Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- Chloroform
- Product Code
- C/4920/08, C/4920/15, C/4920/17, C/4920/21, C/4920/25, C/4920/27 C/4920/PB17, C/4920/PC21, C/4920/21RSS, C/4920/24RSS, C/4920/25RSS, C/4920/34RSS, C/4920/27RSS
- Chemical Name
- Chloroform
- Synonyms
- Methane trichloride; Methenyl trichloride; Formyl trichloride
Regulatory Identifiers
- CAS Number
- 67-66-3 Check regulations →
- EC Number
- 200-663-8 Check regulations →
- REACH No.
- 01-2119486657-20
Identified Uses
Laboratory chemicals. Sector of use: SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites. Product category: PC21 - Laboratory chemicals. Process categories: PROC15 - Use as a laboratory reagent. Environmental release category: ERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)
Uses advised against
All other uses
Manufacturers & Suppliers
Fisher Scientific UK
national supplier
Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom
Thermo Fisher Scientific
national supplier
Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium
Emergency Contacts
Fisher Scientific UK
01509 231166
Chemtrec US
(800) 424-9300
Chemtrec EU
001-703-527-3887
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS06
GHS08
Hazard Statements
Precautionary Statements
Get a free compliance audit
Upload your SDS inventory and get a detailed compliance report
Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| Chloroform EC: 200-663-8 | 67-66-3 | 99% | Yes |
| 1-Pentene EC: 203-694-5 | 109-67-1 | 0.01% | Yes |
REACH registration number: 01-2119486657-20
Notes
Amylene is used as a stabilizer, but there is evidence that it may not prevent phosgene generation. Chloroform stabilized with amylene should be tested for phosgene content.
First Aid Measures
Emergency procedures for chemical exposure incidents
Remove to fresh air. If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required.
Symptoms: Difficulty in breathing. Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing.
Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Do NOT induce vomiting. Call a physician or poison control center immediately.
Immediate Medical Attention
Immediate medical attention is required.
Medical Treatment
Treat symptomatically. Signs of overdose include stupor and respiratory depression.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.
No information available.
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Thermal decomposition can lead to release of irritating gases and vapors.
Firefighter Protection
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Use personal protective equipment as required. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas.
Should not be released into the environment.
Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.
Materials: inert absorbent material
Related Products
Similar products with comparable safety profiles
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance.
Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from direct sunlight. Store under an inert atmosphere. Protect from moisture.
Handle in accordance with good industrial hygiene and safety practice.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Use only under a chemical fume hood. Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source
Protective gloves. Glove material: Viton (R) (Breakthrough time: >480 minutes, Level 6, EN 374), Neoprene (Breakthrough time: <25 minutes, thickness: 0.45 mm), Butyl rubber (Breakthrough time: <15 minutes, thickness: 0.35 mm).
Goggles (European standard - EN 166)
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator. Recommended Filter type: low boiling organic solvent Type AX Brown conforming to EN371. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator. Recommended half mask: Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141.
Long sleeved clothing.
Prevent product from entering drains.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
Stable under normal conditions. UNSTABLE (REACTIVE) UPON DEPLETION OF INHIBITOR. Light sensitive.
None known, based on information available
Hazardous polymerization does not occur. None under normal processing.
Incompatible products. Heat, flames and sparks. Excess heat. Exposure to light. Protect from moisture.
Strong oxidizing agents. Alkali metals. Aluminium. Acetone.
Carbon monoxide (CO). Carbon dioxide (CO₂). Phosgene. Hydrogen chloride gas.
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
The data for this section has not been processed yet.
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.
Waste is classified as hazardous.
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- UN1888
- Shipping Name
- Chloroform
- Transport Class
- 6.1
- Packing Group
- III
No special precautions required.
No special precautions required.
No special precautions required.
Regulatory Information
Chemical regulations, safety assessments, and compliance status
Frequently Asked Questions
Common questions about safety, handling, and properties
What other names is Chloroform known by?
Chloroform is also known as: Methane trichloride; Methenyl trichloride; Formyl trichloride
What is the hazard signal word for Chloroform?
The signal word is danger.
What is the physical form of Chloroform?
Chloroform is a liquid appearing as colorless with colorless color. It has aromatic sweet odor.
What is the solubility of Chloroform?
8 g/L (20°C)
What is Chloroform used for?
Laboratory chemicals. Sector of use: SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites. Product category: PC21 - Laboratory chemicals. Process categories: PROC15 - Use as a laboratory reagent. Environmental release category: ERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)
What are the hazard statements for Chloroform?
This substance has 8 hazard statements:
- H302: Harmful if swallowed
- H315: Causes skin irritation
- H319: Causes serious eye irritation
- H331: Toxic if inhaled
- H336: May cause drowsiness or dizziness
- H351: Suspected of causing cancer
- H361d: Suspected of damaging the unborn child
- H372: Causes damage to organs through prolonged or repeated exposure
What is the melting point of Chloroform?
The melting point is -63 °C / -81.4 °F and the boiling point is 61 °C / 141.8 °F.