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Safety Data Sheet EN

Methyl PROXITOL Acetate

CAS 108-65-6
EC 203-603-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Methyl PROXITOL Acetate
Product Code
U5126
Chemical Name
1-methoxy-2-propanol acetate
Synonyms
PMA

Regulatory Identifiers

CAS Number
108-65-6 Check regulations →
EC Number
203-603-9 Check regulations →

Identified Uses

Solvent. Substance/Mixture Please refer to Ch16 and/or the annexes for the registered uses under REACH.

Uses advised against

This product must not be used in applications other than the above without first seeking the advice of the supplier.

Manufacturers & Suppliers

S

Shell Chemicals Europe B.V.

manufacturer

PO Box 2334 3000 CH Rotterdam Netherlands

+31 (0)10 441 5137 / +31 (0)10 441 5191

Emergency Contacts

Emergency Contact

+44 (0) 1235 239 670

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3 H226

GHS Pictograms

GHS02 - Flammable

GHS02

Hazard Statements

H226 Flammable liquid and vapour.

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P280 Wear protective gloves/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P370 + P378 In case of fire: Use appropriate media to extinguish.
P403 + P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Substances

Hazardous components and further information on contained substances.

Chemical Name CAS Number Concentration Hazardous
1-Methoxy-2acetoxypropane EC: 203-603-9 108-65-6 99.8% Yes
Methoxypropanolacetate EC: 274-724-2 70657-70-4 0.1% No
2-methoxypropanol EC: 216-455-5 1589-47-5 0.01% No
1-Methoxypropane-2-ol EC: 203-539-1 107-98-2 0.01% No
Butylated Hydroxytoluene EC: 204-881-4 128-37-0 0.0025% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

No treatment necessary under normal conditions of use. If symptoms persist, obtain medical advice.

Symptoms: Respiratory irritation signs and symptoms may include a temporary burning sensation of the nose and throat, coughing, and/or difficulty breathing.

Skin contact

Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention.

Symptoms: Skin irritation signs and symptoms may include a burning sensation, redness, or swelling.

Eye contact

Flush eyes with water while holding eyelids open. Rest eyes for 30 minutes. If redness, burning, blurred vision, or swelling persist transport to the nearest medical facility for additional treatment.

Symptoms: Eye irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blurred vision.

Ingestion

In general no treatment is necessary unless large quantities are swallowed, however, get medical advice.

Immediate Medical Attention

Causes central nervous system depression. Potential for chemical pneumonitis. Call a doctor or poison control center for guidance.

Medical Treatment

Causes central nervous system depression. Potential for chemical pneumonitis. Call a doctor or poison control center for guidance.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Read in conjunction with the Exposure Scenario for your specific use contained in the Annex. The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Use sealed systems as far as possible. Adequate explosion-proof ventilation to control airborne concentrations below the exposure guidelines/limits. Local exhaust ventilation is recommended. Firewater monitors and deluge systems are recommended. Eye washes and showers for emergency use. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated.

Hands

Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection. Longer term protection: Nitrile rubber gloves. Incidental contact/Splash protection: PVC, neoprene or nitrile rubber gloves For continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognize that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time maybe acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Glove thickness should be typically greater than 0.35 mm depending on the glove make and model. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended.

Eyes

If material is handled such that it could be splashed into eyes, protective eyewear is recommended. Approved to EU Standard EN166.

Respiratory

If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are unsuitable (e.g. airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. If air-filtering respirators are suitable for conditions of use: Select a filter suitable for organic gases and vapours meeting EN14387 [Filter type A, for use against certain organic gases and vapours with a boiling point >65C (149F)].

Skin/Body

Skin protection is not required under normal conditions of use. For prolonged or repeated exposures use impervious clothing over parts of the body subject to exposure. If repeated and/or prolonged skin exposure to the substance is likely, then wear suitable gloves tested to relevant Standard, and provide employee skin care programmes. Protective clothing approved to EU Standard EN14605. Wear antistatic and flame retardant clothing, if a local risk assessment deems it so.

Environmental

Read in conjunction with the Exposure Scenario for your specific use contained in the Annex. Take appropriate measures to fulfil the requirements of relevant environmental protection legislation. Avoid contamination of the environment by following advice given in Chapter 6. If necessary, prevent undissolved material from being discharged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water. Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. Minimise release to the environment. An environmental assessment must be made to ensure compliance with local environmental legislation. Information on accidental release measures are to be found in section 6.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Explosive Limits
---
Form
---
Lower Explosive Limit
1.5 %(V)
Melting Point
-65 C
Kinematic Viscosity
Data not available
Solubility In Water
198 g/l (20 C)
Solubility In Fat
---
Relative Density
0.96 - 0.97 (20 C)
Vapor Pressure
502 Pa (25 C)
Odor Threshold
Data not available
Cloud Point
---
Colour
clear
Auto Ignition Temperature
333 C
State Under Standard Conditions
---
Relative Evaporation Rate
---
Flammability
Not applicable
Decomposition Temperature
no data available
Properties Status
---
Freezing Point
-65 C
Upper Explosive Limit
7 %(V)
Physical State Data
liquid
Solidification Point
---
Softening Point
---
Physical State
Liquid.
Density
967 kg/m3 (20 C)
Vapor Density
---
Ph
Not applicable
Boiling Point
143 - 149 C
Evaporation Rate
0.3
Voc Content
---
Molecular Weight
132 g/mol
Flash Point
45 C
Solubility
---
Appearance
Liquid.
Metal Corrosion
---
Colour Intensity
---
Partition Coefficient
log Pow: 1.2
Crystallisation Point
---
Odor
Ethereal
Dynamic Viscosity
1.23 mPa.s (20 C)
Bulk Density
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3272
Shipping Name
ESTERS, N.O.S.
Packing Group
III
ADR

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

IMDG

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

IATA

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Methyl PROXITOL Acetate known by?

Methyl PROXITOL Acetate is also known as: PMA

What is the hazard signal word for Methyl PROXITOL Acetate?

The signal word is warning.

What is the physical form of Methyl PROXITOL Acetate?

Methyl PROXITOL Acetate is a liquid. appearing as liquid. with clear color. It has ethereal odor.

What is Methyl PROXITOL Acetate used for?

Solvent. Substance/Mixture Please refer to Ch16 and/or the annexes for the registered uses under REACH.

What are the hazard statements for Methyl PROXITOL Acetate?

This substance has 1 hazard statement:

  • H226: Flammable liquid and vapour.

What is the melting point of Methyl PROXITOL Acetate?

The melting point is -65 C and the boiling point is 143 - 149 C.

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