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Na - Methylate sol. 30 % ZeroPCF

DANGER liquid SDS/MSDS

Chemical Product Identification & Regulatory Data

Official chemical identifiers, CAS numbers, and regulatory compliance information

Basic Product Information

Product Name
Na - Methylate sol. 30 % ZeroPCF

Regulatory Identifiers

CAS Number
N/A

Chemical Abstracts Service registry number - unique identifier for chemical substances

UFI Code
3D4V-EF2J-800Q-8QDC

Unique Formula Identifier - for poison centres and emergency response

Uses Information

Identified Uses
industrial chemicals

Overview

Na - Methylate sol. 30 % ZeroPCF is a colourless to yellowish substance commonly used industrial chemicals.

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GHS Hazard Classification & Safety Warnings

Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications

Classification Status

Classified

Signal Word

danger (Danger)

Hazard Classifications

Flam. Liq. Category 3 H226
Met. Corr. Category 1 H290
Acute Tox. Category 3 H331
Acute Tox. Category 3 H301
Acute Tox. Category 3 H311
Skin Corr. Category 1A H314
Eye Dam. Category 1 H318
STOT SE Category 1 H370

GHS Hazard Pictograms & Safety Symbols

GHS02 GHS Hazard Pictogram: Flammable hazard - Fire risk materials including gases, liquids, and solids

GHS02

GHS05 GHS Hazard Pictogram: Corrosive hazard - Materials that can cause severe skin burns and eye damage

GHS05

GHS06 GHS Hazard Pictogram: Acute toxicity hazard - Poisonous materials that can cause death or serious harm

GHS06

GHS08 GHS Hazard Pictogram: Serious health hazard - Carcinogenic, mutagenic, or toxic to organs

GHS08

GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions

Hazard Statements

  • H226: Flammable liquid and vapour.
  • H290: May be corrosive to metals.
  • H370: Causes damage to organs.
  • H314: Causes severe skin burns and eye damage.
  • H301: Toxic if swallowed, in contact with skin or if inhaled.

Precautionary Statements

  • P280: Wear protective gloves, protective clothing and eye protection or face protection.
  • P271: Use only outdoors or in a well-ventilated area.
  • P310: Immediately call a POISON CENTER or physician.
  • P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P403+P235: Store in a well-ventilated place. Keep cool.
  • P501: Dispose of contents and container to hazardous or special waste collection point.

Chemical Manufacturers & Supply Chain

Authorized suppliers, manufacturers, and distribution network information

BASF SE

manufacturer

๐Ÿ“

67056 Ludwigshafen, GERMANY

๐ŸŒ

DE

๐Ÿ“ž

+49 621 60 42737

24/7 Emergency Response & Poison Control

Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies

Emergency Contact

๐Ÿ“ž

+49 180 2273-112

Chemical Composition & Hazardous Ingredients

Detailed component analysis, concentration ranges, and hazardous substance identification

Product Type

mixture

General Composition

Preparation based on: sodium methanolate, methanol

Chemical Components & Hazardous Substances

Chemical Name CAS Number Concentration Hazardous
methanol
EC: 200-659-6
67-56-1 50-75% โš ๏ธ Hazardous
sodium methanolate
EC: 204-699-5
124-41-4 25-50% โš ๏ธ Hazardous
sodium hydroxide
EC: 215-185-5
1310-73-2 1% โš ๏ธ Hazardous

Emergency First Aid Measures

Critical first aid procedures for chemical exposure incidents and medical emergencies

๐Ÿซ Inhalation Exposure

Keep patient calm, remove to fresh air, seek medical attention.

Symptoms:

Irritates the respiratory tract.

๐Ÿ–๏ธ Skin Contact

Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

Symptoms:

Skin corrosion.

๐Ÿ‘๏ธ Eye Contact

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

Symptoms:

Irritates the eyes, potential for blindness.

๐Ÿฝ๏ธ Ingestion/Swallowing

Immediately rinse mouth and then drink 200 - 300 ml water, do not induce vomiting, seek medical attention. Administer 50 ml of pure ethanol in a drinkable concentration. Seek medical attention.

Symptoms:

Information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11.

๐Ÿšจ Immediate Medical Attention Required

Symptomatic treatment (decontamination, vital functions).

