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Safety Data Sheet EN

Na-Methylate sol. 30 % ZeroPCF

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Na-Methylate sol. 30 % ZeroPCF

Regulatory Identifiers

CAS Number
N/A
UFI Code
3D4V-EF2J-800Q-8QDC

Identified Uses

industrial chemicals

Manufacturers & Suppliers

B

BASF SE

manufacturer

67056 Ludwigshafen, GERMANY

+49 621 60 42737

Emergency Contacts

Emergency Contact

+49 180 2273-112

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Met. Corr. Cat. 1 H290
Acute Tox. Cat. 3 H331
Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H311
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 1 H370

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapour.
H290 May be corrosive to metals.
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H370 Causes damage to organs.

Precautionary Statements

P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves, protective clothing and eye protection or face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or physician.
P403 + P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents and container to hazardous or special waste collection point.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Preparation based on: sodium methanolate, methanol

Chemical Name CAS Number Concentration Hazardous
Methanol EC: 200-659-6 67-56-1 50 - 75% Yes
sodium methoxide EC: 204-699-5 124-41-4 25 - 50% Yes
Sodium Hydroxide (NaOH) EC: 215-185-5 1310-73-2 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Keep patient calm, remove to fresh air, seek medical attention.

Symptoms: Irritates the respiratory tract.

Skin contact

Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

Symptoms: Skin corrosion.

Eye contact

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

Symptoms: Irritates the eyes, potential for blindness.

Ingestion

Immediately rinse mouth and then drink 200 - 300 ml water, do not induce vomiting, seek medical attention. Administer 50 ml of pure ethanol in a drinkable concentration. Seek medical attention.

Symptoms: Information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11.

Immediate Medical Attention

Symptomatic treatment (decontamination, vital functions).

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ventilation systems and respiratory protection may be necessary if ventilation is inadequate. Suitable methods to assess inhalation exposure include European Standards EN 482, 689 and 14042. TRGS 402 must be observed in Germany.

Hands

Chemical resistant protective gloves (EN ISO 374-1). Suitable materials with prolonged, direct contact (Protective index 6, > 480 minutes permeation time according to EN ISO 374-1): butyl rubber (0.7 mm), fluoroelastomer (FKM) (0.7 mm). Suitable materials for short-term contact (Protective index 2, > 30 minutes permeation time according to EN ISO 374-1): nitrile rubber (NBR) (0.4 mm), chloroprene rubber (CR) (0.5 mm), polyvinylchloride (PVC) (0.7 mm). Manufacturer's directions for use should be observed.

Eyes

Safety glasses with side-shields (frame goggles) (e.g. EN 166) and face shield.

Respiratory

Wear respiratory protection if ventilation is inadequate. Gas filter for gases/vapours of organic compounds (boiling point >65 ℃, e.g. EN 14387 Type A).

Skin/Body

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
liquid
Appearance
colourless to yellowish
Colour
colourless to yellowish
Colour Intensity
---
Form
liquid
Odor
perceptible, of methanol
Odor Threshold
Not determined since harmful by inhalation.
Ph
approx. 11
Melting Point
---
Boiling Point
92 ℃
Flash Point
33 ℃
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
6,8 ℃
Relative Evaporation Rate
---
Evaporation Rate
No applicable information available.
Vapor Pressure
approx. 34 hPa
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
0,969 g/cm3
Flammability
Flammable liquid and vapour.
Upper Explosive Limit
36,5 %(V)
Lower Explosive Limit
5,5 %(V)
Explosive Limits
---
Auto Ignition Temperature
455 ℃
Decomposition Temperature
---
Solubility
hydrolyzes
Partition Coefficient
n-octanol/water (log Kow): - 0,77 (20 ℃)
Solubility In Water
hydrolyzes
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
42 mm/a
Dynamic Viscosity
64 mPa.s
Kinematic Viscosity
66 mm2/s (20 ℃)
Properties Status
---
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1289
Shipping Name
SODIUM METHYLATE SOLUTION
Transport Class
3,8
Packing Group
III
ADR

Tunnel code: D/E

IMDG

EmS: F-E; S-C

IATA

None known

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Na-Methylate sol. 30 % ZeroPCF?

The signal word is danger.

What is the physical form of Na-Methylate sol. 30 % ZeroPCF?

Na-Methylate sol. 30 % ZeroPCF is a liquid appearing as colourless to yellowish with colourless to yellowish color. It has perceptible, of methanol odor.

What is the solubility of Na-Methylate sol. 30 % ZeroPCF?

hydrolyzes

What is Na-Methylate sol. 30 % ZeroPCF used for?

industrial chemicals

What are the hazard statements for Na-Methylate sol. 30 % ZeroPCF?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapour.
  • H290: May be corrosive to metals.
  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
  • H314: Causes severe skin burns and eye damage.
  • H370: Causes damage to organs.

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