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Safety Data Sheet EN

Naphtha, (petroleum), full-range straight run

CAS 64741-42-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Naphtha, (petroleum), full-range straight run
Product Code
001B8974
Chemical Name
Naphtha, (petroleum), full-range straight run
Synonyms
Naphtha F.R.

Regulatory Identifiers

CAS Number
64741-42-0 Check regulations →
REACH No.
01-2119474679-18-0089

Identified Uses

For use as a component in gasoline. Feedstock in chemical industry. Refinery Feedstock. Please refer to Ch16 and/or the annexes for the registered uses under REACH.

Uses advised against

This product must not be used in applications other than those recommended in Section 1, without first seeking the advice of the supplier.

Manufacturers & Suppliers

S

Shell Deutschland Oil GmbH

manufacturer

Suhrenkamp 71-77, D-22335 Hamburg

(+49) 40 6324-6255

Emergency Contacts

Emergency Contact

+49 (0)40 6324-5110

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 1 H224
Skin Irrit. Cat. 2 H315
Asp. Tox. Cat. 1 H304
Repr. Cat. 2 H361fd
Muta. Cat. 1B H340
Carc. Cat. 1B H350
STOT SE Cat. 3 H336
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H224 Extremely flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H340 May cause genetic defects.
H350 May cause cancer.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

A complex combination of hydrocarbons produced by distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C4 through C11 and boiling in the range of approximately minus 20°C to 220°C (-4°F to 428°F).

Chemical Name CAS Number Concentration Hazardous
Naphtha, (petroleum), full-range straight run EC: 265-042-6 64741-42-0 100% Yes

Contains Benzene, CAS # 71-43-2. Contains Toluene, CAS # 108-88-3. Contains Ethylbenzene, CAS # 100-41-4. Contains n-Hexane, CAS # 110-54-3. Contains Xylene (Mixed Isomers), CAS # 1330-20-7. Contains Cyclohexane, CAS# 110-82-7. Contains Tri-methyl-benzene (all isomers), CAS# 25551-13-7.

Notes

Product is not a mixture according regulation 1907/2006/EC.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If rapid recovery does not occur, transport to nearest medical facility for additional treatment.

Symptoms: Coughing, choking, wheezing, difficulty in breathing, chest congestion, shortness of breath, fever, dizziness, light-headedness, headache, nausea, loss of coordination, unconsciousness, death.

Skin contact

Remove contaminated clothing. Immediately flush skin with large amounts of water for at least 15 minutes, and follow by washing with soap and water if available. If redness, swelling, pain and/or blisters occur, transport to the nearest medical facility for additional treatment.

Symptoms: Burning sensation, redness, swelling, and/or blisters.

Eye contact

Flush eyes with water while holding eyelids open. Rest eyes for 30 minutes. If redness, burning, blurred vision, or swelling persist, transport to the nearest medical facility for additional treatment.

Symptoms: Burning sensation, temporary redness of the eye.

Ingestion

If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration.

Immediate Medical Attention

If rapid recovery does not occur, if redness, swelling, pain and/or blisters occur, if eye symptoms persist, or if delayed signs and symptoms appear within the next 6 hours (fever greater than 101°F (38.3°C), shortness of breath, chest congestion or continued coughing or wheezing).

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.

Unsuitable media

Do not use direct water jets on the burning product as they could cause a steam explosion and spread of the fire. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.

Specific hazards

Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. The vapour is heavier than air, spreads along the ground and distant ignition is possible. Will float and can be reignited on surface water.

Instructions

If the fire cannot be extinguished the only course of action is to evacuate immediately. Keep adjacent containers cool by spraying with water. If possible remove containers from the danger zone.

Firefighter Protection

Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate the area of all non-essential personnel. Ventilate contaminated area thoroughly. Shut off leaks, if possible without personal risks. Remove all possible sources of ignition in the surrounding area and evacuate all personnel. Attempt to disperse the gas or to direct its flow to a safe location for example by using fog sprays.

Small spill

For small liquid spills (< 1 drum), transfer by mechanical means to a labelled, sealable container for product recovery or safe disposal. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely.

Large spill

For large liquid spills (> 1 drum), transfer by mechanical means such as vacuum truck to a salvage tank for recovery or safe disposal. Do not flush away residues with water. Retain as contaminated waste. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely.

Environmental

Prevent from spreading or entering into drains, ditches or rivers by using sand, earth, or other appropriate barriers.

Cleanup methods

transfer by mechanical means, soak up with an appropriate absorbent material, remove contaminated soil

Materials: appropriate absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid breathing vapours or contact with material. Only use in well ventilated areas. Wash thoroughly after handling. Air-dry contaminated clothing in a well-ventilated area before laundering. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Prevent spillages. When using do not eat or drink. Extinguish any naked flames. Do not smoke. Remove ignition sources. Avoid sparks. Never siphon by mouth. The vapour is heavier than air, spreads along the ground and distant ignition is possible. Avoid exposure.

Storage

Tanks must be specifically designed for use with this product. Bulk storage tanks should be diked (bunded). Locate tanks away from heat and other sources of ignition. Keep only in original container. Keep container tightly closed. Keep containers closed when not in use.