Fire Fighting Measures & Emergency Response

Fire suppression methods, extinguishing media, and firefighting safety procedures

โœ… Suitable Extinguishing Media

dry powder, Dry sand, alcohol-resistant foam

โŒ Unsuitable Extinguishing Media

water, carbon dioxide

โš ๏ธ Specific Fire Hazards

Risk of exothermic reaction.

๐Ÿ”ฅ Fire Fighting Instructions

Vapours are heavier than air and may accumulate in low areas and travel a considerable distance up to the source of ignition. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Sealed containers should be protected against heat as this results in pressure build-up.

๐Ÿ›ก๏ธ Firefighter Protection Equipment

Wear self-contained breathing apparatus and chemical-protective clothing.

Accidental Release Measures & Spill Response

Emergency spill cleanup procedures, containment methods, and environmental protection

๐Ÿšจ Emergency Procedures

For emergency responders: Take appropriate protective measures.

๐Ÿ’ง Small Spill Procedures

Pick up with suitable absorbent material.

๐ŸŒŠ Large Spill Procedures

Pump off product.

๐ŸŒ Environmental Precautions

Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water.

๐Ÿงน Cleanup Methods

Dispose of absorbed material in accordance with regulations.

Cleanup Materials:

suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr)

Related Chemical Substances & Alternative Products

Similar chemicals with comparable safety profiles and industrial applications

Technical Specifications & Material Properties

Physical state, chemical properties, melting point, boiling point, and material characteristics

๐Ÿงช Physical State
liquid
Critical Property
๐Ÿ“Š Physical State Data
liquid
๐Ÿ“Š State Under Standard Conditions
liquid
๐Ÿ‘๏ธ Appearance
colourless to yellowish
๐ŸŽจ Colour
colourless to yellowish
๐Ÿ“Š Colour Intensity
Not available
๐Ÿ“Š Form
liquid
๐Ÿ‘ƒ Odor
perceptible, of methanol
๐Ÿ“Š Odor Threshold
Not determined since harmful by inhalation.
๐Ÿงช Ph
approx. 11
๐ŸงŠ Melting Point
Not available
๐Ÿ’จ Boiling Point
92 โ„ƒ
Critical Property
๐Ÿ”ฅ Flash Point
33 โ„ƒ
Critical Property
๐Ÿ“Š Freezing Point
Not available
๐Ÿ“Š Softening Point
Not available
๐Ÿ“Š Solidification Point
Not available
๐Ÿ“Š Cloud Point
Not available
๐Ÿ“Š Crystallisation Point
6,8 โ„ƒ
๐Ÿ“Š Relative Evaporation Rate
Not available
๐Ÿ’จ Evaporation Rate
No applicable information available.
๐Ÿ’จ Vapor Pressure
approx. 34 hPa
๐Ÿ“Š Vapor Density
Not available
๐Ÿ“Š Relative Density
Not available
๐Ÿ“Š Bulk Density
Not available
โš–๏ธ Density
0,969 g/cm3
Critical Property
๐Ÿ”ฅ Flammability
Flammable liquid and vapour.
๐Ÿ“Š Upper Explosive Limit
36,5 %(V)
๐Ÿ“Š Lower Explosive Limit
5,5 %(V)
๐Ÿ“Š Explosive Limits
Not available
๐Ÿ“Š Auto Ignition Temperature
455 โ„ƒ
๐Ÿ“Š Decomposition Temperature
Not available
๐Ÿ’ง Solubility
hydrolyzes
๐Ÿ“Š Partition Coefficient
n-octanol/water (log Kow): - 0,77 (20 โ„ƒ)
๐Ÿ“Š Solubility In Water
hydrolyzes
๐Ÿ“Š Solubility In Fat
Not available
๐Ÿ“Š Molecular Weight
Not available
๐Ÿ“Š Voc Content
Not available
๐Ÿ“Š Metal Corrosion
42 mm/a
๐Ÿ“Š Dynamic Viscosity
64 mPa.s
๐Ÿ“Š Kinematic Viscosity
66 mm2/s (20 โ„ƒ)
๐Ÿ“Š Properties Status
Not available

Safe Handling & Storage Procedures

Industrial handling precautions, storage conditions, and workplace safety requirements

โš ๏ธ Handling Precautions

โ€ข Ensure thorough ventilation of stores and work areas.

โ€ข Protect against moisture.

โ€ข Protect against heat.

