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Safety Data Sheet EN

Continuous filaments glass fibres for plastic reinforcement

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Continuous filaments glass fibres for plastic reinforcement

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

S

Saint-Gobain Vetrotex International

manufacturer

767, quai des Allobroges, BP 929, 73009 Chambéry Cedex

S

Saint-Gobain Vertex A.S.

manufacturer

Sokolovska 106, CZ-57021 Litomysl

+ (420) 464 651 140

S

Saint-Gobain Vertex A.S.

manufacturer

Zahradni 256, ICZ-67125 Hodonice

+ (420) 624 207 111

S

Saint-Gobain Vetrotex Italia SpA

manufacturer

Via Parini 10, I-20045 Besana Brianza

+ (39) 0 362 98 5208

S

Saint-Gobain Loreet S.A.

manufacturer

57, rue du M° de Rochambeau, BP 74, F-41100 Vendôme Cedex

+33 (0)2 54 73 40 00

S

Saint-Gobain Vetrotex Italia SpA

manufacturer

Via Piave 29, I-17047 Vado Ligure

+ (39) 0 19 28 921

S

Saint-Gobain Revetex S.r.l.

manufacturer

Corso Rigola 89, I-13100 Vercelli (Italie)

+ (39) 0161 215810

S

Saint-Gobain Vetrotex France S.A.

manufacturer

130, avenue des Follaz, BP 928, F-73009 Chambéry Cedex

+ 33 (0) 4 79 96 82 00

S

Saint-Gobain Syneroglus

manufacturer

Industriepark, Drukkerijstraat 9, B-9240 Zele (Belgique)

+32 52 45 76 11

S

Saint-Gobain Vetrotex Canada Inc.

manufacturer

201 Hugel Avenue, Midland, Ontario L4R 4G1

+1 705 526 7867

B

Beijing Saint-Gobain Vetrotex Glassfiber Co Ltd

manufacturer

Mailbox 293, Fangshan District, Beijing 102402 China

+86 10 8033 2785

S

Saint-Gobain Vidros S.A.

manufacturer

Rodovia Campinas-Tietê km 40.5, Bairro Corte Preto, Capivari, SP-CEP 13360-000 (Brésil)

+55 19 3492 9000

S

Saint-Gobain Vetrotex Korea Ltd

manufacturer

40 Soryong Dong, Gumun, Jeonbuk 573-400

+82 63 469 1201

S

Saint-Gobain Vetrotex America Inc

manufacturer

4515 Allendale Road P.O. Box CT, Wichita Falls, TX 76310

+1 940 691 0020

S

Saint-Gobain Vetrotex Thailand Co Ltd

manufacturer

79-24 Moo 2 Srinakarin Road, Nongbon, Praves Bangkok 10260

+66 2 366 0240

S

Saint-Gobain Technical Fabrics Cerbay

manufacturer

211 Randy Drive PO Box 937, Wichita Falls, TX 76307

+1 940 723 5998

Emergency Contacts

Environment, Industrial Hygiene and Safety Director of the Reinforcement Branch of Saint-Gobain / Saint-Gobain Vetrotex International

+33 4 79 75 53 00

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Glass fibres are a mixture of E GLASS in the form of continuous strands and a SIZE with, in addition, a BINDER in the case of mats.

Chemical Name CAS Number Concentration Hazardous
E GLASS 65997-17-3 --- No
SIZE --- 2.5% No
BINDER --- 10% No
organo-silane --- 0.05% Yes

Most of the mixture is made up of basically non-reactive high molecular weight polymers not listed as substances in the 1981 European Inventory of Existing Commercial Substances (EINECS) nor in the ELINCS appendices and are generally exempt from registration on the American TSCA lists. In some cases, sizes are prepared from polymers with reactive sites or containing reactive monomers included in these lists. Most of the reactive sites are polymerised during the manufacturing process. A second type of ingredient present in almost all sizes is a member of the organo-silane family (less than 0.05% of the final weight). Other products can be used in sizes (usually under 0.1% of total weight). Binders for mats are high molecular weight polymers deposited in quantities under 10% and polymerised on chopped or continuous glass strand mats.

Notes

This Material Safety Data Sheet is valid for all Saint-Gobain Vetrotex glass fibre products listed. Glass fibres are not substances but preparations within the meaning of EEC Directive 67/548. The CAS number of glass fibre is 65997-17-3 (corresponding to the oxides used for production).

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

remove from the scene of exposure to fresh air

Skin contact

wash copiously with lukewarm soapy water without rubbing excessively

Eye contact

flush in running water (for at least 10 minutes) and consult if necessary a doctor

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

water or chemical powder

Specific hazards

Only the packaging (plastic film, paper, cardboard, wood) and the small amounts of size or binder are likely to burn. Combustion gases are basically carbon dioxide and water vapour. There may be small quantities of carbon monoxide and other unidentified substances.

