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Safety Data Sheet EN

Propionaldehyde

CAS 123-38-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Propionaldehyde
Product Code
AC131510000; AC131510010; AC131510025;AC131510100;AC131510250
Synonyms
Propanal

Regulatory Identifiers

CAS Number
123-38-6 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use.

Manufacturers & Suppliers

F

Fisher Scientific Company

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

A

Acros Organics

One Reagent Lane, Fair Lawn, NJ 07410

Emergency Contacts

Emergency Contact

001-800-ACROS-01

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2
Acute Tox. Cat. 4
Acute Tox. Cat. 4
Skin Irrit. Cat. 2
Eye Dam. Cat. 1
STOT SE Cat. 3

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapor
H302 + H332 Harmful if swallowed or if inhaled
H315 Causes skin irritation
H318 Causes serious eye damage
H335 May cause respiratory irritation

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P233 Keep container tightly closed
P235 Keep cool
P240 Ground/bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash face, hands and any exposed skin thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
P304 + P341 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P330 Rinse mouth
P332 + P313 If skin irritation occurs: Get medical advice/attention
P363 Wash contaminated clothing before reuse
P370 + P378 In case of fire: Use CO2, dry chemical, or foam for extinction
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Propionaldehyde 123-38-6 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Symptoms: headache, dizziness, tiredness, nausea and vomiting

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Symptoms: Causes severe eye damage.

Ingestion

Clean mouth with water and drink afterwards plenty of water.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

No information available

Specific hazards

Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Should not be released into the environment.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

Storage

Flammables area. Keep away from heat, sparks and flame. Keep refrigerated. Keep container tightly closed in a dry and well-ventilated place. Keep under nitrogen.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting equipment.

Hands

Wear appropriate protective gloves

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

No protective equipment is needed under normal use conditions.

Skin/Body

Wear appropriate protective clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colorless
Colour
Colorless
Colour Intensity
---
Form
---
Odor
Stench
Odor Threshold
No information available
Ph
Not applicable
Melting Point
-81 °C / -113.8 °F
Boiling Point
48 °C / 118.4 °F @ 760 mmHg
Flash Point
-40 °C / -40 °F
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No information available
Vapor Pressure
330 hPa @ 20 °C
Vapor Density
No information available
Relative Density
0.798
Bulk Density
---
Density
---
Flammability
Not applicable
Upper Explosive Limit
17 vol %
Lower Explosive Limit
2.9 vol %
Explosive Limits
---
Auto Ignition Temperature
190 °C / 374 °F
Decomposition Temperature
No information available
Solubility
Soluble in water
Partition Coefficient
No data available
Solubility In Water
Soluble in water
Solubility In Fat
---
Molecular Weight
58.08
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.6 mPa s at 20 °C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Air sensitive. May form explosive peroxides on prolonged storage.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Polymerization can occur.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition. Exposure to air.

Incompatible

Strong oxidizing agents, Strong bases, Reducing Agent, Strong acids, Amines

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO₂)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1275
Shipping Name
PROPIONALDEHYDE
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Propionaldehyde known by?

Propionaldehyde is also known as: Propanal

What is the hazard signal word for Propionaldehyde?

The signal word is danger.

What is the physical form of Propionaldehyde?

Propionaldehyde is a liquid appearing as colorless with colorless color. It has stench odor.

What is the solubility of Propionaldehyde?

Soluble in water

What is Propionaldehyde used for?

Laboratory chemicals.

What are the hazard statements for Propionaldehyde?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H302 + H332: Harmful if swallowed or if inhaled
  • H315: Causes skin irritation
  • H318: Causes serious eye damage
  • H335: May cause respiratory irritation

What is the melting point of Propionaldehyde?

The melting point is -81 °C / -113.8 °F and the boiling point is 48 °C / 118.4 °F @ 760 mmHg.