NextSDS Logo
te

tert-Butyl peroxide

DANGER liquid SDS/MSDS

Chemical Product Identification & Regulatory Data

Official chemical identifiers, CAS numbers, and regulatory compliance information

Basic Product Information

Product Name
tert-Butyl peroxide
Product Code
168521
Chemical Name
di- tert -butyl peroxide 617-001-00-2

Regulatory Identifiers

CAS Number

Chemical Abstracts Service registry number - unique identifier for chemical substances

EC Number

European Community number - used for regulatory compliance in EU/EEA

Uses Information

Identified Uses
Laboratory chemicals, Synthesis of substances

Overview

tert-Butyl peroxide (CAS: 110-05-4 ) is a clear, liquid substance commonly used laboratory chemicals, synthesis of substances.

Manage Your Safety Data Sheets

Organize and access your chemical safety data with ease.

GHS Hazard Classification & Safety Warnings

Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications

Classification Status

Classified

Signal Word

danger (Danger)

Hazard Classifications

Flam. Liq. Category 2 H225
Self-react. Category E H242
Muta. Category 2 H341
Aquatic Acute Category 3 H402
Aquatic Chronic Category 3 H412

GHS Hazard Pictograms & Safety Symbols

GHS02 GHS Hazard Pictogram: Flammable hazard - Fire risk materials including gases, liquids, and solids

GHS02

GHS08 GHS Hazard Pictogram: Serious health hazard - Carcinogenic, mutagenic, or toxic to organs

GHS08

GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions

Hazard Statements

  • H225: Highly flammable liquid and vapour.
  • H242: Heating may cause a fire.
  • H341: Suspected of causing genetic defects.
  • H412: Harmful to aquatic life with long lasting effects.

Precautionary Statements

  • P201: Obtain special instructions before use.
  • P202: Do not handle until all safety precautions have been read and understood.
  • P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
  • P220: Keep/Store away from clothing/ combustible materials.
  • P233: Keep container tightly closed.
  • P234: Keep only in original container.
  • P235: Keep cool.
  • P240: Ground/bond container and receiving equipment.
  • P241: Use explosion-proof electrical/ ventilating/ lighting equipment.
  • P242: Use only non-sparking tools.
  • P243: Take precautionary measures against static discharge.
  • P273: Avoid release to the environment.
  • P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
  • P281: Use personal protective equipment as required.
  • P303+P361+P353: IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P308+P313: IF exposed or concerned: Get medical advice/ attention.
  • P370+P378: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
  • P405: Store locked up.
  • P410: Protect from sunlight.
  • P411+P235: Store at temperatures not exceeding .? °C/ .? ºF. Keep cool.
  • P420: Store away from other materials.
  • P501: Dispose of contents/ container to an approved waste disposal plant.

Chemical Manufacturers & Supply Chain

Authorized suppliers, manufacturers, and distribution network information

Sigma-Aldrich

manufacturer

📍

3050 Spruce Street SAINT LOUIS MO 63103 USA

🌍

US

📞

+1 800-325-5832

📠

+1 800-325-5052

24/7 Emergency Response & Poison Control

Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies

CHEMTREC

📞

+1-703-527-3887

🌍

US

Chemical Composition & Hazardous Ingredients

Detailed component analysis, concentration ranges, and hazardous substance identification

Product Type

substance

General Composition

Di-tert-butyl peroxide

Chemical Components & Hazardous Substances

Chemical Name CAS Number Concentration Hazardous
di- tert -butyl peroxide 617-001-00-2
EC: 203-733-6
110-05-4 90-100% ⚠️ Hazardous

Emergency First Aid Measures

Critical first aid procedures for chemical exposure incidents and medical emergencies

🫁 Inhalation Exposure

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

🖐️ Skin Contact

Wash off with soap and plenty of water. Consult a physician.

👁️ Eye Contact

Flush eyes with water as a precaution.

