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Safety Data Sheet EN

Propionaldehyde

CAS 123-38-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Propionaldehyde
Product Code
AC131510000; AC131510010; AC131510025;AC131510100;AC131510250
Synonyms
Propanal

Regulatory Identifiers

CAS Number
123-38-6 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use.

Manufacturers & Suppliers

F

Fisher Scientific Company

One Reagent Lane Fair Lawn, NJ 07410

(201) 796-7100

A

Acros Organics

One Reagent Lane Fair Lawn, NJ 07410

Emergency Contacts

ACROS

001-800-ACROS-01

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2
Acute Tox. Cat. 4
Acute Tox. Cat. 4
Skin Irrit. Cat. 2
Eye Dam. Cat. 1
STOT SE Cat. 3

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapor
H302 + H332 Harmful if swallowed or if inhaled
H315 Causes skin irritation
H318 Causes serious eye damage
H335 May cause respiratory irritation

Precautionary Statements

Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Wear protective gloves/protective clothing/eye protection/face protection
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Keep cool
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
If skin irritation occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor/physician
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
In case of fire: Use CO2, dry chemical, or foam for extinction
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Propionaldehyde 123-38-6 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Symptoms: headache, dizziness, tiredness, nausea and vomiting

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Symptoms: Skin irritation

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Symptoms: Causes severe eye damage.

Ingestion

Clean mouth with water and drink afterwards plenty of water.

Immediate Medical Attention

Get medical attention; call a physician if symptoms persist or occur.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Specific hazards

Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Ensure adequate ventilation. Use personal protective equipment as required. Remove all sources of ignition. Take precautionary measures against static discharges. Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Use spark-proof tools and explosion-proof equipment.

Environmental

Should not be released into the environment. Do not flush into surface water or sanitary sewer system.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Ensure adequate ventilation.

Storage

Flammables area. Keep away from heat, sparks and flame. Keep refrigerated. Keep container tightly closed in a dry and well-ventilated place. Keep under nitrogen. May form explosive peroxides on prolonged storage.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Keep away from heat, sparks and flame.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting equipment.

Hands

Wear appropriate protective gloves and clothing to prevent skin exposure.

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

No protective equipment is needed under normal use conditions.

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colorless
Colour
Colorless
Colour Intensity
---
Form
---
Odor
Stench
Odor Threshold
No information available
Ph
Not applicable
Melting Point
-81 °C / -113.8 °F
Boiling Point
48 °C / 118.4 °F @ 760 mmHg
Flash Point
-40 °C / -40 °F
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No information available
Vapor Pressure
330 hPa @ 20 °C
Vapor Density
No information available
Relative Density
0.798
Bulk Density
---
Density
---
Flammability
Not applicable
Upper Explosive Limit
17 vol %
Lower Explosive Limit
2.9 vol %
Explosive Limits
---
Auto Ignition Temperature
190 °C / 374 °F
Decomposition Temperature
No information available
Solubility
Soluble in water
Partition Coefficient
No data available
Solubility In Water
Soluble in water
Solubility In Fat
---
Molecular Weight
58.08
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.6 mPa s at 20 °C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Air sensitive. May form explosive peroxides on prolonged storage.

Reactivity

None known, based on information available

Hazardous reactions

Polymerization can occur. None under normal processing.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition. Exposure to air.

Incompatible

Strong oxidizing agents, Strong bases, Reducing Agent, Strong acids, Amines

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO₂)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1275
Shipping Name
PROPIONALDEHYDE
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Propionaldehyde known by?

Propionaldehyde is also known as: Propanal

What is the hazard signal word for Propionaldehyde?

The signal word is danger.

What is the physical form of Propionaldehyde?

Propionaldehyde is a liquid appearing as colorless with colorless color. It has stench odor.

What is the solubility of Propionaldehyde?

Soluble in water

What is Propionaldehyde used for?

Laboratory chemicals.

What are the hazard statements for Propionaldehyde?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H302 + H332: Harmful if swallowed or if inhaled
  • H315: Causes skin irritation
  • H318: Causes serious eye damage
  • H335: May cause respiratory irritation

What is the melting point of Propionaldehyde?

The melting point is -81 °C / -113.8 °F and the boiling point is 48 °C / 118.4 °F @ 760 mmHg.

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