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Safety Data Sheet EN

Ammonia solution S.G. 0.91 (25%)

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ammonia solution S.G. 0.91 (25%)
Product Code
A/3360/PB15, A/3360/PB17, A/3360/P27, A/3360/99
Synonyms
Ammonia solution; Ammonia water; Ammonium hydrate

Regulatory Identifiers

CAS Number
N/A
UFI Code
CXH5-QF3D-MS2Y-ES0C

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

F

Fisher Scientific UK

distributor

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

01509 231166

T

Thermo Fisher Scientific

distributor

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

Emergency Contacts

Chemtrec US

(800) 424-9300

Chemtrec EU

001-703-527-3887

National Poisons Information Centre (NPIC)

01 809 2166

8am-10pm, 7 days a week

Poison Centre

+356 2395 2000

Poison Centre

+357 2240 5611

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335
Aquatic Acute Cat. 1 H400

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H314 Causes severe skin burns and eye damage
H335 May cause respiratory irritation
H400 Very toxic to aquatic life

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Ammonia solution S.G. 0.91 (25%)

Chemical Name CAS Number Concentration Hazardous
Ammonium hydroxide EC: 215-647-6 1336-21-6 25 - 30% Yes
Ammonia --- --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Ingestion

Do NOT induce vomiting. Call a physician or Poison Control Centre immediately.

Symptoms: Severe swelling, severe damage to the delicate tissue and danger of perforation.

Immediate Medical Attention

Immediate medical attention is required. Call a physician or Poison Control Centre immediately.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO₂, dry chemical, dry sand, alcohol-resistant foam. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

No information available.

Specific hazards

Keep product and empty container away from heat and sources of ignition. Thermal decomposition can lead to release of irritating gases and vapors.

Instructions

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

Firefighter Protection

Wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas. Avoid contact with skin, eyes and inhalation of vapors.

Environmental

Should not be released into the environment.

Cleanup methods

Collect spillage.

Materials: inert absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only under a chemical fume hood. Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Do not ingest. If swallowed then seek immediate medical assistance. Do not breathe mist/vapors/spray.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place.

Hygiene

Handle in accordance with good industrial hygiene and safety practice.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Butyl rubber (> 480 minutes, 0.5 mm, EN 374); Viton (R) (> 480 minutes, 0.4 mm); Neoprene (> 480 minutes, 0.45 mm). (minimum requirement)

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Inorganic gases and vapours filter Type B Grey or Ammonia and organic ammonia derivatives filter Type K Green conforming to EN14387. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure. Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Environmental

Prevent product from entering drains. Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colorless
Colour
Colorless
Colour Intensity
---
Form
---
Odor
Ammonia-like
Odor Threshold
No data available
Ph
12
Melting Point
-57 °C / -70.6 °F
Boiling Point
38 °C / 100.4 °F
Flash Point
No information available
Freezing Point
---
Softening Point
No data available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
500 hPa @ 20 °C
Vapor Density
0.59
Relative Density
0.88-0.91
Bulk Density
Not applicable
Density
0.88-0.91
Flammability
No data available
Upper Explosive Limit
28 Vol%
Lower Explosive Limit
15 Vol%
Explosive Limits
---
Auto Ignition Temperature
651 °C / 1203.8 °F
Decomposition Temperature
No data available
Solubility
No information available
Partition Coefficient
---
Solubility In Water
Soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. None under normal processing.

Avoid

Incompatible products. Excess heat.

Incompatible

Strong oxidizing agents. Metals. Acids. Fluorine. Halogens.

Decomposition

Nitrogen oxides (NOx).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity Ecotoxicity effects

Very toxic to aquatic organisms. The product contains following substances which are hazardous for the environment. | Component | Freshwater Fish | Water Flea | Freshwater Algae | | --- | --- | --- | --- |

Very toxic to aquatic organisms. The product contains following substances which are hazardous for the environment.

12.1. Toxicity Ecotoxicity effects

Freshwater Fish: 0.53 mg/l LC50 96h, 0.75 - 3.4 mg/l LC50 96h, 8.2 mg/L LC50 96h; Water Flea: EC50: 0.66 mg/L/48h; Freshwater Algae: -

12.1. Toxicity Ecotoxicity effects

Ecotoxicity effects | Component | Freshwater Fish | Water Flea | Freshwater Algae | | Ammonia | LC50: 0.26 - 4.6 mg/L, 96h (Lepomis macrochirus) LC50: = 1.17 mg/L, 96h flow-through (Lepomis macrochirus) LC50: 0.73 - 2.35 mg/L, 96h (Pimephales promelas) LC50: = 5.9 mg/L, 96h static (Pimephales promelas) LC50: > 1.5 mg/L, 96h (Poecilia reticulata) LC50: = 1.19 mg/L, 96h static (Poecilia reticulata) LC50: = 0.44 mg/L, 96h (Cyprinus carpio) | EC50 = 25.4 mg/L, 48h (Daphnia magna) NOEC = 0.79 mg/L (Daphnia magna) | |

12.1. Toxicity Ecotoxicity effects

Ecotoxicity effects | Component | Microtox | M-Factor | | Ammonium hydroxide | | 1 |

12.1. Toxicity Ecotoxicity effects

| Component | Microtox | M-Factor | | Ammonia | EC50 = 2.0 mg/L 5 min | 1 |

12.2. Persistence and degradability

Persistence Degradation in sewage treatment plant Persistence is unlikely, based on information available. Contains substances known to be hazardous to the environment or not degradable in waste water treatment plants.

Persistence is unlikely. Contains substances known to be hazardous to the environment or not degradable in waste water treatment plants.

12.3. Bioaccumulative potential

Bioaccumulation is unlikely

Bioaccumulation is unlikely.

12.4. Mobility in soil

The product is water soluble, and may spread in water systems. Disperses rapidly in air

12.5. Results of PBT and vPvB assessment

No data available for assessment.

No data available for assessment.

12.6. Endocrine disrupting properties

**Endocrine Disruptor Information** This product does not contain any known or suspected endocrine disruptors

This product does not contain any known or suspected endocrine disruptors

12.7. Other adverse effects

**Persistent Organic Pollutant** **Ozone Depletion Potential** This product does not contain any known or suspected substance This product does not contain any known or suspected substance

This product does not contain any known or suspected substance for Persistent Organic Pollutant or Ozone Depletion Potential.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

Disposal

Should not be released into the environment.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2672
Shipping Name
AMMONIA SOLUTION
Transport Class
8
Packing Group
III
ADR

No special precautions required.

IMDG

No special precautions required.

IATA

No special precautions required.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Ammonia solution S.G. 0.91 (25%) known by?

Ammonia solution S.G. 0.91 (25%) is also known as: Ammonia solution; Ammonia water; Ammonium hydrate

What is the hazard signal word for Ammonia solution S.G. 0.91 (25%)?

The signal word is danger.

What is the physical form of Ammonia solution S.G. 0.91 (25%)?

Ammonia solution S.G. 0.91 (25%) is a liquid appearing as colorless with colorless color. It has ammonia-like odor.

What is the solubility of Ammonia solution S.G. 0.91 (25%)?

No information available

What is Ammonia solution S.G. 0.91 (25%) used for?

Laboratory chemicals.

What are the hazard statements for Ammonia solution S.G. 0.91 (25%)?

This substance has 3 hazard statements:

  • H314: Causes severe skin burns and eye damage
  • H335: May cause respiratory irritation
  • H400: Very toxic to aquatic life

What is the melting point of Ammonia solution S.G. 0.91 (25%)?

The melting point is -57 °C / -70.6 °F and the boiling point is 38 °C / 100.4 °F.