Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- Sodium methylate solution 28% in methanol (NM-28)
Regulatory Identifiers
- CAS Number
- 124-41-4 Check regulations →
- REACH No.
- if available listed in Chapter. 3
Identified Uses
Preliminary / intermediate product for organic syntheses
Manufacturers & Suppliers
Evonik Industries AG
manufacturer
Advanced Intermediates, Chemicals Management (660-112), Postfach 1345, D-63403 Hanau, Germany
+49 (0)6181 59-3207
Emergency Contacts
international
+49 (0)2365 49-2232
international (fax)
+49 (0)2365 49-4423
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS02
GHS05
GHS06
GHS08
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
Preparation of: Information on ingredients / Hazardous components as per EU-CLP Regulation (EC) No. 1272/2008
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| sodium methoxide EC: 204-699-5 | 124-41-4 | 28% | Yes |
| methanol EC: 200-659-6 | 67-56-1 | 72% | Yes |
Texts of H phrases, see in Chapter 16 See chapter 16 for text of risk phrases
Notes
Classification deviating from Annex VI, Ordinance (EC) No. 1272/2008 with: Skin corrosion/irritation Category 1A H314. From Annex VI, Directive (EC) No. 1272/2008 supplemental classification with: Corrosive to metals Category 1 H290 Flammable solids Category 1 H228 Acute toxicity Category 4 H302 Reacts violently with water. EUH014. Not a PBT, vPvB substance as per the criteria of the REACH Regulation.
First Aid Measures
Emergency procedures for chemical exposure incidents
Move victims into fresh air. Do not leave victims unattended. Monitor breathing, give oxygen if necessary. Consult doctor immediately. Place unconscious persons in stablized lateral position. Perform cardiopulmonary resuscitation on victims who are unconscious, not breathing and with cardiac arrest (no pulse).
Symptoms: Breathing difficulties.
Wash off immediately with plenty of water. Flush affected areas of skin under running water for at least 10 minutes. In case of complaints: Consult doctor immediately.
Keeping eyelid open, immediately rinse thoroughly for at least 20 minutes using plenty of water or, if necessary, eye rinsing solution. Immediate further treatment in eye clinic/by eye doctor. Continue rinsing eye until arrival at ophthalmic hospital.
Seek medical advice immediately. Do not leave victims unattended. Do not induce vomiting. Place person on side in stable position if unconscious until medical assistance arrives or the patient can be transported to a medical facility for treatment and evaluation.
Symptoms: Gastrointestinal discomfort. Dysopia, loss of eyesight (upon increasing intoxication).
Immediate Medical Attention
Consult doctor immediately (for inhalation and skin contact). Immediate further treatment in eye clinic/by eye doctor (for eye contact). Seek medical advice immediately (for ingestion). Early endoscopy in order to assess mucosa lesions in the oesophagus and stomach which may appear. If necessary, aspirate leftover substance.
Medical Treatment
Antidote treatment: ethanol. Early endoscopy in order to assess mucosa lesions in the oesophagus and stomach which may appear. If necessary, aspirate leftover substance.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
high volume water jet
In case of fire cool endangered containers with water.
Firefighter Protection
In case of fire: Have ready/wear respiratory protection equipment. Wear suitable protective clothing.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Wear personal protective equipment; see section 8.
Do not allow substance to enter soil, bodies of water or sewage canals.
Take up mechanically or with an absorbent material.
Materials: absorbent for liquids, universal absorbent
Related Products
Similar products with comparable safety profiles
Sodium Methylate solution 30 %
---
Na-Methylate sol. 30 %
---
Methylamine, 40% w/w aqueous solution
---
Dimethylamine 40% w/v solution in water
UFI: 3JG5-P289-NX0F-K859
Sodium methoxide
CAS: 124-41-4
Na-Methylate sol. 30 % ZeroPCF
UFI: 3D4V-EF2J-800Q-8QDC
Methylglyoxal solution
---
N,N'-Methylenebisacrylamide, 2% solution
---
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Avoid residues of the product on the containers. Handle and open container with care.
Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions.
Take precautionary measures against static discharges. Keep away from sources of ignition - No smoking.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Provide adequate ventilation.
Applies to handling for longer periods or of large amounts: Glove material butyl-rubber, for example, Butoject (898), Kchele-Cama Latex GmbH (KCL), Germany. Material thickness 0.7 mm. Method DIN EN 374. Applies to handling for brief periods or of small amounts: Glove material Nitrile, for example, Camatril 731, Kchele-Cama Latex GmbH (KCL), Germany. Material thickness 0.33 mm. Method DIN EN 374.
safety glasses with side-shields conforming to EN166 and/or goggles
in case vapors or aerosols appear use respiratory equipment with suitable filter or wear a self contained respiratory apparatus. Suitable filter: A, code colour brown. Note time limit for wearing respiratory protective equipment.
Select materials and equipment for physical protection depending on the concentration and volume of hazardous substances and the workplace involved.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
The data for this section has not been processed yet.
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
12.1. Toxicity
12.2. Persistence and degradability
The substance is considered readily biodegradable according to appropriate OECD tests, although it cannot be determined for physico-chemical reasons.
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
A PBT/vPvB evaluation is not available, since a chemical safety evaluation is not required / has not been carried out.
12.6. Other adverse effects
No further information available
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
The data for this section has not been processed yet.
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- UN 1289
- Shipping Name
- SODIUM METHYLATE SOLUTION
- Transport Class
- 3 (8)
- Packing Group
- III
Yes
No
Yes
Regulatory Information
Chemical regulations, safety assessments, and compliance status
The product is subject to the EC directive 2012/18/EC and amendments. Please observe Appendix XVII of the EU Regulation 1907/2006 (Restrictions on the manufacture, placing on the market, and use of certain dangerous substances, preparations and articles) as well as their amendments. Please note Directive 92/85/EEC (Pregnant Workers Directive) and Directive 94/33/EC (Protection of Young Workers at the Workplace Directive).
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for Sodium methylate solution 28% in methanol (NM-28)?
The signal word is danger.
What is the physical form of Sodium methylate solution 28% in methanol (NM-28)?
Sodium methylate solution 28% in methanol (NM-28) is a viscous liquid appearing as viscous liquid colourless with colourless color. It has alcoholic odor.
What is Sodium methylate solution 28% in methanol (NM-28) used for?
Preliminary / intermediate product for organic syntheses
What are the hazard statements for Sodium methylate solution 28% in methanol (NM-28)?
This substance has 7 hazard statements:
- H226: Flammable liquid and vapour.
- H290: May be corrosive to metals.
- H301: Toxic if swallowed.
- H311: Toxic in contact with skin.
- H314: Causes severe skin burns and eye damage.
- H331: Toxic if inhaled.
- H370: Causes damage to organs.