Firefighter Protection

make it necessary to use protective devices in the event of a major fire.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

In leaching tests glass fibre wastes did not emit any significant quantities of dangerous products and they can therefore be considered as Inert Industrial Wastes, or even Common Industrial Wastes, as defined by national and local regulations. All waste and scrap material should be disposed of in accordance with applicable national, federal, state and local regulations (see paragraph 13).

Cleanup methods

Vacuum clean, sweep or shovel into containers normally used for glass fibre waste (selective collection).

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

It is preferable to avoid prolonged contact with the skin: wear gloves, garments with sleeves and long leggings or protective overalls, goggles, and dust masks.

Storage

store away from excessive humidity to prevent damage to the product and to the packing materials which could lead to storage safety problems.

Hygiene

Wash work garments separately from other clothes.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use every appropriate means (suction, modification of manufacturing methods to reduce fibre dust...) to try to reduce the concentration of fibres likely to cause irritation.

Hands

gloves for the hands

Eyes

safety goggles (or masks) or safety glasses

Respiratory

during occasional operations releasing high quantities of dust, wear minimum FP1 or preferably FP2 EEC approved dust masks. Type 3M 8710 or 3M 9900 respirators approved according to American National Institute For Occupational Safety And Health (NIOSH) directives, can be used, for example.

Skin/Body

long-sleeved garments and long leggings to prevent irritation. People with delicate skin should apply barrier cream to exposed skin areas.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Auto Ignition Temperature
---
Form
continuous or chopped or mats of fibre made up of continuous, parallel filaments glued together.
Kinematic Viscosity
---
Flash Point
---
Cloud Point
---
Vapor Pressure
---
Appearance
---
Softening Point
approximately 850°C
Physical State
solid
Partition Coefficient
---
Decomposition Temperature
200°C
Ph
not applicable
Relative Evaporation Rate
---
Physical State Data
solid
Solubility
very low solubility in water. Sizes and binders can be partially (and even totally) dissolved in most organic solvents.
Dynamic Viscosity
---
Flammability
---
Solubility In Water
very low solubility in water.
Colour Intensity
---
Solidification Point
---
Vapor Density
---
Odor Threshold
---
Metal Corrosion
---
Density
2.6 g / cu. cm.
Upper Explosive Limit
---
Crystallisation Point
---
State Under Standard Conditions
---
Solubility In Fat
---
Explosive Limits
---
Relative Density
---
Molecular Weight
---
Voc Content
---
Bulk Density
---
Lower Explosive Limit
---
Melting Point
1200°C to 1250°C
Odor
none, except for some products from which a slightly basic or acid odour is sometimes released when a pallet or carton is opened. This odour never indicates that an eventual toxic product has been released in a dangerous amount.
Evaporation Rate
---
Freezing Point
---
Boiling Point
---
Properties Status
---
Colour
white or yellowish white
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable in normal use and storage conditions, and in normally foreseeable usage conditions.

Reactivity

Glass reinforcement strands are stable and never generate hazardous chemical reactions.

Hazardous reactions

Glass reinforcement strands are stable and never generate hazardous chemical reactions.

Decomposition

In continuous combustion conditions, in addition to water vapour and CO₂, small quantities of CO and NOx may be released from the combustion of the size and/or the binder. Other products may be released in limited quantities, depending on combustion conditions.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Glass fibres waste cannot be destroyed by incineration – and can damage incinerators by the formation of a vitrified mass.

Disposal

Glass fibre wastes can be buried in landfills approved for inert waste or common industrial waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Continuous filaments glass reinforcements do not require hazardous product labelling. General hygiene and work safety regulations apply. Continuous filament glass reinforcement for plastics are preparations and for this reason are not listed as such in substance lists in several countries. When importing to these countries, it may be necessary to list the ingredients of the preparation.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Continuous filaments glass fibres for plastic reinforcement?

The signal word is no signal word.

What is the physical form of Continuous filaments glass fibres for plastic reinforcement?

Continuous filaments glass fibres for plastic reinforcement is a solid with white or yellowish white color. It has none, except for some products from which a slightly basic or acid odour is sometimes released when a pallet or carton is opened. this odour never indicates that an eventual toxic product has been released in a dangerous amount. odor.

What is the solubility of Continuous filaments glass fibres for plastic reinforcement?

very low solubility in water. Sizes and binders can be partially (and even totally) dissolved in most organic solvents.

What is the melting point of Continuous filaments glass fibres for plastic reinforcement?

The melting point is 1200°C to 1250°C .