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Safety Data Sheet EN

tert-Butyl alcohol

CAS 75-65-0
EC 200-889-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
tert-Butyl alcohol
Product Code
L12338
Chemical Name
tert-Butyl alcohol
Synonyms
tert-Butyl alcohol; 2-Methyl-2-propanol; 2-Methylpropan-2-ol

Regulatory Identifiers

CAS Number
75-65-0 Check regulations →
EC Number
200-889-7 Check regulations →

Identified Uses

Laboratory chemicals. Sector of use: SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites; Product category: PC21 - Laboratory chemicals; Process categories: PROC15 - Use as a laboratory reagent; Environmental release category: ERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)

Uses advised against

No Information available

Manufacturers & Suppliers

T

Thermo Fisher (Kandel) GmbH

manufacturer

Erlenbachweg 2, 76870 Kandel, Germany

+49 (0) 721 84007 280

Fisher Scientific AG logo

Fisher Scientific AG

distributor

Neuhofstrasse 11, CH 4153 Reinach

+41 (0) 56 618 41 11

https://www.fishersci.ch/ch/en/customer-help-support/forms/email-us.html

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

Tox Info Suisse

145

24hr

Tox Info Suisse

+41-44 251 51 51

Chemtrec

0800 564 402

24h

Chemtrec

+41-43 508 20 11

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Acute Tox. Cat. 4 H332
Eye Irrit. Cat. 2 H319
STOT SE Cat. 3 H335
STOT SE Cat. 3 H336

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapor
H319 Causes serious eye irritation
H332 Harmful if inhaled
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P280 Wear eye protection/ face protection
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P312 Call a POISON CENTER or doctor if you feel unwell

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
tert-Butyl alcohol EC: 200-889-7 75-65-0 95% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Symptoms: Difficulty in breathing. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Clean mouth with water and drink afterwards plenty of water.

Immediate Medical Attention

Get medical attention if symptoms occur or persist. Call a physician if symptoms persist or skin irritation persists.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

Water may be ineffective.

Specific hazards

Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required.

Environmental

Should not be released into the environment.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Flammables area. Keep away from heat, sparks and flame.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Butyl rubber (480 minutes, 0.35 mm, EN 374, Level 6), Neoprene gloves (480 minutes, 0.45 mm, EN 374), Viton (R) (480 minutes, 0.3 mm). Inspect gloves before use. Observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Gloves are suitable for the task considering chemical compatibility, dexterity, operational conditions, user susceptibility, and specific local conditions such as danger of cuts, abrasion. Handle gloves with care avoiding skin contamination.

Eyes

Goggles (European standard - EN 166)

Respiratory

No protective equipment is needed under normal use conditions. For large scale/emergency use, use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. For small scale/Laboratory use, maintain adequate ventilation.

Skin/Body

Long sleeved clothing.

Environmental

No information available.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear
Colour
---
Colour Intensity
---
Form
---
Odor
Strong
Odor Threshold
No data available
Ph
7
Melting Point
25 - 25.5 C / 77 - 77.9 F
Boiling Point
83 C / 181.4 F @ 760 mmHg
Flash Point
11 C / 51.8 F
Freezing Point
---
Softening Point
No data available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
36 mbar @ 20 C
Vapor Density
2.6 (Air = 1.0)
Relative Density
0.775
Bulk Density
Not applicable Liquid
Density
0.775
Flammability
Highly flammable On basis of test data (liquid); Not applicable Liquid (solid,gas)
Upper Explosive Limit
8 Vol%
Lower Explosive Limit
1.8 Vol%
Explosive Limits
---
Auto Ignition Temperature
490 C / 914 F
Decomposition Temperature
No data available
Solubility
No information available
Partition Coefficient
tert-Butyl alcohol 0.317
Solubility In Water
Miscible
Solubility In Fat
---
Molecular Weight
74.12
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
6.43 mPa.s (25C)
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Ecotoxicity effects Do not empty into drains. | Component | Freshwater Fish | Water Flea | Freshwater Algae | | --- | --- | --- | --- | | tert-Butyl alcohol | LC50 >961 mg/L/96h (Pimephales promelas) | EC50 933 mg/L 48 h | EC50 1000 mg/L 72 h | | Component | Microtox | M-Factor | | --- | --- | --- | | tert-Butyl alcohol | EC50 > 10000 mg/L 17 h | |

12.2. Persistence and degradability

Resistence Readily biodegradable Persistence is unlikely, based on information available.

The substance is readily biodegradable and persistence is unlikely.

12.3. Bioaccumulative potential

Bioaccumulation is unlikely | Component | log Pow | Bioconcentration factor (BCF) | | --- | --- | --- | tert-Butyl alcohol | 0.317 | 1.09 dimensionless |

Bioaccumulation is unlikely

12.4. Mobility in soil

The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces. Will likely be mobile in the environment due to its volatility. Disperses rapidly in air

The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces. Will likely be mobile in the environment due to its volatility. Disperses rapidly in air.

12.5. Results of PBT and vPvB assessment

Substance is not considered persistent, bioaccumulative and toxic (PBT) / very persistent and very bioaccumulative (vPvB).

The substance is not considered to be PBT or vPvB.

12.6. Endocrine disrupting properties

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors

The product does not contain any known or suspected endocrine disruptors.

12.7. Other adverse effects

Persistent Organic Pollutant Ozone Depletion Potential This product does not contain any known or suspected substance This product does not contain any known or suspected substance

The product does not contain any known or suspected persistent organic pollutants or substances with ozone depletion potential.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1120
Shipping Name
BUTANOLS
Packing Group
II
ADR

No special precautions required.

IMDG

No special precautions required.

IATA

No special precautions required.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is tert-Butyl alcohol known by?

tert-Butyl alcohol is also known as: tert-Butyl alcohol; 2-Methyl-2-propanol; 2-Methylpropan-2-ol

What is the hazard signal word for tert-Butyl alcohol?

The signal word is danger.

What is the physical form of tert-Butyl alcohol?

tert-Butyl alcohol is a liquid appearing as clear . It has strong odor.

What is the solubility of tert-Butyl alcohol?

No information available

What is tert-Butyl alcohol used for?

Laboratory chemicals. Sector of use: SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites; Product category: PC21 - Laboratory chemicals; Process categories: PROC15 - Use as a laboratory reagent; Environmental release category: ERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)

What are the hazard statements for tert-Butyl alcohol?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H319: Causes serious eye irritation
  • H332: Harmful if inhaled
  • H335: May cause respiratory irritation
  • H336: May cause drowsiness or dizziness

What is the melting point of tert-Butyl alcohol?

The melting point is 25 - 25.5 C / 77 - 77.9 F and the boiling point is 83 C / 181.4 F @ 760 mmHg.