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n-Hexane

DANGER Fluid SDS/MSDS
Chemical Identity

Product Identification & Regulatory Data

Official chemical identifiers, CAS numbers, and regulatory compliance information

Basic Product Information

Product Name
n-Hexane
Product Code
4022
Chemical Name
Hexane-(n) a.r.
Synonyms
pure grade / hexyl hydride / high purity normal hexane / n-caproylhydride / n-hexane / n-hexyl hydride / normal-caproyl hydride / normal-hexane / normal-hexyl hydride / skellysolve B / solvent hexane

Regulatory Identifiers

CAS Number

Chemical Abstracts Service registry number - unique identifier for chemical substances

EC Number

European Community number - used for regulatory compliance in EU/EEA

Uses Information

Identified Uses
For professional users only. Life cycle stages: IS Use at industrial Sites, M Manufacture. Sector of Use: SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites, SU9 Manufacture of fine chemicals, SU10 Formulation [mixing] of preparations and/or re-packaging (excluding alloys), SU24 Scientific research and development. Product category: PC19 Intermediate, PC20 Processing aids such as pH-regulators, flocculants, precipitants, neutralization agents, PC21 Laboratory chemicals, PC29 Pharmaceuticals, PC39 Cosmetics, personal care products, PC40 Extraction agents. Process category: PROC1 Chemical production or refinery in closed process without likelihood of exposure or processes with equivalent containment conditions. PROC2 Chemical production or refinery in closed continuous process with occasional controlled exposure or processes with equivalent containment conditions, PROC3 Manufacture or formulation in the chemical industry in closed batch processes with occasional controlled exposure or processes with equivalent containment condition, PROC4 Chemical production where opportunity for exposure arises, PROC5 Mixing or blending in batch processes, PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including weighing), PROC15 Use as laboratory reagent. Environmental release category: ERC1 Manufacture of the substance, ERC2 Formulation into mixture, ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article), ERC6a Use of intermediate. Article category: AC0 Other. Application of the substance / the mixture: Industrial use, Chemical analytics, Laboratory chemical.
Uses Advised Against
The product is not intended for use by consumers

Overview

n-Hexane (CAS: 110-54-3 ) is a liquid substance commonly used for professional users only. life cycle stages: is use at industrial sites, m manufacture. sector of use: su3 industrial uses: uses of substances as such or in preparations at industrial sites, su9 manufacture of fine chemicals, su10 formulation [mixing] of preparations and/or re-packaging (excluding alloys), su24 scientific research and development. product category: pc19 intermediate, pc20 processing aids such as ph-regulators, flocculants, precipitants, neutralization agents, pc21 laboratory chemicals, pc29 pharmaceuticals, pc39 cosmetics, personal care products, pc40 extraction agents. process category: proc1 chemical production or refinery in closed process without likelihood of exposure or processes with equivalent containment conditions. proc2 chemical production or refinery in closed continuous process with occasional controlled exposure or processes with equivalent containment conditions, proc3 manufacture or formulation in the chemical industry in closed batch processes with occasional controlled exposure or processes with equivalent containment condition, proc4 chemical production where opportunity for exposure arises, proc5 mixing or blending in batch processes, proc9 transfer of substance or mixture into small containers (dedicated filling line, including weighing), proc15 use as laboratory reagent. environmental release category: erc1 manufacture of the substance, erc2 formulation into mixture, erc4 use of non-reactive processing aid at industrial site (no inclusion into or onto article), erc6a use of intermediate. article category: ac0 other. application of the substance / the mixture: industrial use, chemical analytics, laboratory chemical..

