Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- Chloroform
- Product Code
- 288306
- Chemical Name
- Chloroform
Regulatory Identifiers
- CAS Number
- 67-66-3 Check regulations →
Identified Uses
Laboratory chemicals, Synthesis of substances
Uses advised against
The product is being supplied under the TSCA R&D Exemption (40 CFR Section 720.36). It is the recipient's responsibility to comply with the requirements of the R&D exemption. The product may not be used for a non-exempt commercial purpose under TSCA unless appropriate consent is granted in writing by MilliporeSigma.
Manufacturers & Suppliers
Sigma-Aldrich Inc.
manufacturer
3050 SPRUCE ST, ST. LOUIS MO 63103, UNITED STATES
+1 314 771-5765
Emergency Contacts
CHEMTREC
800-424-9300
24 Hours/day; 7 Days/week
CHEMTREC
+1-703-527-3887
24 Hours/day; 7 Days/week
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS06
GHS07
GHS08
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| Chloroform EC: 200-663-8 | 67-66-3 | 100% | Yes |
| ethanol | --- | 1 - 5% | Yes |
First Aid Measures
Emergency procedures for chemical exposure incidents
After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.
Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Water, Foam, Carbon dioxide (CO2), Dry powder
For this substance/mixture no limitations of extinguishing agents are given.
Carbon oxides, Hydrogen chloride gas, Combustible. Development of hazardous combustion gases or vapours possible in the event of fire.
Suppress (knock down) gases/vapors/mists with a water spray jet.
Firefighter Protection
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.
Do not let product enter drains.
Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.
Materials: liquid-absorbent material (e.g. Chemizorb®)
Related Products
Similar products with comparable safety profiles
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Full contact: Material: Viton®, Minimum layer thickness: 0.7 mm, Break through time: 480 min, Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M). Splash contact: Material: butyl-rubber, Minimum layer thickness: 0.7 mm, Break through time: 10 min, Material tested: Butoject® (KCL 898).
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Recommended Filter type: Filter type AX. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
protective clothing
Do not let product enter drains.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
Sensitivity to light heat-sensitive. The product is chemically stable under standard ambient conditions (room temperature). Contains the following stabilizer(s): ethanol (>=0.5 - <=1 %)
No data available
Risk of explosion with: Ammonia, Amines, nitrogen oxides, bases, Oxygen, alkali amides, organic nitro compounds, strong alkalis, Fluorine, peroxi compounds, Alkaline earth metals, Alkali metals, Powdered metals, Methanol with alcoholates, Methanol with strong alkalis, Iron in powder form, various alloys, sensitive to shock, Methanol with Sodium hydroxide, magnesium in powder form, Oxygen with alkali compounds, Aluminum in powder form, Acetone with alkali compounds, Potassium sensitive to shock, sodium sensitive to shock. Violent reactions possible with: phosphines, bis(dimethylamino)dimethyl tin, nonmetallic hydrogen compounds, Powdered metals, Light metals, Ketones, mineral acids, Strong oxidizing agents, semimetallic hydrogen compounds
no information available
rubber, various plastics
In the event of fire: see section 5
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
The data for this section has not been processed yet.
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
Waste material must be disposed of in accordance with the national and local regulations.
Leave chemicals in original containers. No mixing with other waste.
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- 1888
- Shipping Name
- ChloroformSOLUTION
- Transport Class
- 6.1
- Packing Group
- III
Regulatory Information
Chemical regulations, safety assessments, and compliance status
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for Chloroform?
The signal word is danger.
What is the physical form of Chloroform?
Chloroform is a liquid appearing as liquid, clear with colorless color. It has sweet odor.
What is the solubility of Chloroform?
organic solvent at 20 C (68 F) - miscible
What is Chloroform used for?
Laboratory chemicals, Synthesis of substances
What are the hazard statements for Chloroform?
This substance has 9 hazard statements:
- H302: Harmful if swallowed.
- H315: Causes skin irritation.
- H319: Causes serious eye irritation.
- H331: Toxic if inhaled.
- H336: May cause drowsiness or dizziness.
- H351: Suspected of causing cancer.
- H361: Suspected of damaging fertility or the unborn child.
- H372: Causes damage to organs (Liver, Kidney) through prolonged or repeated exposure if swallowed.
- H402: Harmful to aquatic life.
What is the melting point of Chloroform?
The melting point is -64 °C (-83 °F) and the boiling point is 60.5 - 61.5 °C 140.9 - 142.7 °F at 1,013.25 hPa.