🍽️ Ingestion/Swallowing

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Related Chemical Substances & Alternative Products

Similar chemicals with comparable safety profiles and industrial applications

Technical Specifications & Material Properties

Physical state, chemical properties, melting point, boiling point, and material characteristics

🧪 Physical State
liquid
Critical Property
📊 Physical State Data
liquid
📊 State Under Standard Conditions
Not available
👁️ Appearance
clear, liquid
🎨 Colour
light yellow
📊 Colour Intensity
Not available
📊 Form
Not available
👃 Odor
very faint
📊 Odor Threshold
No data available
🧪 Ph
No data available
🧊 Melting Point
-39.99 ℃ (-39.98 °F)
Critical Property
💨 Boiling Point
109 - 110 °℃ (228 - 230 °F)
Critical Property
🔥 Flash Point
1 °℃ (34 ºF)
Critical Property
📊 Freezing Point
Not available
📊 Softening Point
Not available
📊 Solidification Point
Not available
📊 Cloud Point
Not available
📊 Crystallisation Point
Not available
📊 Relative Evaporation Rate
Not available
💨 Evaporation Rate
No data available
💨 Vapor Pressure
53 hPa (40 mmHg) at 20 ℃ (68 ºF)
📊 Vapor Density
5.05 - (Air = 1.0)
📊 Relative Density
0.796 g/mL at 25 ℃ (77 ºF)
📊 Bulk Density
Not available
⚖️ Density
Not available
🔥 Flammability
No data available
📊 Upper Explosive Limit
No data available
📊 Lower Explosive Limit
No data available
📊 Explosive Limits
Not available
📊 Auto Ignition Temperature
No data available
📊 Decomposition Temperature
190 °C (374 ºF)
💧 Solubility
0.171 g/l at 20 °℃ (68 °F) - soluble
📊 Partition Coefficient
log Pow: 3.2 at 22 ℃ (72 ºF)
📊 Solubility In Water
0.171 g/l at 20 °℃ (68 °F) - soluble
📊 Solubility In Fat
Not available
📊 Molecular Weight
Not available
📊 Voc Content
Not available
📊 Metal Corrosion
Not available
📊 Dynamic Viscosity
Not available
📊 Kinematic Viscosity
Not available
📊 Properties Status
Not available

Exposure Controls & Personal Protective Equipment (PPE)

Occupational exposure limits, engineering controls, and required safety equipment

🏭 Engineering Controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

🧤 Hand Protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact Material: Nitrile rubber Minimum layer thickness: 0.2 mm Break through time: 480 min Material tested:Dermatril® P (KCL 743 / Aldrich Z677388, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 240 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail [email protected], test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

👁️ Eye Protection

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

😷 Respiratory Protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

🦺 Skin/Body Protection

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

🌍 Environmental Exposure Controls

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

Transportation & Shipping Information

UN numbers, shipping names, transport classes, and regulatory transport requirements

🏷️ UN Number

3107

📦 Proper Shipping Name

Organic peroxide type E, liquid (Di-tert-butyl peroxide)

⚠️ Transport Hazard Class

5.2

✈️ IATA Air Transport Precautions

Keep away from heat

Chemical Safety FAQ & Common Questions

Most frequently asked questions about safety, handling, storage, and regulatory compliance

What is the hazard signal word for tert-Butyl peroxide?

The signal word for this substance is "danger".

What is the physical form of tert-Butyl peroxide?

tert-Butyl peroxide is a liquid appearing as clear, liquid with light yellow color. It has very faint odor.

What is the solubility of tert-Butyl peroxide?

0.171 g/l at 20 °℃ (68 °F) - soluble

What is tert-Butyl peroxide used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for tert-Butyl peroxide?

This substance has 4 hazard statements: H225: Highly flammable liquid and vapour. H242: Heating may cause a fire. H341: Suspected of causing genetic defects. H412: Harmful to aquatic life with long lasting effects.

What is the melting point of tert-Butyl peroxide?

The melting point is -39.99 ℃ (-39.98 °F) and the boiling point is 109 - 110 °℃ (228 - 230 °F).