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Safety Data Sheet EN

Raw Pygas

CAS 68477-53-2
EC 270-736-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Raw Pygas
Chemical Name
Distillates (petroleum), steam-cracked, C5-12 fraction
Synonyms
LICHTE AROM OLIE (BENZEEN >10 - < 50%)

Regulatory Identifiers

CAS Number
68477-53-2 Check regulations →
EC Number
270-736-7 Check regulations →
REACH No.
01-2119493702-34-0003

Identified Uses

Manufacture of substance Distribution of substance Use as an intermediate Formulation and (re)packing of substances and mixtures Use as a fuel (Industrial use) Use as a fuel (Professional use)

Manufacturers & Suppliers

S

SABIC Petrochemicals B.V.

global supplier

Europaboulevard 1, Sittard P.O. Box 5151, 6130 PD Sittard The Netherlands

Emergency Contacts

Emergency Contact

+1-760-476-3961

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Muta. Cat. 1B H340
Carc. Cat. 1B H350
Asp. Tox. Cat. 1 H304
Aquatic Chronic Cat. 4 H413

GHS Pictograms

GHS02 - Flammable

GHS02

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H340 May cause genetic defects.
H350 May cause cancer.
H413 May cause long lasting harmful effects to aquatic life.

Precautionary Statements

Obtain special instructions before use.
Wear protective gloves: > 8 hours (breakthrough time): Viton (> 0.70 mm), nitrile rubber (> 0.38 mm) .
Wear eye or face protection: Recommended: full-face mask.
Keep away from heat, sparks, open flames and hot surfaces. - No smoking.
Use explosion-proof electrical, ventilating, lighting and all material-handling equipment.
Avoid release to the environment.
IF SWALLOWED: Immediately call a POISON CENTER or physician.
Do NOT induce vomiting.
IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
Keep cool.
Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type UVCB

Raw Pygas

Chemical Name CAS Number Concentration Hazardous
Distillates (petroleum), steam-cracked, C5-12 fraction EC: 270-736-7 68477-53-2 100% Yes
iso-alkaanen, cyclisch (<0,1% benzeen CAS 71-43-2) EC: 200-753-7 71-43-2 25 - 50% Yes
Toluene imp. EC: 203-625-9 108-88-3 10 - 25% Yes
pentaan stof met nationale blootstellingsgrenswaarde(n) op de werkvloer (BE); stof waarvoor binnen de Gemeenschap een blootstellingsgrens op de werkvloer geldt EC: 203-692-4 109-66-0 5 - 10% Yes
ethylbenzene EC: 202-849-4 100-41-4 5 - 10% Yes
XYLENE; MELANGE ISOMERES O,M,P EC: 215-535-7 1330-20-7 1 - 10% Yes
Styrene EC: 202-851-5 100-42-5 1 - 5% Yes
3a,4,7,7a- tetrahydro-4,7- methanondeen EC: 201-052-9 77-73-6 0.1 - 5% Yes
Isopreen EC: 201-143-3 78-79-5 0.1 - 5% Yes
cyclopentane EC: 206-016-6 287-92-3 0.1 - 5% Yes
Cyclohexane stof waarvoor binnen de Gemeenschap een blootstellingsgrens op de werkvloer geldt EC: 203-806-2 110-82-7 0.1 - 5% Yes
Hexane (mixture of isomers) EC: 203-777-6 110-54-3 1 - 2.5% Yes
naftaleen stof waarvoor binnen de Gemeenschap een blootstellingsgrens op de werkvloer geldt EC: 202-049-5 91-20-3 0.1 - 1% Yes

See Section 16 for the full text of the H statements declared above. See Section 16 for the full text of the R-phrases declared above. Occupational exposure limits, if available, are listed in Section 8.

Notes

There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the substance and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: No known significant effects or critical hazards.

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: No known significant effects or critical hazards.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Symptoms: No known significant effects or critical hazards.

Ingestion

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: May be fatal if swallowed and enters airways. Adverse symptoms may include the following: nausea or vomiting.

Immediate Medical Attention

Get medical attention. If unconscious, get medical attention immediately. Call a poison center or physician. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Medical Treatment

Treat symptomatically. No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. > 8 hours (breakthrough time): Viton (> 0.70 mm), nitrile rubber (> 0. 38 mm)

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Recommended: full-face mask

Respiratory

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: selfcontained breathing apparatus (SCBA)

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods. Recommended: chemical-resistant protective suit. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Flash Point
Closed cup: <4C
State Under Standard Conditions
---
Relative Evaporation Rate
---
Physical State
Liquid.
Voc Content
---
Solubility
Very slightly soluble in the following materials: cold water.
Physical State Data
liquid
Explosive Limits
---
Relative Density
Not available.
Dynamic Viscosity
---
Vapor Density
Not available.
Odor Threshold
Not available.
Softening Point
---
Solubility In Fat
---
Melting Point
-100 to -29C
Colour
Colourless to light yellow.
Density
0.9 g/cm
Kinematic Viscosity
Kinematic (40C): <0.01 cm [2] /s
Crystallisation Point
---
Cloud Point
---
Metal Corrosion
---
Upper Explosive Limit
Not available.
Colour Intensity
---
Vapor Pressure
20 to 30 kPa [room temperature]
Bulk Density
---
Odor
Aromatic.
Flammability
Not available.
Auto Ignition Temperature
2.2 to 6.5
Solidification Point
---
Decomposition Temperature
Not available.
Freezing Point
-100 to -29C
Form
---
Partition Coefficient
Not available.
Appearance
---
Solubility In Water
Very slightly soluble in the following materials: cold water.
Properties Status
---
Boiling Point
>36C
Ph
Not available.
Evaporation Rate
Not available.
Lower Explosive Limit
Not available.
Molecular Weight
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3295
Shipping Name
HYDROCARBONS, LIQUID, N.O.S.
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Raw Pygas known by?

Raw Pygas is also known as: LICHTE AROM OLIE (BENZEEN >10 - < 50%)

What is the hazard signal word for Raw Pygas?

The signal word is danger.

What is the physical form of Raw Pygas?

Raw Pygas is a liquid. with colourless to light yellow. color. It has aromatic. odor.

What is the solubility of Raw Pygas?

Very slightly soluble in the following materials: cold water.

What is Raw Pygas used for?

Manufacture of substance Distribution of substance Use as an intermediate Formulation and (re)packing of substances and mixtures Use as a fuel (Industrial use) Use as a fuel (Professional use)

What are the hazard statements for Raw Pygas?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H304: May be fatal if swallowed and enters airways.
  • H340: May cause genetic defects.
  • H350: May cause cancer.
  • H413: May cause long lasting harmful effects to aquatic life.

What is the melting point of Raw Pygas?

The melting point is -100 to -29C and the boiling point is >36C.

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