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Safety Data Sheet EN

Phosphoric acid

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Phosphoric acid
Product Form
Pure product in solution
Chemical Name
Phosphoric acid, Orthophosphoric acid

Regulatory Identifiers

CAS Number
N/A
REACH No.
01-2119485924-24

Identified Uses

See table on the front page of the annex.

Uses advised against

This product is not recommended for any industrial, professional or consumer use other than identified in table on the front page of the annex.

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1B H314

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.

Precautionary Statements

P234 Keep only in original container.
P260 Do not breathe dust, fume, gas, mist, vapours, spray.
P280 Wear protective gloves, protective clothing, eye protection, face protection.
P301 + P330 + P331 IF SWALLOWED : Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair) : Remove immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Phosphoric acid ...% EC: 231-633-2 7664-38-2 25% Yes

Notes

The full text of the R-phrases and (EU)H-statements is in section 16. Nota B (Regulation (EC) No 1272/2008) applies to the product or one or more of its components. Note: SCL applicable

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim into fresh air. Allow the affected person to rest. If not breathing, give artificial respiration. Get immediate medical advice/attention.

Skin contact

Remove contaminated clothing while rinsing. Rinse skin immediately with mild soap and plenty of water. (at least 20') (shower if necessary). Consult doctor if irritation develops.

Eye contact

Rinse immediately thoroughly and long (at least 15 min.) with plenty of water. Remove contact lenses. Consult eye doctor. Keep rinsing or dripping the eye during transport.

Ingestion

DO NOT INDUCE VOMITING. Rinse mouth with water. Give victim plenty of water to drink. Take the patient IMMEDIATELY to the hospital.

Immediate Medical Attention

Get immediate medical advice/attention (inhalation), consult doctor if irritation develops (skin), consult eye doctor (eye), take the patient IMMEDIATELY to the hospital (ingestion).

Medical Treatment

For specialist advice doctors should contact the NVCI or the Belgian Poison center.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Extinguishing powder, Alcohol resistant foam, Water spray.

Unsuitable media

Heavy water stream.

Specific hazards

Fire may liberate toxic and biting vapours of phosphoric oxides.

Instructions

Apply water spray or fog to cool nearby equipment.

Firefighter Protection

Use self-contained breathing apparatus and wear protective clothes when in close proximity to fire.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate all personnel immediately and ventilate area. Avoid breathing vapour and contact with skin, eyes and clothing.

Environmental

Shut off leaks if without risks. Dike in the spilled product as much as possible with inert material. Prevent entry of product in public water, sewers or soil.

Cleanup methods

Collect the spillage in closable, corrosion resistant, suitable disposal containers.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

STRONG HYGIENE! Avoid breathing vapour and contact with skin, eyes and clothing. Wear recommended personal protective equipment. (See section 8) Avoid heating, splashing and formation of vapour when emptying, pouring, diluting or dissolving the product. When diluting, always pour the acid solution upon the water, never the other way round.

Storage

Keep only in the original, safely locked container in a well ventilated and dark place. All dangerous products should be placed on a drip tray or should be barreled.

Hygiene

When using, do not eat, drink or smoke.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ventilation ( If possible through the floor ), Local exhaust .

Hands

Suitable material for safety gloves (EN 374): The suitability (break trough time, material thickness, ...) for a specific workplace should be discussed with the producers of the protective gloves. Butyl rubber , PVC .

Eyes

Closed safety glasses or face shield.

Respiratory

CE-approved gas respirator ( Filter type BE/P2).

Skin/Body

Suitable protective clothing ( Acid proof ).

Environmental

See sections 6, 7, 12 en 13.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid (>75%: Viscous liquid )
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear , Colourless .
Colour
Colourless
Colour Intensity
---
Form
Clear
Odor
Almost odourless
Odor Threshold
No data available.
Ph
1,2 (85 g/100ml)
Melting Point
-11,8 to 21,1 °C (30%-85%)
Boiling Point
101,8 - 158 °C (30%-85%)
Flash Point
Not applicable.
Freezing Point
-11,8 to 21,1 °C (30%-85%)
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable.
Vapor Pressure
0,2 - 0,4 kPa
Vapor Density
---
Relative Density
1,0
Bulk Density
---
Density
1,2 - 1,8 kg/l
Flammability
---
Upper Explosive Limit
Not applicable.
Lower Explosive Limit
Not applicable.
Explosive Limits
---
Auto Ignition Temperature
Not applicable.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
Not established.
Solubility In Water
100 g/100ml
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
app. 2,0 - 32 mPa.s (30-85%)
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable at normal circumstances.

Reactivity

Reacts violently with oxidizing agents and lyes.

Hazardous reactions

The substance decomposes on heating to form pyrophosphoric acid, metaphosphoric acid, phosphorous pentoxide. Contact with metallic substances may release inflammable hydrogen gas. Contact with : Acids => Creation of toxic gases. ( Sulfides , Cyanides )

Avoid

High temperatures , Light .

Incompatible

Oxidizing agents , Bases , Several metals , Acids .

Decomposition

Pyrophosphoric acid , Metaphosphoric acid , Phosphorus pentoxide , Sulfides , Cyanides .

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The product has to be destroyed according to national or local legislation, by a company specialised in handling hazardous waste products.

Disposal

The product has to be destroyed according to national or local legislation, by a company specialised in handling hazardous waste products.

Waste Codes

XXXXXX European waste product code EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1805
Shipping Name
Phosphoric acid, solution
Transport Class
8
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Phosphoric acid?

The signal word is danger.

What is the physical form of Phosphoric acid?

Phosphoric acid is a liquid (>75%: viscous liquid ) appearing as clear , colourless . with colourless color. It has almost odourless odor.

What is Phosphoric acid used for?

See table on the front page of the annex.

What are the hazard statements for Phosphoric acid?

This substance has 2 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.

What is the melting point of Phosphoric acid?

The melting point is -11,8 to 21,1 °C (30%-85%) and the boiling point is 101,8 - 158 °C (30%-85%).