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Safety Classification

GHS Hazard Classification & Safety Warnings

Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications

Classification Status

Classified

Signal Word

danger (Danger)

Hazard Classifications

STOT SE Category 3 H336
Flam. Liq. Category 2 H225
Repr. Category 2 H361
STOT RE Category 2 H373
Asp. Tox. Category 1 H304
Aquatic Chronic Category 2 H411
Skin Irrit. Category 2 H315

GHS Hazard Pictograms & Safety Symbols

GHS02 GHS Hazard Pictogram: Flammable hazard - Fire risk materials including gases, liquids, and solids

GHS02

GHS07 GHS Hazard Pictogram: Health hazard warning - Materials harmful to health including irritants and sensitizers

GHS07

GHS08 GHS Hazard Pictogram: Serious health hazard - Carcinogenic, mutagenic, or toxic to organs

GHS08

GHS09 GHS Hazard Pictogram: Environmental hazard - Materials toxic to aquatic life and environment

GHS09

GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions

Hazard Statements

  • H225: Highly flammable liquid and vapour.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H336: May cause drowsiness or dizziness.
  • H361: Suspected of damaging fertility or the unborn child.
  • H373: May cause damage to organs through prolonged or repeated exposure.
  • H411: Toxic to aquatic life with long lasting effects.

Precautionary Statements

  • P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P241: Use explosion-proof [electrical/ventilating/lighting] equipment.
  • P280: Wear protective gloves/protective clothing/eye protection/face protection.
  • P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
  • P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P403+P233: Store in a well-ventilated place. Keep container tightly closed.
  • P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
Supply Chain

Manufacturers & Suppliers

Authorized suppliers, manufacturers, and distribution network information

Th. Geyer GmbH & Co. KG company logo - Safety Data Sheet supplier organization

Th. Geyer GmbH & Co. KG

manufacturer

Dornierstr. 4 6 D-71272 Renningen

DE

+49(0)7159-1637-0

+49 (0)7159/18417

Emergency

24/7 Emergency Response

Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies

National Poisons Information Service

(00 44) 87 06 00 62 66

GB

NHS 111

111

GB

In England and Wales

NHS 24

111

GB

In Scotland

Composition

Chemical Composition & Hazardous Ingredients

Detailed component analysis, concentration ranges, and hazardous substance identification

Product Type

substance

Chemical Components & Hazardous Substances

Chemical Name CAS Number Concentration Hazardous
Hexane-(n) a.r.
EC: 203-777-6
110-54-3 Not specified Non-hazardous
First Aid

Emergency First Aid Measures

Critical first aid procedures for chemical exposure incidents and medical emergencies

Inhalation Exposure

Remove person from danger zone. Supply fresh air. Seek immediate medical advice.

Skin Contact

Wash with plenty of soap and water, take off soiled clothes and shoes. After prolonged contact (accidental/forced) or any signs of skin changes (redness or other signs of inflammation), consult a doctor. If skin irritation continues, consult a doctor.

Symptoms:

redness or other signs of inflammation, skin irritation

Eye Contact

Protect unharmed eye. Remove contact lenses. Seek medical treatment. Immediately rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

Ingestion/Swallowing

Do not induce vomiting - risk of aspiration. Keep airways clear. Call a doctor immediately.

Symptoms:

Pulmonary failure possible after aspiration of vomit.

Immediate Medical Attention Required

In case of lung irritation, administer glucocorticoid dose aerosol. If swallowed or in case of vomiting, danger of entering the lungs. Monitor circulation, possible shock treatment. Later observation for pneumonia and pulmonary oedema. Symptomatic treatment.

Medical Treatment

In case of lung irritation, administer glucocorticoid dose aerosol. Monitor circulation, possible shock treatment. Later observation for pneumonia and pulmonary oedema. Symptomatic treatment.

Alternatives

Related Chemical Substances & Alternative Products

Similar chemicals with comparable safety profiles and industrial applications

Section 9

Technical Specifications & Material Properties

Physical state, chemical properties, melting point, boiling point, and material characteristics

