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Safety Data Sheet EN

Nickel standard 1000 mg Ni, (NiCl₂ in H₂O) Titrisol®

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Nickel standard 1000 mg Ni, (NiCl₂ in H₂O) Titrisol®
Product Code
109989

Regulatory Identifiers

CAS Number
N/A
REACH No.
This product is a mixture. REACH Registration Number see section 3.

Identified Uses

Reagent for analysis For additional information on uses please refer to the Merck Chemicals portal (www.merckgroup.com).

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

64271 Darmstadt * Germany

+49 6151 72-0

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Resp. Sens. Cat. 1 H334
Skin Sens. Cat. 1 H317
Muta. Cat. 2 H341
Carc. Cat. 1A H350i
Repr. Cat. 1B H360D
STOT RE Cat. 1 H372
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H341 Suspected of causing genetic defects.
H350i May cause cancer by inhalation.
H360D May damage the unborn child.
H372 Causes damage to organs (Lungs, Skin) through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P273 Avoid release to the environment.
P280 Wear protective gloves.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P314 Get medical advice/ attention if you feel unwell.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/ physician.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Aqueous solution

Chemical Name CAS Number Concentration Hazardous
nickel(II) chloride 7718-54-9 3 - 5% Yes

Notes

A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) No 1907/2006, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air. Call in physician.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Symptoms: nickel dermatitis

Eye contact

rinse out with plenty of water. Call in ophthalmologist.

Ingestion

immediately make victim drink water (two glasses at most). Consult a physician.

Immediate Medical Attention

Call in physician. Call in ophthalmologist.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Not combustible. Ambient fire may liberate hazardous vapours.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. Observe label precautions.

Storage

Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: - Glove material: Nitrile rubber - Glove thickness: 0,11 mm - Break through time: > 480 min splash contact: - Glove material: Nitrile rubber - Glove thickness: 0,11 mm - Break through time: > 480 min The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 741 Dermatril® L (full contact), KCL 741 Dermatril® L (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet <(>, <) > supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Safety glasses

Respiratory

required when vapours/aerosols are generated. Recommended Filter type: filter ABEK The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the respective supplier. protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
light green
Colour Intensity
---
Form
liquid
Odor
odourless
Odor Threshold
No information available.
Ph
ca. 4,4 at 20 °C
Melting Point
---
Boiling Point
---
Flash Point
---
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
---
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
ca. 1,04 g/cm³ at 20 °C
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
at 20 °C soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

See section 10.3

Hazardous reactions

Violent reactions possible with: The generally known reaction partners of water.

Avoid

no information available

Incompatible

no information available

Decomposition

no information available

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (NICKEL(II)-CHLORIDE SOLUTION)
Transport Class
9
Packing Group
III
ADR

yes

IMDG

yes

IATA

no

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Nickel standard 1000 mg Ni, (NiCl₂ in H₂O) Titrisol®?

The signal word is danger.

What is the physical form of Nickel standard 1000 mg Ni, (NiCl₂ in H₂O) Titrisol®?

Nickel standard 1000 mg Ni, (NiCl₂ in H₂O) Titrisol® is a liquid with light green color. It has odourless odor.

What is Nickel standard 1000 mg Ni, (NiCl₂ in H₂O) Titrisol® used for?

Reagent for analysis For additional information on uses please refer to the Merck Chemicals portal (www.merckgroup.com).

What are the hazard statements for Nickel standard 1000 mg Ni, (NiCl₂ in H₂O) Titrisol®?

This substance has 7 hazard statements:

  • H317: May cause an allergic skin reaction.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H341: Suspected of causing genetic defects.
  • H350i: May cause cancer by inhalation.
  • H360D: May damage the unborn child.
  • H372: Causes damage to organs (Lungs, Skin) through prolonged or repeated exposure.
  • H411: Toxic to aquatic life with long lasting effects.