โ€ข When using do not eat, drink or smoke.

โ€ข Hands and/or face should be washed before breaks and at the end of the shift.

โ€ข Change clothes immediately after contamination.

โ€ข Avoid all sources of ignition: heat, sparks, open flame.

โ€ข Take precautionary measures against static discharges.

โ€ข Use antistatic tools.

โ€ข Render equipment and apparatus inert (nitrogen, inert gases) and ground before putting into operation.

โ€ข Fire extinguishers should be kept handy.

๐Ÿช Storage Conditions

โ€ข Keep container tightly closed in a cool, well-ventilated place.

โ€ข Keep under dry nitrogen.

โ€ข Protect against moisture.

โ€ข Protect against heat.

โ€ข Keep away from sources of ignition - No smoking.

๐Ÿงผ General Hygiene Measures

Hands and/or face should be washed before breaks and at the end of the shift. Change clothes immediately after contamination.

๐Ÿ”ฅ Fire Prevention Measures

Avoid all sources of ignition: heat, sparks, open flame. Take precautionary measures against static discharges. Use antistatic tools.

Exposure Controls & Personal Protective Equipment (PPE)

Occupational exposure limits, engineering controls, and required safety equipment

๐Ÿญ Engineering Controls

Ventilation systems and respiratory protection may be necessary if ventilation is inadequate. Suitable methods to assess inhalation exposure include European Standards EN 482, 689 and 14042. TRGS 402 must be observed in Germany.

๐Ÿงค Hand Protection

Chemical resistant protective gloves (EN ISO 374-1). Suitable materials with prolonged, direct contact (Protective index 6, > 480 minutes permeation time according to EN ISO 374-1): butyl rubber (0.7 mm), fluoroelastomer (FKM) (0.7 mm). Suitable materials for short-term contact (Protective index 2, > 30 minutes permeation time according to EN ISO 374-1): nitrile rubber (NBR) (0.4 mm), chloroprene rubber (CR) (0.5 mm), polyvinylchloride (PVC) (0.7 mm). Manufacturer's directions for use should be observed.

๐Ÿ‘๏ธ Eye Protection

Safety glasses with side-shields (frame goggles) (e.g. EN 166) and face shield.

๐Ÿ˜ท Respiratory Protection

Wear respiratory protection if ventilation is inadequate. Gas filter for gases/vapours of organic compounds (boiling point >65 โ„ƒ, e.g. EN 14387 Type A).

๐Ÿฆบ Skin/Body Protection

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

Chemical Stability & Reactivity Data

Chemical stability, hazardous reactions, and incompatible materials information

โœ… Chemical Stability

The product is stable if stored and handled as prescribed/indicated. Peroxides: The product/the substance has not a tendency towards the formation of peroxide.

โš—๏ธ Reactivity

No hazardous reactions if stored and handled as prescribed/indicated., Strong exothermic reaction with acids., Vapours may form explosive mixture with air. Corrosion to metals: Corrosive effect on metals. Aluminium Corrosion rate > 6.25 mm/a using 7075-T6 or AZ5GU-T6

โš ๏ธ Hazardous Reactions

Exothermic reaction. Reacts with water and acids.

๐Ÿšซ Conditions to Avoid

Avoid all sources of ignition: heat, sparks, open flame. Avoid contact with air. Avoid moisture.

๐Ÿงช Incompatible Materials

Substances to avoid: Carbon dioxide, water, acids, substances with an acid reaction, light metals

๐Ÿ’จ Hazardous Decomposition Products

Hazardous decomposition products: sodium hydroxide, methanol

Ecological Information & Environmental Impact

Environmental toxicity, biodegradation, bioaccumulation, and ecological effects data