Physical State
Fluid
Critical Property
Physical State Data
liquid
State Under Standard Conditions
Not available
Appearance
Liquid
Colour
Colourless
Colour Intensity
Not available
Form
Liquid
Odor
Characteristic
Odor Threshold
Not available
Ph
Not determined.
Melting Point
-95.3 C
Critical Property
Boiling Point
~68 C
Critical Property
Flash Point
-26 C
Critical Property
Freezing Point
-95.3 C
Softening Point
Not available
Solidification Point
Not available
Cloud Point
Not available
Crystallisation Point
Not available
Relative Evaporation Rate
Not available
Evaporation Rate
Not determined.
Vapor Pressure
Not determined.
Vapor Density
Not determined.
Relative Density
Not determined.
Bulk Density
Not available
Density
~0.66 g/cm
Critical Property
Flammability
Not applicable.
Upper Explosive Limit
7.4 Vol %
Lower Explosive Limit
1.2 Vol %
Explosive Limits
Not available
Auto Ignition Temperature
240 C
Decomposition Temperature
Not determined.
Solubility
Not available
Partition Coefficient
Not determined.
Solubility In Water
0.05 g/l
Solubility In Fat
Not available
Molecular Weight
Not available
Voc Content
Not available
Metal Corrosion
Void
Dynamic Viscosity
Not determined.
Kinematic Viscosity
Not determined.
Properties Status
Not available
Section 8

Exposure Controls & Personal Protective Equipment

Occupational exposure limits, engineering controls, and required safety equipment

Engineering Controls

No further data; see section 7.

Hand Protection

Labsoluteprotective Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves Nitrile rubber, NBR Material thickness > 0.4 mm The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material level 6 for application > 480 min The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eye Protection

Safety glasses

Respiratory Protection

Not necessary if room is well-ventilated.

Skin/Body Protection

Protective work clothing (e. g. safety shoes EN ISO 20345, long-sleeved protective working garments).

Section 14

Transportation & Shipping Information

UN numbers, shipping names, transport classes, and regulatory transport requirements

UN Number

UN1208

Proper Shipping Name

HEXANES, ENVIRONMENTALLY HAZARDOUS

Transport Hazard Class

3

Packing Group

II

ADR Transport Precautions

Warning: Flammable liquids.

IMDG Maritime Transport Precautions

Warning: Flammable liquids.

IATA Air Transport Precautions

Warning: Flammable liquids.

FAQ

Chemical Safety FAQ & Common Questions

Most frequently asked questions about safety, handling, storage, and regulatory compliance

What other names is n-Hexane known by?

n-Hexane is also known as: pure grade / hexyl hydride / high purity normal hexane / n-caproylhydride / n-hexane / n-hexyl hydride / normal-caproyl hydride / normal-hexane / normal-hexyl hydride / skellysolve B / solvent hexane

What is the hazard signal word for n-Hexane?

The signal word for this substance is "danger".

What is the physical form of n-Hexane?

n-Hexane is a fluid appearing as liquid with colourless color. It has characteristic odor.

What is n-Hexane used for?

For professional users only. Life cycle stages: IS Use at industrial Sites, M Manufacture. Sector of Use: SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites, SU9 Manufacture of fine chemicals, SU10 Formulation [mixing] of preparations and/or re-packaging (excluding alloys), SU24 Scientific research and development. Product category: PC19 Intermediate, PC20 Processing aids such as pH-regulators, flocculants, precipitants, neutralization agents, PC21 Laboratory chemicals, PC29 Pharmaceuticals, PC39 Cosmetics, personal care products, PC40 Extraction agents. Process category: PROC1 Chemical production or refinery in closed process without likelihood of exposure or processes with equivalent containment conditions. PROC2 Chemical production or refinery in closed continuous process with occasional controlled exposure or processes with equivalent containment conditions, PROC3 Manufacture or formulation in the chemical industry in closed batch processes with occasional controlled exposure or processes with equivalent containment condition, PROC4 Chemical production where opportunity for exposure arises, PROC5 Mixing or blending in batch processes, PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including weighing), PROC15 Use as laboratory reagent. Environmental release category: ERC1 Manufacture of the substance, ERC2 Formulation into mixture, ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article), ERC6a Use of intermediate. Article category: AC0 Other. Application of the substance / the mixture: Industrial use, Chemical analytics, Laboratory chemical.

What are the hazard statements for n-Hexane?

This substance has 7 hazard statements: H225: Highly flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H336: May cause drowsiness or dizziness. H361: Suspected of damaging fertility or the unborn child. H373: May cause damage to organs through prolonged or repeated exposure. H411: Toxic to aquatic life with long lasting effects.

What is the melting point of n-Hexane?

The melting point is -95.3 C and the boiling point is ~68 C.