Hygiene

Wash thoroughly after handling. When using do not eat or drink.

Fire prevention

Extinguish any naked flames. Do not smoke. Remove ignition sources. Avoid sparks. Locate tanks away from heat and other sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use sealed systems as far as possible. Adequate explosion-proof ventilation to control airborne concentrations below the exposure guidelines/limits. Local exhaust ventilation is recommended.

Hands

Chemical resistant gloves/gauntlets. Select gloves tested to a relevant standard (e.g. Europe EN374, US F739). When prolonged or frequent repeated contact occurs, Nitrile gloves may be suitable. (Breakthrough time of > 240 minutes.) For incidental contact/splash protection Neoprene, PVC gloves may be suitable. Contaminated gloves should be replaced.

Eyes

Chemical splash goggles (chemical monogoggles). Approved to EU Standard EN166.

Respiratory

If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Where air-filtering respirators are unsuitable (e.g. airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus. All respiratory protection equipment and use must be in accordance with local regulations. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65 °C (149 °F)] meeting EN14387.

Skin/Body

Chemical resistant gloves/gauntlets, boots, and apron (where risk of splashing).

Environmental

Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Vapor Density
Data not available
Solubility
Data not available
Molecular Weight
---
Partition Coefficient
Not applicable.
Decomposition Temperature
Data not available
State Under Standard Conditions
---
Kinematic Viscosity
0,5 mm2/s at 40 °C / 104 °F
Appearance
Pale yellow. Straw. Liquid.
Melting Point
Not applicable.
Cloud Point
---
Crystallisation Point
---
Solidification Point
---
Form
Liquid.
Softening Point
---
Boiling Point
ca. -20 - 220 °C / -4 - 428 °F
Colour Intensity
---
Odor
Hydrocarbon.
Solubility In Water
Not applicable
Metal Corrosion
---
Solubility In Fat
---
Relative Evaporation Rate
---
Lower Explosive Limit
1,4 %(V)
Physical State
Liquid
Upper Explosive Limit
7,6 %(V)
Dynamic Viscosity
---
Odor Threshold
---
Flammability
---
Bulk Density
Data not available
Vapor Pressure
90 - 860 hPa at 37,8 °C / 100,0 °F
Explosive Limits
---
Flash Point
< 0 °C / 32 °F
Relative Density
0,707 at 15 °C / 59 °F
Auto Ignition Temperature
280 - 470 °C / 536 - 878 °F
Density
0,645 - 0,760 g/cm3 at 15 °C / 59 °F
Ph
Not applicable.
Properties Status
---
Voc Content
---
Colour
Pale yellow. Straw.
Evaporation Rate
---
Freezing Point
Not applicable.
Physical State Data
liquid
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions of use.

Reactivity

May oxidise in the presence of air.

Hazardous reactions

May oxidise in the presence of air.

Avoid

Avoid heat, sparks, open flames and other ignition sources.

Incompatible

Strong oxidising agents.

Decomposition

Hazardous decomposition products are not expected to form during normal storage. Thermal decomposition is highly dependent on conditions. A complex mixture of airborne solids, liquids and gases, including carbon monoxide, carbon dioxide and other organic compounds will be evolved when this material undergoes combustion or thermal or oxidative degradation.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Waste arising from a spillage or tank cleaning should be disposed of in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand.

Disposal

Recover or recycle if possible.

Waste Codes

13 07 03 wastes of liquid fuels, other fuels (including mixtures) EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1268
Shipping Name
PETROLEUM DISTILLATES, N.O.S. (Naphtha, (petroleum), full-range straight run)
Transport Class
3
Packing Group
I
ADR

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

IMDG

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

IATA

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Performed

Contains component(s) which are restricted for use with young people. Contains component(s) which may potentially endanger the health of pregnant woman and the unborn child.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Naphtha, (petroleum), full-range straight run known by?

Naphtha, (petroleum), full-range straight run is also known as: Naphtha F.R.

What is the hazard signal word for Naphtha, (petroleum), full-range straight run?

The signal word is danger.

What is the physical form of Naphtha, (petroleum), full-range straight run?

Naphtha, (petroleum), full-range straight run is a liquid appearing as pale yellow. straw. liquid. with pale yellow. straw. color. It has hydrocarbon. odor.

What is the solubility of Naphtha, (petroleum), full-range straight run?

Data not available

What is Naphtha, (petroleum), full-range straight run used for?

For use as a component in gasoline. Feedstock in chemical industry. Refinery Feedstock. Please refer to Ch16 and/or the annexes for the registered uses under REACH.

What are the hazard statements for Naphtha, (petroleum), full-range straight run?

This substance has 8 hazard statements:

  • H224: Extremely flammable liquid and vapor.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H336: May cause drowsiness or dizziness.
  • H340: May cause genetic defects.
  • H350: May cause cancer.
  • H361fd: Suspected of damaging fertility. Suspected of damaging the unborn child.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Naphtha, (petroleum), full-range straight run?

The melting point is Not applicable. and the boiling point is ca. -20 - 220 °C / -4 - 428 °F.