๐ŸŒฑ Toxicity

Assessment of aquatic toxicity: The product has not been tested. The statement has been derived from the properties of the hydrolysis products. Information on:sodium hydroxide Assessment of aquatic toxicity: Depending on local conditions and existing concentrations, disturbances in the biodegradation process of activated sludge are possible. There is a high probability that the product is not acutely harmful to aquatic organisms. The effect strongly depends on the pH-value. The data refers to the dissociated form of the substance. Information on:methanol Assessment of aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. Information on:sodium hydroxide Toxicity to fish: LC50 (96 h) 125 mg/l, Gambusia affinis (other, static) The product will cause changes in the pH value of the test system. The result refers to an unneutralized sample. Literature data. Information on:methanol Toxicity to fish: LC50 (96 h) 15.400 mg/l, Lepomis macrochirus (other, Flow through.) Information on:sodium hydroxide Aquatic invertebrates: EC50 (48 h) 40,4 mg/l, Ceriodaphnia sp. (other, static) Literature data. Information on:methanol Aquatic invertebrates: EC50 (48 h) 18.260 mg/l, Daphnia magna (OECD Guideline 202, part 1, semistatic) Information on:methanol Aquatic plants: EC50 (96 h) approx. 22.000 mg/l (growth rate), Selenastrum capricornutum (OECD Guideline 201, static) Information on:methanol Microorganisms/Effect on activated sludge: EC50 (3 h) > 1.000 mg/l, (OECD Guideline 209, aquatic) EC50 (24 h) 880 mg/l, Nitrosomonas sp. (Inhibition of nitrification, aquatic)

๐ŸŒฑ Persistence and degradability

Assessment biodegradation and elimination (H2O): The product is unstable in water. The elimination data also refer to products of hydrolysis. Information on:sodium hydroxide Assessment biodegradation and elimination (H2O): Inorganic product which cannot be eliminated from water by biological purification processes. Information on:methanol Assessment biodegradation and elimination (H2O): Readily biodegradable (according to OECD criteria). Information on:methanol Elimination information: 95 % BOD of the ThOD (20 d) (OECD 301D; 92/69/EWG, C.4-E) (aerobic, activated sludge, domestic, non-adapted) Readily biodegradable (according to OECD criteria).

๐ŸŒฑ Bioaccumulative potential

Information on:methanol Assessment bioaccumulation potential: Significant accumulation in organisms is not to be expected. Information on:sodium hydroxide Assessment bioaccumulation potential: Accumulation in organisms is not to be expected.

๐ŸŒฑ Mobility in soil

Assessment transport between environmental compartments: Adsorption in soil: Adsorption to solid soil phase is not expected.

๐ŸŒฑ Results of PBT and vPvB assessment

The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative).

๐ŸŒฑ Endocrine disrupting properties

Product does not contain a substance above legal limits included in the list established in accordance with Article 59(1) of Regulation (EC) No 1907/2006 for having endocrine disrupting properties or is identified to have endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605.

๐ŸŒฑ Other adverse effects

The product does not contain substances that are listed in Regulation (EC) 1005/2009 on substances that deplete the ozone layer.

Waste Disposal & Treatment Methods

Waste disposal procedures, treatment methods, and regulatory compliance requirements

โ™ป๏ธ Waste Treatment Methods

Obtain the consent of pollution control authorities before discharging to wastewater treatment plants.

Transportation & Shipping Information

UN numbers, shipping names, transport classes, and regulatory transport requirements

๐Ÿท๏ธ UN Number

UN1289

๐Ÿ“ฆ Proper Shipping Name

SODIUM METHYLATE SOLUTION

โš ๏ธ Transport Hazard Class

3,8

๐Ÿ“‹ Packing Group

III

๐Ÿš› ADR Transport Precautions

Tunnel code: D/E

๐Ÿšข IMDG Maritime Transport Precautions

EmS: F-E; S-C

โœˆ๏ธ IATA Air Transport Precautions

None known

Chemical Safety FAQ & Common Questions

Most frequently asked questions about safety, handling, storage, and regulatory compliance

What is the hazard signal word for Na - Methylate sol. 30 % ZeroPCF?

The signal word for this substance is "danger".

What is the physical form of Na - Methylate sol. 30 % ZeroPCF?

Na - Methylate sol. 30 % ZeroPCF is a liquid appearing as colourless to yellowish with colourless to yellowish color. It has perceptible, of methanol odor.

What is the solubility of Na - Methylate sol. 30 % ZeroPCF?

hydrolyzes

What is Na - Methylate sol. 30 % ZeroPCF used for?

industrial chemicals

What are the hazard statements for Na - Methylate sol. 30 % ZeroPCF?

This substance has 5 hazard statements: H226: Flammable liquid and vapour. H290: May be corrosive to metals. H370: Causes damage to organs. H314: Causes severe skin burns and eye damage. H301: Toxic if swallowed, in contact with skin or if inhaled.