Offer surplus and non-recyclable solutions to a licensed disposal company.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tri-o-tolyl phosphate)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Tri-o-tolyl phosphate?

The signal word is danger.

What is the physical form of Tri-o-tolyl phosphate?

Tri-o-tolyl phosphate is a liquid appearing as form: liquid colour: light yellow with light yellow color. It has odourless odor.

What is the solubility of Tri-o-tolyl phosphate?

No data available

What is Tri-o-tolyl phosphate used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Tri-o-tolyl phosphate?

This substance has 3 hazard statements:

  • H302: Harmful if swallowed.
  • H370: Causes damage to organs.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Tri-o-tolyl phosphate?

The melting point is 11 °C (52 °F) and the boiling point is 476.49 °C (889.68 °F) at 1,013 hPa (760 mmHg).